[2] Li S Y. Ionothermal synthesis and fluorescence property of a complex constructed by seven nuclear ［(CH3COO)2Co7(OH)2］.clusters and 4,4’-Oxybisbenzoic acid ligand［J］.Chin J Struct Chem,2016,35(6):980-986.

[3] Evans O R, Lin W B. Crystal engineering of NLO materials based on metalorganic coordination networks［J］.Acc Chem Res, 2002,35:511-522.

[4] Zhai Q G, Bu X H, Mao C Y, et al. Systematic and dramatic tuning on gas sorption performance in heterometallic metal-organic frameworks［J］.J Am Chem Soc,2016,138:2524-2527.

[5] Rao P C, Chaudhary S P, Kuznetsov D, et al. Transformation of one-dimensional achiral structure to three dimensional chiral structure: Mechanistic study and catalytic activities of chiral structure［J］.Inorg.Chem.2016,55: 12669-12674.

[6] Morris R E. Ionothermal synthesis-ionic liquids as functional solvents in the preparation of crystalline materials［J］.Chem Commun,2009,2:2990-2998.

[7] Huo Q S, Margolese D I, Ciesla U, et al. Organization of organic molecules with inorganic molecular species into nanocomposite biphase arrays［J］.Chem Mater,1994,6(8):1176-1191.

[8] Bala R, Kaur A, Kashyap M, et al. Second-sphere coordination in anion binding: Synthesis, characterization and X-ray structures of bis (diethylenetriamine) cobalt (III) complexes containing benzoates［J］.J Mol Struct,2014,1063:203-212.

[9] Wakako K, Akio M, Hisayoshi O, et al. Highly symmetric 3D ferrimagnets, ［Mn(dien)］3［M(CN)6］2?2H2O (M=Cr, Mn; dien= diethylenetriamine):synthesis, structures and magnetic properties［J］.Polyhedron,2013,64:122-127.

[10] Liu Z H, Zhang J J, Zhang W J, et al. Crystal structure of bis (diethytenetriamine) cobalt (II) tetrahydroxypentaborate ［Co(C4H13N3)2］［B5O6(OH)4］2［J］.Z Kristallogr NCS,2005,220:555-556.

[11] Zhou X T, Hockless C R, Willis A C, et al. Oxidative condensation reactions of (diethylenetriamine) cobalt (III) complexes with substituted bis (pyridin-2-yl) methane ligands[J].J Mol Struct,2005,740:91-100.

[12] Jiang Y C, Wang S L, Li K H, Synthesis, crystal structure, magnetic susceptibility, and mossbauer spectroscopy of a mixed-valence organic inorganic hybrid compound:(H3DETA)［Fe3(C2O4)2(HPO4)2(PO4)］(DETA=Diethylenetriamine)［J］.Chem Mater,2003,15:1633-1638.

[15] Sheldrick G M. SHELXS 97, Program for X-ray Crystal Structure Solution ［P］.University of Gttingrn,Germany 1997．

[16] Sheldrick G M. SHELXS 97, Program for X-ray Crystal Structure Refinement ［P］.University of Gttingrn,Germany 1997．

[18] Cui Y, Yue Y, Qian G, et al. Luminescent functional metal-organic frameworks［J］.Chem Rev,2012,112:1126-1162.