• Acta Photonica Sinica
  • Vol. 51, Issue 3, 0316002 (2022)
Dongbao LIANG, Rui ZHANG*, Yufang SHEN, and Jian ZHANG
Author Affiliations
  • Key Laboratory of Nonferrous Materials and New Processing Technology,Ministry of Education,Guangxi Key Laboratory of Optical and Electronic Materials and Devices,College of Materials Science and Engineering,Guilin University of Technology,Guilin ,Guangxi 541004,China
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    DOI: 10.3788/gzxb20225103.0316002 Cite this Article
    Dongbao LIANG, Rui ZHANG, Yufang SHEN, Jian ZHANG. Synthesis and Luminescent Properties of BaLaGa3O7:Bi3+ Phosphors[J]. Acta Photonica Sinica, 2022, 51(3): 0316002 Copy Citation Text show less
    XRD patterns of BaLa1-xGa3O7:xBi3+(0.01≤x≤0.13)samples and schematic of crystal structure of BaLaGa3O7
    Fig. 1. XRD patterns of BaLa1-xGa3O7xBi3+(0.01≤x≤0.13)samples and schematic of crystal structure of BaLaGa3O7
    SEM image and corresponding elemental mappings of BaLa0.89Ga3O7:0.11Bi3+ sample
    Fig. 2. SEM image and corresponding elemental mappings of BaLa0.89Ga3O7:0.11Bi3+ sample
    Diffuse reflectance spectra of BaLaGa3O7 host and BaLa0.89Ga3O7:0.11Bi3+ sample
    Fig. 3. Diffuse reflectance spectra of BaLaGa3O7 host and BaLa0.89Ga3O7:0.11Bi3+ sample
    Fluorescence spectra of BaLa1-xGa3O7:xBi3+ (0.01≤x≤0.13)samples and schematic energy level diagram of Bi3+ ions
    Fig. 4. Fluorescence spectra of BaLa1-xGa3O7xBi3+ (0.01≤x≤0.13)samples and schematic energy level diagram of Bi3+ ions
    Relationship between log(I/x)and log(x)for BaLa1-xGa3O7:xBi3+(0.01≤x≤0.13)samples
    Fig. 5. Relationship between log(I/x)and log(x)for BaLa1-xGa3O7xBi3+(0.01≤x≤0.13)samples
    Decay curves of BaLa1-xGa3O7:xBi3+(0.01≤x≤0.13)samples and corresponding fluorescence lifetime
    Fig. 6. Decay curves of BaLa1-xGa3O7xBi3+(0.01≤x≤0.13)samples and corresponding fluorescence lifetime
    Quantum yield of BaLa0.89Ga3O7:0.11Bi3+ sample
    Fig. 7. Quantum yield of BaLa0.89Ga3O7:0.11Bi3+ sample
    Temperature-dependent PL spectra of BaLa0.89Ga3O7:0.11Bi3+ sample
    Fig. 8. Temperature-dependent PL spectra of BaLa0.89Ga3O7:0.11Bi3+ sample
    FormulaBaLa0.89Ga3O7:0.11Bi3+
    Space groupP-421m
    a=b8.165 6(6)
    c/Å5.402 4(1)
    V/Å3360.219 4(8)
    Z2
    Rwp/%5.49
    Rp/%6.18
    χ27.37
    Table 1. Main parameters of Rietveld refinement of the BaLa0.89Ga3O7:0.11Bi3+ sample
    Sampleλex /nmλem /nmPL Intensity at 423 KReference
    Cs3Zn6B9O21:Bi3+322436100%6
    NaGd9(SiO4)6O2:Bi3+34046576%7
    Ca3Lu2Ge3O12:Bi3+38047775%8
    Ba2Ga2GeO7:Bi3+36549735%9
    Ca2MgWO6:Bi3+34055033%10
    K2MgGeO4:Bi3+33561485%22
    BaLaGa3O7:Bi3+34847569%This work
    Table 2. Luminescence properties of some phosphors activated with Bi3+
    Dongbao LIANG, Rui ZHANG, Yufang SHEN, Jian ZHANG. Synthesis and Luminescent Properties of BaLaGa3O7:Bi3+ Phosphors[J]. Acta Photonica Sinica, 2022, 51(3): 0316002
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