Compliant Iontronic Triboelectric Gels with Phase-Locked Structure Enabled by Competitive Hydrogen Bonding

Guoli Du; Yuzheng Shao; Bin Luo; Tao Liu; Jiamin Zhao; Ying Qin; Jinlong Wang; Song Zhang; Mingchao Chi; Cong Gao; Yanhua Liu; Chenchen Cai; Shuangfei Wang; Shuangxi Nie

doi:10.1007/s40820-024-01387-4

[1] Y. Jiang, S. Ji, J. Sun, J. Huang, Y. Li et al., A universal interface for plug-and-play assembly of stretchable devices. Nature 614, 456–462 (2023).

[2] Y. Huang, J. Zhou, P. Ke, X. Guo, C.K. Yiu et al., A skin-integrated multimodal haptic interface for immersive tactile feedback. Nat. Electron. 6, 1020–1031 (2023).

[3] X. Meng, C. Cai, B. Luo, T. Liu, Y. Shao et al., Rational design of cellulosic triboelectric materials for self-powered wearable electronics. Nano-Micro Lett. 15, 124 (2023).

[4] T. Jin, Z. Sun, L. Li, Q. Zhang, M. Zhu et al., Triboelectric nanogenerator sensors for soft robotics aiming at digital twin applications. Nat. Commun. 11, 5381 (2020).

[5] Y. Shao, G. Du, B. Luo, T. Liu, J. Zhao et al., A tough monolithic-integrated triboelectric bioplastic enabled by dynamic covalent chemistry. Adv. Mater. (2024).

[6] C. Gao, W. Zhang, T. Liu, B. Luo, C. Cai et al., Hierarchical porous triboelectric aerogels enabled by heterointerface engineering. Nano Energy 121, 109223 (2024).

[7] X. Wang, Y. Zhang, X. Zhang, Z. Huo, X. Li et al., A highly stretchable transparent self-powered triboelectric tactile sensor with metallized nanofibers for wearable electronics. Adv. Mater. 30, e1706738 (2018).

[8] P. Zhang, W. Guo, Z.H. Guo, Y. Ma, L. Gao et al., Dynamically crosslinked dry ion-conducting elastomers for soft iontronics. Adv. Mater. 33, e2101396 (2021).

[9] J. Zhao, W. Zhang, T. Liu, B. Luo, Y. Qin et al., Multiscale structural triboelectric aerogels enabled by self-assembly driven supramolecular winding. Adv. Funct. Mater. (2024).

[10] H.C. Ates, P.Q. Nguyen, L. Gonzalez-Macia, E. Morales-Narváez, F. Güder et al., End-to-end design of wearable sensors. Nat. Rev. Mater. 7, 887–907 (2022).

[11] S. Chen, L. Sun, X. Zhou, Y. Guo, J. Song et al., Mechanically and biologically skin-like elastomers for bio-integrated electronics. Nat. Commun. 11, 1107 (2020).

[12] Z. Yan, D. Xu, Z. Lin, P. Wang, B. Cao et al., Highly stretchable van der Waals thin films for adaptable and breathable electronic membranes. Science 375, 852–859 (2022).

[13] S. Wang, Y. Fang, H. He, L. Zhang, C.-A. Li et al., Wearable stretchable dry and self-adhesive strain sensors with conformal contact to skin for high-quality motion monitoring. Adv. Funct. Mater. 31, 2007495 (2021).

[14] Z. Li, P. Zhang, Y. Shao, Z.-H. Guo, X. Pu, Stretchable iontronics with robust interface bonding between dielectric and ion-conducting elastomers. Nano Res. 16, 11862–11870 (2023).

[15] J. Min, J. Tu, C. Xu, H. Lukas, S. Shin et al., Skin-interfaced wearable sweat sensors for precision medicine. Chem. Rev. 123, 5049–5138 (2023).

[16] D. Choi, Y. Lee, Z.-H. Lin, S. Cho, M. Kim et al., Recent advances in triboelectric nanogenerators: from technological progress to commercial applications. ACS Nano 17, 11087–11219 (2023).

[17] H.L. Wang, Z.H. Guo, X. Pu, Z.L. Wang, Ultralight iontronic triboelectric mechanoreceptor with high specific outputs for epidermal electronics. Nano-Micro Lett. 14, 86 (2022).

[18] Y. Qin, J. Mo, Y. Liu, S. Zhang, J. Wang et al., Stretchable triboelectric self-powered sweat sensor fabricated from self-healing nanocellulose hydrogels. Adv. Funct. Mater. 32, 2201846 (2022).

[19] M. Ilami, H. Bagheri, R. Ahmed, E.O. Skowronek, H. Marvi, Materials, actuators, and sensors for soft bioinspired robots. Adv. Mater. 33, e2003139 (2021).

[20] L. Li, J. Wang, K. Yang, Z.H. Guo, J. Zhang et al., A recyclable, adhesive and fast self-healable ionic conducting elastomer based on a poly-zwitterionic liquid for soft iontronics. J. Mater. Chem. A 10, 24581–24589 (2022).

