• Chinese Optics Letters
  • Vol. 18, Issue 11, 111402 (2020)
Yuwei Fang1, Junjie Cheng2, Shengbo Wang1, Chun Gu1, Gang Zou2, Hai Ming1, and Lixin Xu1、*
Author Affiliations
  • 1Department of Optics and Optical Engineering, University of Science and Technology of China, Hefei 230026, China
  • 2CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, iChEM, University of Science and Technology of China, Hefei 230026, China
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    DOI: 10.3788/COL202018.111402 Cite this Article Set citation alerts
    Yuwei Fang, Junjie Cheng, Shengbo Wang, Chun Gu, Gang Zou, Hai Ming, Lixin Xu. Design and analysis of a range-extended acidity detector based on a Nile red laser with tandem cuvette system[J]. Chinese Optics Letters, 2020, 18(11): 111402 Copy Citation Text show less
    Experimental setup. A potassium titanyl phosphate (KTP) crystal served as a frequency doubling crystal; the cavity mirror had high transmission (HT) at 532 nm (HT=90%) and high reflectance (HR) in the range of 560 nm to 700 nm (HR=90%); the output coupler had partial transmission (R=85%) from 400 nm to 700 nm.
    Fig. 1. Experimental setup. A potassium titanyl phosphate (KTP) crystal served as a frequency doubling crystal; the cavity mirror had high transmission (HT) at 532 nm (HT=90%) and high reflectance (HR) in the range of 560 nm to 700 nm (HR=90%); the output coupler had partial transmission (R=85%) from 400 nm to 700 nm.
    (a) Laser/FL spectrum. (b) Slope efficiency curve and FWHM of the output spectrum. (c) Oscilloscope trace of output laser. (d) Spectra of output laser in 60 μg/mL NR/ethanol solution containing SA in different concentrations. (e) Spectra of output laser in 200 μg/mL NR/ethanol solution containing SA in different concentrations.
    Fig. 2. (a) Laser/FL spectrum. (b) Slope efficiency curve and FWHM of the output spectrum. (c) Oscilloscope trace of output laser. (d) Spectra of output laser in 60 μg/mL NR/ethanol solution containing SA in different concentrations. (e) Spectra of output laser in 200 μg/mL NR/ethanol solution containing SA in different concentrations.
    Bathochromic shift of laser wavelength corresponding to different concentrations of doped SA.
    Fig. 3. Bathochromic shift of laser wavelength corresponding to different concentrations of doped SA.
    (a) Tandem cuvette detection system of SA. Inset figure: details of tandem cuvette structure containing R6G/ethanol and NR/ethanol with SA. (b) Spectra of output laser in tandem cuvette system with high concentration of SA from 0 ppm to 500 ppm. The laser peak at 565 nm was in the spectrum of R6G/ethanol. (c) Spectra of output laser in tandem cuvette system with low concentration of SA from 1 ppm to 10 ppm. The laser peak at 565 nm was in the spectrum of R6G/ethanol.
    Fig. 4. (a) Tandem cuvette detection system of SA. Inset figure: details of tandem cuvette structure containing R6G/ethanol and NR/ethanol with SA. (b) Spectra of output laser in tandem cuvette system with high concentration of SA from 0 ppm to 500 ppm. The laser peak at 565 nm was in the spectrum of R6G/ethanol. (c) Spectra of output laser in tandem cuvette system with low concentration of SA from 1 ppm to 10 ppm. The laser peak at 565 nm was in the spectrum of R6G/ethanol.
    SolventEthanolDMFAcetoneChloroformEthyl AcetateEther
    Relative polaritya0.6540.3860.3550.2590.2280.117
    Fluorescence peak (nm)634616607602593584
    Table 1. FL Spectra of Nile Red in Different Solvents
    Concentration of SA (ppm)0102050100200500
    Wavelength (nm)652.94658.88663.07668.93673.83677.48678.85
    Table 2. Wavelength of Laser Output in 60 μg/mL NR/Ethanol Solution Corresponding to Different SA Concentrations
    Concentration of SA (ppm)0102050100200500
    Wavelength (nm)653.82666.16669.85675.20679.15679.16679.15
    Table 3. Wavelength of Laser Output in 200 μg/mL NR/Ethanol Solution Corresponding to Different SA Concentrations
    Concentration of SA (ppm)01258102050100200500
    Intensity ratio of dual-wavelength (normalized)00.1020.1430.8511.3904.630NANANANANA
    Wavelength (nm)636.0636.0/648.5636.1/649.2636.3/654.2636.6/654.5636.0/654.8660.1666.5671.2675.5676.0
    Table 4. Intensity Ratio of Dual-wavelength Laser and Wavelength Position Corresponding to Different Concentration of SA in Tandem Cuvette System
    Yuwei Fang, Junjie Cheng, Shengbo Wang, Chun Gu, Gang Zou, Hai Ming, Lixin Xu. Design and analysis of a range-extended acidity detector based on a Nile red laser with tandem cuvette system[J]. Chinese Optics Letters, 2020, 18(11): 111402
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