The chemical composition of copper slag reduction tailings is similar to that of CaOAl2O3SiO2 glassceramics. The preparation of glassceramics with copper slag reduction tailings as the main raw material by melting method provides an effective way for the efficient utilization of copper slag. The effects of different additives (B2O3, CaF2, TiO2 and Cr2O3) on the phase composition, flexural strength, bulk density, water absorption and apparent porosity of glassceramics were studied by DSC, XRD and SEMEDS. The experimental results show that no matter which additive is added, the glassceramics precipitate anorthite and gehlenite with good mechanical properties, and the crystal crystallization mode transforms into overall crystallization. Adding B2O3 makes the best performance of glassceramics, followed by TiO2 and CaF2.