[21] L. Zhang, S. Wang, Z. Wang, Z. Liu, X. Xu et al., Temperature-mediated phase separation enables strong yet reversible mechanical and adhesive hydrogels. ACS Nano 17, 13948–13960 (2023).

[22] B. Luo, C. Cai, T. Liu, X. Meng, X. Zhuang et al., Multiscale structural nanocellulosic triboelectric aerogels induced by hofmeister effect. Adv. Funct. Mater. 33, 2306810 (2023).

[23] F. Chen, X. Li, Y. Yu, Q. Li, H. Lin et al., Phase-separation facilitated one-step fabrication of multiscale heterogeneous two-aqueous-phase gel. Nat. Commun. 14, 2793 (2023).

[24] J. Chen, Y. Gao, L. Shi, W. Yu, Z. Sun et al., Phase-locked constructing dynamic supramolecular ionic conductive elastomers with superior toughness, autonomous self-healing and recyclability. Nat. Commun. 13, 4868 (2022).

[25] M. Zhang, R. Yu, X. Tao, Y. He, X. Li et al., Mechanically robust and highly conductive ionogels for soft ionotronics. Adv. Funct. Mater. 33, 2208083 (2023).

[26] B. Bao, Q. Zeng, K. Li, J. Wen, Y. Zhang et al., Rapid fabrication of physically robust hydrogels. Nat. Mater. 22, 1253–1260 (2023).

[27] J. Wang, Y. Zheng, T. Cui, T. Huang, H. Liu et al., Bioinspired ultra-robust ionogels constructed with soft-rigid confinement space for multimodal monitoring electronics. Adv. Funct. Mater. 34, 2312383 (2024).

[28] H. Xiang, X. Li, B. Wu, S. Sun, P. Wu, Highly damping and self-healable ionic elastomer from dynamic phase separation of sticky fluorinated polymers. Adv. Mater. 35, e2209581 (2023).

[29] M. Wang, P. Zhang, M. Shamsi, J.L. Thelen, W. Qian et al., Tough and stretchable ionogels by in situ phase separation. Nat. Mater. 21, 359–365 (2022).

[30] J. Wu, Z. Zhang, Z. Wu, D. Liu, X. Yang et al., Strong and ultra-tough supramolecular hydrogel enabled by strain-induced microphase separation. Adv. Funct. Mater. 33, 2210395 (2023).

[31] H. Wan, B. Wu, L. Hou, P. Wu, Amphibious polymer materials with high strength and superb toughness in various aquatic and atmospheric environments. Adv. Mater. 36, e2307290 (2024).

[32] A.N. Annaidh, K. Bruyère, M. Destrade, M.D. Gilchrist, M. Otténio, Characterization of the anisotropic mechanical properties of excised human skin. J. Mech. Behav. Biomed. Mater. 5, 139–148 (2012).

[33] A. Pissarenko, M.A. Meyers, The materials science of skin: analysis, characterization, and modeling. Prog. Mater. Sci. 110, 100634 (2020).

[34] D. Zhao, B. Pang, Y. Zhu, W. Cheng, K. Cao et al., A stiffness-switchable, biomimetic smart material enabled by supramolecular reconfiguration. Adv. Mater. 34, e2107857 (2022).

[35] X. Liang, S.A. Boppart, Biomechanical properties of in vivo human skin from dynamic optical coherence elastography. IEEE Trans. Biomed. Eng. 57, 953–959 (2010).

[36] G. Balakrishnan, J. Song, C. Mou, C.J. Bettinger, Recent progress in materials chemistry to advance flexible bioelectronics in medicine. Adv. Mater. 34, e2106787 (2022).

[37] X. Li, S. Xiang, D. Ling, S. Zhang, C. Li et al., Stretchable, self-healing, transparent macromolecular elastomeric gel and PAM/carrageenan hydrogel for self-powered touch sensors. Mater. Sci. Eng. B 283, 115832 (2022).

[38] S. Li, G. Liu, H. Wen, G. Liu, H. Wang et al., A skin-like pressure- and vibration-sensitive tactile sensor based on polyacrylamide/silk fibroin elastomer. Adv. Funct. Mater. 32, 2111747 (2022).

[39] J. Jiang, Q. Guan, Y. Liu, X. Sun, Z. Wen, Abrasion and fracture self-healable triboelectric nanogenerator with ultrahigh stretchability and long-term durability. Adv. Funct. Mater. 31, 2105380 (2021).

[40] Y. Guo, S. Chen, L. Sun, L. Yang, L. Zhang et al., Degradable and fully recyclable dynamic thermoset elastomer for 3D-printed wearable electronics. Adv. Funct. Mater. 31, 2009799 (2021).

[41] Y. Hishikawa, E. Togawa, T. Kondo, Characterization of individual hydrogen bonds in crystalline regenerated cellulose using resolved polarized FTIR spectra. ACS Omega 2, 1469–1476 (2017).

