Compared with discrete variable quantum key distribution (DVQKD), continuous variable (CV) QKD has high security bit rate and other advantages, which, however, are slightly insufficient in secure transmission distance. In addition, the application of quantum catalysis has significantly improved the performance of Gaussian modulated (GM) CVQKD, especially in secure transmission distance. Recently, the application of quantum catalysis has significantly improved the performance of GM-CVQKD. However, whether it can be used to improve the performance of discrete modulated (DM) CVQKD protocol is still ambiguous. Therefore, a scheme of DM CVQKD protocol based on quantum catalysis is proposed in this paper to further improve the performance of the proposed protocol in terms of secure key rate, secure transmission distance and maximum tolerable noise. Our results show that under the same parameters, when the transmittance T introduced by quantum catalysis is optimized, the proposed scheme can effectively further improve the performance of QKD system compared with the original four-state modulation CVQKD scheme. In particular, when the tolerable excess noise is 0.002, the use of quantum catalysis can break the safe communication distance of 300 km with a key rate of 10^–8 bits/pulse. However, if this noise is too large, the improvement in the effect of quantum catalysis on protocol performance will be restrained. In addition, in order to highlight the advantages of the use of quantum catalysis, the ultimate limit PLOB (Pirandola-Laurenza-Ottaviani-Banchi) bound of point-to-point quantum communication is given in this paper. The simulation results indicate that although neither the original scheme nor the proposed scheme can break the bound, compared with the former, the latter can be close to the boundary in long-distance transmission. These results provide theoretical basis for achieving the ultimate goal of global quantum security communication.