• Optics and Precision Engineering
  • Vol. 32, Issue 24, 3537 (2024)
Xiangge LI1, Mai HU2, Tongyu ZHU1, Yong LIU1, and Liangquan JIA1,*
Author Affiliations
  • 1Electrical Engineering, Huzhou University, Huzhou33000, China
  • 2Anhui Institute of Optics and Fine Mechanics, Hefei Institute of Physical Science, Chinese Academy of Sciences, Hefei30031, China
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    DOI: 10.37188/OPE.20243224.3537 Cite this Article
    Xiangge LI, Mai HU, Tongyu ZHU, Yong LIU, Liangquan JIA. Research on high sensitivity methane detection technology in coal mines based on frequency modulation[J]. Optics and Precision Engineering, 2024, 32(24): 3537 Copy Citation Text show less

    Abstract

    To meet the needs of monitoring CH4 gas concentration in coal mines and gas fields, a frequency modulated spectral system based on near-infrared distributed feedback lasers was built for rapid measurement of high concentration methane. The system obtained the optimal modulation frequency range and the optimal signal-to-noise ratio of the absorption component through simulation optimization and experimentation. When the modulation frequency is 353 MHz, the power is 25.08 mW, and the effective optical path is 0.6 m, a CH4 absorption spectral line of 6 046.83 cm-1 is selected to achieve 1 Hz CH4 gas concentration detection. The amplitude of the frequency modulation absorption component signal has a linear relationship with concentration, with a linearity error of 2.88% and a linear fitting coefficient R2 of 0.997 4. For standard CH4 gas with a volume fraction of 2%, the relative error is less than 1.3‰. When the integration time is 1 s, the Allen variance is 4.032 1 ppmv. When the integration time is 347 s, the Allen variance is 0.222 8 ppmv, and the detection sensitivity is 2.28 × 10-7, which meets the measurement requirements for high-speed and highly sensitive CH4 gas. The experimental results indicate that frequency modulation spectroscopy technology has broad application prospects in low detection limit and high sensitivity gas sensing.
    E1(t)=E0eiωct(1)

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    E2(t)=E0n=-+Jn(M)ei(ωc+nωm)t(2)

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    E0[J0(M)eiωct+J1(M)ei(ωc+ωm)t-(3)

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    J1(M)ei(ωc-ωm)t](2)

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    E3(t)=E0[J0(M)T0eiωct+J1(M)T1ei(ωc+ωm)t-(5)

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    J1(M)T-1ei(ωc-ωm)t](3)

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    I3(t)=cE3(t)28π=(7)

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    c8π|E0[J0(M)T0eiωct+J1(M)T1eiωc+ωmt-(8)

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    J1(M)T-1eiωc-ωmt]|2=(9)

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    cE028π{[J02T0T0*+J12T1T1*+J12T-1T-1*]+(10)

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    2Re[J0J1(T0T1*-T0*T-1)e-iωmt]-(11)

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    2Re[J12T1*T-1e-i2ωmt]}(4)

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    I3(t)=cE028π{[J02e-2δ0+J12e-2δ1+J12e-2δ-1]+(13)

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    2J0J1e-2δ0[(δ-1-δ1)cos ωmt+(14)

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    (ϕ1+ϕ-1-2ϕ0)sin ωmt](5)

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    IFM-mix(ω)=cE02Ame-2δ08π[1+J1(δ-1-δ1)cos φ+(16)

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    J1(ϕ1+ϕ-1-2ϕ0)sin φ](6)

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    IFM(ω)=I0e-2δ0γM(δ-1-δ1)(7)

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    QFM(ω)=-I0e-2δ0γM(ϕ1+ϕ-1-2ϕ0)(8)

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    -Δδ=δ-1-δ1(9)

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    Δϕ=ϕ1+ϕ-1-2ϕ0(10)

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    ϕV(ν)=2aπΔνDln 2π-+exp(-y2)a2+(w-y)2dy(11)

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    ΔνD=ν08kT ln2mc27.162 3×10-7ν0TM(12)

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    ΔνC=PjXj2γi-j(T)γi-j(T)=γi-j(T0)T0Tnj(13)

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    ϕV(ν)=2aπΔνDln 2πRe[K(w,a)](14)

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    K(w,a)=i=0pαixixp+1+i=0pβixi,x=a-iw(15)

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    ΔνV=0.534 6ΔνC+(0.216 6ΔνC2+ΔνD2)0.5(16)

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    Δδ(ν)=2aπΔνDln 2πRe[K(w|ν0=ωc+ωm,a)]-(28)

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    Re[K(w|ν0=ωc-ωm,a)](17)

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    ax2+bx+c=0(18)

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    minxF(x,xdata)-ydata22=(31)

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    minxi(F(x, xdatai)-ydatai)2(19)

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    Xiangge LI, Mai HU, Tongyu ZHU, Yong LIU, Liangquan JIA. Research on high sensitivity methane detection technology in coal mines based on frequency modulation[J]. Optics and Precision Engineering, 2024, 32(24): 3537
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