[42] S. Zhu, Y. Wu, Q. Chen, Z. Yu, C. Wang et al., Dissolution of cellulose with ionic liquids and its application: a mini-review. Green Chem. 8, 325–327 (2006).

[43] R. Guo, Q. Zhang, Y. Wu, H. Chen, Y. Liu et al., Extremely strong and tough biodegradable poly(urethane) elastomers with unprecedented crack tolerance via hierarchical hydrogen-bonding interactions. Adv. Mater. 35, e2212130 (2023).

[44] L. Chen, C. Zhao, J. Huang, J. Zhou, M. Liu, Enormous-stiffness-changing polymer networks by glass transition mediated microphase separation. Nat. Commun. 13, 6821 (2022).

[45] Y. Lai, X. Kuang, P. Zhu, M. Huang, X. Dong et al., Colorless, transparent, robust, and fast scratch-self-healing elastomers via a phase-locked dynamic bonds design. Adv. Mater. 30, e1802556 (2018).

[46] A.-L. Esquirol, P. Sarazin, N. Virgilio, Tunable porous hydrogels from cocontinuous polymer blends. Macromolecules 47, 3068–3075 (2014).

[47] G. Ge, K. Mandal, R. Haghniaz, M. Li, X. Xiao et al., Deep eutectic solvents-based ionogels with ultrafast gelation and high adhesion in harsh environments. Adv. Funct. Mater. 33, 2207388 (2023).

[48] D. Zhao, Y. Zhu, W. Cheng, G. Xu, Q. Wang et al., A dynamic gel with reversible and tunable topological networks and performances. Matter 2, 390–403 (2020).

[49] C. Zhang, Z. Wang, H. Zhu, Q. Zhang, S. Zhu, Dielectric gels with microphase separation for wide-range and self-damping pressure sensing. Adv. Mater. 36, e2308520 (2024).

[50] E. Ducrot, Y. Chen, M. Bulters, R.P. Sijbesma, C. Creton, Toughening elastomers with sacrificial bonds and watching them break. Science 344, 186–189 (2014).

[51] K. Sato, T. Nakajima, T. Hisamatsu, T. Nonoyama, T. Kurokawa et al., Phase-separation-induced anomalous stiffening, toughening, and self-healing of polyacrylamide gels. Adv. Mater. 27, 6990–6998 (2015).

[52] Y. Wang, Y. Liu, N. Hu, P. Shi, C. Zhang et al., Highly stretchable and self-healable ionogels with multiple sensitivity towards compression, strain and moisture for skin-inspired ionic sensors. Sci. China Mater. 65, 2252–2261 (2022).

[53] V.R. Feig, H. Tran, M. Lee, Z. Bao, Mechanically tunable conductive interpenetrating network hydrogels that mimic the elastic moduli of biological tissue. Nat. Commun. 9, 2740 (2018).

[54] K.-X. Hou, S.-P. Zhao, D.-P. Wang, P.-C. Zhao, C.-H. Li et al., A puncture-resistant and self-healing conductive gel for multifunctional electronic skin. Adv. Funct. Mater. 31, 2107006 (2021).

[55] L. Cai, J. Fan, S. Ding, D. He, X. Zeng et al., Soft composite gels with high toughness and low thermal resistance through lengthening polymer strands and controlling filler. Adv. Funct. Mater. 33, 2207143 (2023).

[56] M. Zammali, S. Liu, W. Yu, A biomimetic skin-like sensor with multiple sensory capabilities based on hybrid ionogel. Sens. Actuat. A Phys. 330, 112855 (2021).

[57] E.K. Boahen, B. Pan, H. Kweon, J.S. Kim, H. Choi et al., Ultrafast, autonomous self-healable iontronic skin exhibiting piezo-ionic dynamics. Nat. Commun. 13, 7699 (2022).

[58] G. Du, J. Wang, Y. Liu, J. Yuan, T. Liu et al., Fabrication of advanced cellulosic triboelectric materials via dielectric modulation. Adv. Sci. 10, e2206243 (2023).

[59] D. Lu, T. Liu, X. Meng, B. Luo, J. Yuan et al., Wearable triboelectric visual sensors for tactile perception. Adv. Mater. 35, e2209117 (2023).

[60] Z. Huang, X. Chen, S.J.K. O’Neill, G. Wu, D.J. Whitaker et al., Highly compressible glass-like supramolecular polymer networks. Nat. Mater. 21, 103–109 (2022).

[61] X. Qu, Z. Liu, P. Tan, C. Wang, Y. Liu et al., Artificial tactile perception smart finger for material identification based on triboelectric sensing. Sci. Adv. 8, eabq2521 (2022).

[62] J. Wang, Y. Liu, T. Liu, S. Zhang, Z. Wei et al., Dynamic thermostable cellulosic triboelectric materials from multilevel-non-covalent interactions. Small (2023).

微信扫一扫：分享

微信扫一扫：分享