• Chinese Optics Letters
  • Vol. 16, Issue 6, 060201 (2018)
Yingyu Niu* and Rong Wang
Author Affiliations
  • School of Science, Dalian Jiaotong University, Dalian 116028, China
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    DOI: 10.3788/COL201816.060201 Cite this Article Set citation alerts
    Yingyu Niu, Rong Wang. Photoassociation reaction of OH molecules through reverse ladder transition[J]. Chinese Optics Letters, 2018, 16(6): 060201 Copy Citation Text show less

    Abstract

    Photoassociation via reverse ladder transition controlled by two and four laser pulses is investigated using the time-dependent quantum wave packet method. The calculated results show that the amplitudes of the pulses have an enormous effect on the target population and total yield of association. For the target state with a high energy level, the population of background states can reduce the state-selectivity. Although, the total yield of association is decreased, the four pulses can induce the population transferring to low vibrational levels, and the state-selectivity of the target state is high.
    itΨ(R,θ,t)=(H^mol+H^int)Ψ(R,θ,t),(1)

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    H^mol=22m2R222mR21sinθθ(sinθθ)+V^,(2)

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    H^int=ε(t)cosθμ(R),(3)

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    ε(t)=iEisin2[π(tti)τi]cos[ωi(tti)],(4)

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    continuumstateω1|16,1ω1{|13,0|13,2}ω1|11,1ω2|9,0.(5)

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    continuumstateω1|16,1ω1{|13,0|13,2}ω1|11,1ω2{|9,0|9,2}ω2|7,1ω3{|5,0|5,2}ω3|3,1ω4{|2,0|2,2}ω4|1,1ω4|0,0.(6)

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    Yingyu Niu, Rong Wang. Photoassociation reaction of OH molecules through reverse ladder transition[J]. Chinese Optics Letters, 2018, 16(6): 060201
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