• Acta Physica Sinica
  • Vol. 69, Issue 1, 014210-1 (2020)
Gui-Hua Sun*, Qing-Li Zhang, Jian-Qiao Luo, Dun-Lu Sun, Chang-Jiang Gu, Li-Li Zheng, Song Han, and Wei-Min Li
DOI: 10.7498/aps.69.20191150 Cite this Article
Gui-Hua Sun, Qing-Li Zhang, Jian-Qiao Luo, Dun-Lu Sun, Chang-Jiang Gu, Li-Li Zheng, Song Han, Wei-Min Li. Growth and characterization of Ti:MgAl2O4 laser crystal by Czochralski method [J]. Acta Physica Sinica, 2020, 69(1): 014210-1 Copy Citation Text show less
As-grown Ti:MgAl2O4 crystal with the size of Ø30 mm × 70 mm.尺寸为Ø30 mm × 70 mm的Ti:MgAl2O4晶体
Fig. 1. As-grown Ti:MgAl2O4 crystal with the size of Ø30 mm × 70 mm. 尺寸为Ø30 mm × 70 mm的Ti:MgAl2O4晶体
X-ray diffraction patterns of the as-grown Ti:MgAl2O4 crystal and MgAl2O4 standard patterns (JCPDS, no. 77-0435).Ti:MgAl2O4晶体的粉末衍射图和MgAl2O4晶体的标准谱图(JCPDS, no. 77-0435)
Fig. 2. X-ray diffraction patterns of the as-grown Ti:MgAl2O4 crystal and MgAl2O4 standard patterns (JCPDS, no. 77-0435). Ti:MgAl2O4晶体的粉末衍射图和MgAl2O4晶体的标准谱图(JCPDS, no. 77-0435)
X-ray rocking curve of (100) plane of the as-grown Ti:MgAl2O4 crystal.Ti:MgAl2O4晶体(100)面的摇摆曲线
Fig. 3. X-ray rocking curve of (100) plane of the as-grown Ti:MgAl2O4 crystal. Ti:MgAl2O4晶体(100)面的摇摆曲线
Raman spectra of the as-grown Ti:MgAl2O4 crystal.Ti:MgAl2O4晶体的拉曼谱图
Fig. 4. Raman spectra of the as-grown Ti:MgAl2O4 crystal. Ti:MgAl2O4晶体的拉曼谱图
Transmittance spectra of the as-grown Ti:MgAl2O4 crystal before and after annealing in the range of 250−1200 nm.退火前后Ti:MgAl2O4晶体在250−1200 nm范围内的透过光谱
Fig. 5. Transmittance spectra of the as-grown Ti:MgAl2O4 crystal before and after annealing in the range of 250−1200 nm. 退火前后Ti:MgAl2O4晶体在250−1200 nm范围内的透过光谱
Emission spectra of the as-grown Ti:MgAl2O4 crystal before and after annealing excited by 271 nm at room temperature.退火前后Ti:MgAl2O4晶体在271 nm波长激发下的室温荧光发射光谱
Fig. 6. Emission spectra of the as-grown Ti:MgAl2O4 crystal before and after annealing excited by 271 nm at room temperature. 退火前后Ti:MgAl2O4晶体在271 nm波长激发下的室温荧光发射光谱
ESR spectrum of the as-grown Ti:MgAl2O4 crystal before and after annealing at 130 K.Ti:MgAl2O4晶体在130 K时的ESR谱
Fig. 7. ESR spectrum of the as-grown Ti:MgAl2O4 crystal before and after annealing at 130 K. Ti:MgAl2O4晶体在130 K时的ESR谱
Excitation spectra of the as-grown Ti:MgAl2O4 crystal before and after annealing with 480 nm as monitoring.退火前后Ti:MgAl2O4晶体480 nm发射的激发光谱
Fig. 8. Excitation spectra of the as-grown Ti:MgAl2O4 crystal before and after annealing with 480 nm as monitoring. 退火前后Ti:MgAl2O4晶体480 nm发射的激发光谱
Emission decay curve of the as-grown Ti:MgAl2O4 crystal at room temperature.室温下Ti:MgAl2O4晶体的荧光衰减曲线
Fig. 9. Emission decay curve of the as-grown Ti:MgAl2O4 crystal at room temperature. 室温下Ti:MgAl2O4晶体的荧光衰减曲线
不同的MgAl2O4振动模式/cm–1
F2g(1) EgF2g(2) A1g
Natural Cr:MgAl2O4 crystal[13]312407667769
MgAl2O4 crystal[14]311410671772
MgAl2O4 ceramic[15]312407666767
Natural Cr, V:MgAl2O4 crystal[16]305405663770
Non-stoichiometric MgAl2O4 powder[17]306406670766
MgAl2O4 polycrystalline [18]311407667767
Table 1.

Raman vibration peaks of several different MgAl2O4.

几种不同的MgAl2O4的拉曼振动峰

Gui-Hua Sun, Qing-Li Zhang, Jian-Qiao Luo, Dun-Lu Sun, Chang-Jiang Gu, Li-Li Zheng, Song Han, Wei-Min Li. Growth and characterization of Ti:MgAl2O4 laser crystal by Czochralski method [J]. Acta Physica Sinica, 2020, 69(1): 014210-1
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