A theoretical calculation is presented for third-harmonic generation in KDP crystal for type Ⅱ- type Ⅱ polarization-mismatch scheme by using the four-stepped Runge-Kutta method. For the “Shenguang Ⅱ” frequency tripling system, the doubling angle θd and the tripling angle θt are located at optimized situation, by changing detuned values of the polarization angle θp, the corresponding changes of pulse shape properties was gotten. The results show that when the polarization angle θp is located at optimized situation, the full width at half maximum (FWHM) τ is minimum and the pulse shape rises fastest. Increasing the θp from optimized situation causes the τ widens faster and the pulse shape rises slower than decreasing the θp from optimized situation. In the experiment, by changing the polarization angle θp, the pulse shapes consistency of the “Shenguang Ⅱ” eight frequency tripling beams has been accomplished. This work offers a method for adjusting crystals and actualizing power balance.