Coptidis plays an important role in the field of traditional Chinese medicine. However, it is easily polluted by heavy metals in environment (water and soil), and thus can affect human health. In order to detect the heavy metal elements Cu and Pb in Coptidis, which was purchased from the Chinese herbal medicine market in Chongqing, the reheated double-pulse laser-induced breakdown spectroscopy (RDP-LIBS) is investigated. In order to reduce the experimental error caused by the irregular shape, it is necessary to pretreat the Coptidis samples prior to the determination step. The Coptidis samples are dried, milled, and sieved to form thin cylindrical tablets each with a diameter of 13 mm and thickness of 2 mm, which are formed under a mechanical press of 10 MPa for 2 min. The influences of the main experimental parameters, such as double-pulse LIBS detection delay, double-pulse LIBS laser energy, and double-pulse LIBS pulse interval are optimized. According to the LIBS signal intensity and signal-to-background ratio, the optimal laser energy set of the characteristic line Cu I (324.46 nm) covers E₁ = 15 mJ and E₂ = 35 mJ, and the pulse interval and detection delay time are 1.4 μs and 1.5 μs respectively; the laser energy set of Pb I (405.78 nm) also covers E₁ = 15 mJ and E₂ = 35 mJ, and the pulse interval and detection delay time are 1.6 μs and 1.7 μs, respectively. Comparing with the scenarios of single-pulse laser-induced breakdown spectroscopy, it can be seen that the spectral intensity of Cu I (324.46 nm) increases from 5779 counts to 12749 counts, i.e. it increases about 2.2 times; the spectral intensity of Pb I (405.78 nm) characteristic line increases from 4703 counts to 15838 counts, i.e. it increases about 3.3 times. It is shown that the second laser pulse re-excites the plasma which is generated by the first laser pulse, thus making the plasma emission spectrum stronger. The detection performances of heavy metal elements in Chinese medicinal materials are evaluated by RDP-LIBS and SP-LIBS. The results show that the detection limit of Cu decreases from 5.13 mg/kg to 1.91 mg/kg, and the detection limit of Pb decreases from 10.87 mg/kg to 3.03 mg/kg. There was observed a noticeable difference in the limit of detection between Cu and Pb, which meets the requirements of the Green Industry Standard for Import and Export of Medicinal Plants. Moreover, the linear curve fitting degree of RDP-LIBS is higher than that of SP-LIBS, which indicates that the RDP-LIBS technology has better detection performance in Chinese herbal medicine.