The time evolution properties of photon distribution in the interaction of entangled double atoms and coherent field are studied by means of numerical calculation.The results show that the coherent field which has not photon anti-bunching and photon sub-Poisson distribution can gain these non-classical properties through the interaction with the entangled double atoms.And it is found that with the intensifying of entangle between initial state non-classical properties of photon distribution will increase corresponding,which indicates that non-classical light emission can be generated from the interaction of given entangled double atoms.