• Laser & Optoelectronics Progress
  • Vol. 55, Issue 11, 111602 (2018)
Xiaotong Xie**, Haitao Zhu, He Liu, Qinjiang He, and Renli Fu*
Author Affiliations
  • College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu 210016, China
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    DOI: 10.3788/LOP55.111602 Cite this Article Set citation alerts
    Xiaotong Xie, Haitao Zhu, He Liu, Qinjiang He, Renli Fu. Low-Temperature Sintering and Properties of Ceramics Fabricated from YAG∶Ce 3+ Phosphor Powder [J]. Laser & Optoelectronics Progress, 2018, 55(11): 111602 Copy Citation Text show less
    Flow char of coating process
    Fig. 1. Flow char of coating process
    Particle distributions of YAG∶Ce3+ phosphor powder
    Fig. 2. Particle distributions of YAG∶Ce3+ phosphor powder
    SEM images of YAG∶Ce3+ phosphor powder. (a) Original particles; (b) particles after ball milling; (c) particles after coating
    Fig. 3. SEM images of YAG∶Ce3+ phosphor powder. (a) Original particles; (b) particles after ball milling; (c) particles after coating
    UV-Vis absorption spectra of coated YAG∶Ce3+ phosphor powder
    Fig. 4. UV-Vis absorption spectra of coated YAG∶Ce3+ phosphor powder
    Coating model of YAG∶Ce3+ phosphor powder particle
    Fig. 5. Coating model of YAG∶Ce3+ phosphor powder particle
    Light illumination on spherical receiving surfaces of YAG∶Ce3+ phosphor powder particles before and after coating. (a) After TEOS coating; (b) before TEOS coating
    Fig. 6. Light illumination on spherical receiving surfaces of YAG∶Ce3+ phosphor powder particles before and after coating. (a) After TEOS coating; (b) before TEOS coating
    Light mapping of YAG∶Ce3+ ceramics excited by 460 nm blue light. (a) Non-excited state; (b) excited state
    Fig. 7. Light mapping of YAG∶Ce3+ ceramics excited by 460 nm blue light. (a) Non-excited state; (b) excited state
    Emission spectra
    Fig. 8. Emission spectra
    Relative densities of YAG∶Ce3+ ceramics with different amounts of TEOS after inserting at 1475-1625 ℃ for 5 h
    Fig. 9. Relative densities of YAG∶Ce3+ ceramics with different amounts of TEOS after inserting at 1475-1625 ℃ for 5 h
    Micro-morphologies of YAG ceramics after inserting at 1575 ℃ for 5 h. (a) Before coated with 2% TEOS; (b) after coated with 2% TEOS
    Fig. 10. Micro-morphologies of YAG ceramics after inserting at 1575 ℃ for 5 h. (a) Before coated with 2% TEOS; (b) after coated with 2% TEOS
    Relative densities of YAG ceramics sintered at 1400-1500 ℃ under different doping conditions
    Fig. 11. Relative densities of YAG ceramics sintered at 1400-1500 ℃ under different doping conditions
    Micro-morphologies of YAG ceramics sintered at different temperatures and and at different doping. (a) Cuo-TiO2 doped, 1450 ℃; (b) CuO doped, 1475 ℃
    Fig. 12. Micro-morphologies of YAG ceramics sintered at different temperatures and and at different doping. (a) Cuo-TiO2 doped, 1450 ℃; (b) CuO doped, 1475 ℃
    Rockwell hardness of samples after sintering at different temperatures for 5 h
    Fig. 13. Rockwell hardness of samples after sintering at different temperatures for 5 h
    Fracture toughness of samples after sintering at different temperatures for 5 h
    Fig. 14. Fracture toughness of samples after sintering at different temperatures for 5 h
    Rockwell hardness and fracture toughness of YAG ceramics doped with 2% CuO
    Fig. 15. Rockwell hardness and fracture toughness of YAG ceramics doped with 2% CuO
    Rockwell hardness and fracture toughness of YAG ceramic doped with 2% CuO-TiO2
    Fig. 16. Rockwell hardness and fracture toughness of YAG ceramic doped with 2% CuO-TiO2
    MaterialSizePhysical parameter
    YAG∶Ce3+ phosphor powder particlesRadius: 1.5 μmn=2.1, α=0.82 mm-1
    TEOS coating-layerInner radius: 1.5 μmExternal radius: 1.6 μmn=1.6, α=0 mm-1
    Light source0.5 μm×0.5 μm×0.5 μmPower: 1 W, wavelength: 200 nm
    Spherical receiverInner radius: 3.6 μmExternal radius: 4.0 μmInner surface: perfect absorption
    Table 1. Model size parameters and physical properties of TEOS-coated YAG∶Ce3+ phosphor powder particles[29-32]
    TreatmentmodeParticle sized(0.5) /μmSinteringtemperate T /℃Linearshrinkage Ls /%Densityρ /(g·cm-3)Relativedensity /%
    Original particles22.305165012.3%4.1391.7
    Ball milling 24 h15.604165013.7%4.2193.5
    Grinding 2 h+ball milling 24 h3.182162514.6%4.3194.8
    Table 2. Particle size and sintering properties of powder
    Xiaotong Xie, Haitao Zhu, He Liu, Qinjiang He, Renli Fu. Low-Temperature Sintering and Properties of Ceramics Fabricated from YAG∶Ce 3+ Phosphor Powder [J]. Laser & Optoelectronics Progress, 2018, 55(11): 111602
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