• NUCLEAR TECHNIQUES
  • Vol. 47, Issue 10, 100302 (2024)
Gang YANG1, Bingqi LIU1,*, Guoyi LU2, Yangchun LENG2, and Xianguo TUO3
Author Affiliations
  • 1Chengdu University, Chengdu 610106, China
  • 2Southwest Univercity of Science and Technology, Mianyang 621010, China
  • 3Chengdu University of Technology, Chengdu 610059, China
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    DOI: 10.11889/j.0253-3219.2024.hjs.47.100302 Cite this Article
    Gang YANG, Bingqi LIU, Guoyi LU, Yangchun LENG, Xianguo TUO. Research on the carbonization law of cement and its adsorption of 137Cs[J]. NUCLEAR TECHNIQUES, 2024, 47(10): 100302 Copy Citation Text show less
    XRD pattern of cement
    Fig. 1. XRD pattern of cement
    FT-IR pattern of cement
    Fig. 2. FT-IR pattern of cement
    SEM pattern of carbonized cement(a) Cement paste, (b) Carbonization for 28 d, (c) Carbonization for 1 d, (d) Carbonization for 3 d, (e) Carbonization for 7 d
    Fig. 3. SEM pattern of carbonized cement(a) Cement paste, (b) Carbonization for 28 d, (c) Carbonization for 1 d, (d) Carbonization for 3 d, (e) Carbonization for 7 d
    Adsorption-desorption and pore size distribution curve of carbonized cement(a) Cement paste, (b) Carbonization for 1 d, (c) Carbonization for 3 d, (d) Carbonization for 7 d, (e) Carbonization for 28 d
    Fig. 4. Adsorption-desorption and pore size distribution curve of carbonized cement(a) Cement paste, (b) Carbonization for 1 d, (c) Carbonization for 3 d, (d) Carbonization for 7 d, (e) Carbonization for 28 d
    TGA-DTG curve of carbonized cement(a) Cement paste, (b) Carbonization for 1 d, (c) Carbonization for 3 d, (d) Carbonization for 7 d, (e) Carbonization for 28 d
    Fig. 5. TGA-DTG curve of carbonized cement(a) Cement paste, (b) Carbonization for 1 d, (c) Carbonization for 3 d, (d) Carbonization for 7 d, (e) Carbonization for 28 d
    Effect of time on the adsorption of 137Cs on carbonized cement
    Fig. 6. Effect of time on the adsorption of 137Cs on carbonized cement
    Fitting curve of dynamic model of adsorption of 137Cs by carbonized cement(a) Quasi-first-order kinetic model, (b) Quasi-second-order kinetic model
    Fig. 7. Fitting curve of dynamic model of adsorption of 137Cs by carbonized cement(a) Quasi-first-order kinetic model, (b) Quasi-second-order kinetic model
    Langmuir isothermal model fitting curve of carbonized cement adsorption 137Cs(a) Cemrnt paste, (b) Carbonization cement
    Fig. 8. Langmuir isothermal model fitting curve of carbonized cement adsorption 137Cs(a) Cemrnt paste, (b) Carbonization cement
    Freundlich isothermal model fitting curve of carbonized cement adsorption 137Cs(a) Cemrnt paste, (b) Carbonization cement
    Fig. 9. Freundlich isothermal model fitting curve of carbonized cement adsorption 137Cs(a) Cemrnt paste, (b) Carbonization cement
    样品名称Sample name比表面积Specific surface area / m2∙g-1
    水泥净浆Cement paste10.687
    碳化1 d水泥Carbonize 1 d cement41.896
    碳化3 d水泥Carbonize 3 d cement49.336
    碳化7 d水泥Carbonize7 d cement51.482
    碳化28 d水泥Carbonize 28 d cement68.523
    Table 1. Specific surface area of cement before and after carbonization
    样品Sample准一级动力学模型Quasi-first-order kinetic model准二级动力学模型Quasi-second-order kinetic model
    Qe(cal) / Bq∙g-1Qe(exp) / Bq∙g-1k1 / h-1R2Qe(cal) / Bq∙g-1Qe(exp) / Bq∙g-1k2 / g∙Bq-1∙h-1R2
    水泥净浆Cement paste10.2291.430.2220.85092.5191.430.0510.999
    碳化1 d Carbonize 1 d12.12199.860.2930.993200.80199.860.0750.999
    碳化3 d Carbonize 3 d7.07204.370.2330.989204.91204.370.1070.999
    碳化7 d Carbonize 7 d8.92197.990.1790.781198.81197.990.0590.999
    碳化28 d Carbonize 28 d23.06195.170.3040.958196.46195.170.0360.999
    Table 2. Kinetic model parameters of adsorption of 137Cs by carbonated cement
    样品名称SampleLangmuir吸附等温模型Langmuir adsorption isothermal modelFreundlich吸附等温模型Freundlich adsorption isothermal model
    Qm / Bq∙g-1KL / L∙Bq-1R2KF / Bq1-n∙Ln∙g-1nR2
    水泥净浆Cement paste148.810.0020.9690.6431.3430.703
    碳化1 d Carbonize 1 d925.930.0030.9843.2871.1880.611
    碳化3 d Carbonize 3 d699.300.0060.98123.6932.2580.469
    碳化7 d Carbonize 7 d653.590.0040.9967.5941.5920.791
    碳化28 d Carbonize 28 d636.940.0030.9993.9261.3970.662
    Table 3. Isothermal model parameters of adsorption of 137Cs by carbonated cement
    Gang YANG, Bingqi LIU, Guoyi LU, Yangchun LENG, Xianguo TUO. Research on the carbonization law of cement and its adsorption of 137Cs[J]. NUCLEAR TECHNIQUES, 2024, 47(10): 100302
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