• Chinese Journal of Lasers
  • Vol. 51, Issue 10, 1002313 (2024)
Jiali Gao1, Xu Wang1, Yunbo Hao2, Zhiqiang Wang1, and Kai Zhao2、*
Author Affiliations
  • 1College of Mechanical Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
  • 2Shanghai Aerospace Equipments Manufacturer Co., Ltd., Shanghai 200245, China
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    DOI: 10.3788/CJL240435 Cite this Article Set citation alerts
    Jiali Gao, Xu Wang, Yunbo Hao, Zhiqiang Wang, Kai Zhao. In-Situ Gradient Additive Forming and Interfacial Microstructure Evolution of Ti6Al4V/NiTi Heterogeneous Functional Material (Invited)[J]. Chinese Journal of Lasers, 2024, 51(10): 1002313 Copy Citation Text show less
    Transport diagram of heterogeneous alloy powder, as well as morphology and particle size distributions of two kinds of powders. (a) Schematic diagram of synchronous delivery of heterogeneous alloy powder; (b) micro-morphology of Ti6Al4V powder; (c) particle size distribution of Ti6Al4V powder; (d) micro-morphology of Ni55.5Ti44.5 powder; (e) particle size distribution of Ni55.5Ti44.5 powder
    Fig. 1. Transport diagram of heterogeneous alloy powder, as well as morphology and particle size distributions of two kinds of powders. (a) Schematic diagram of synchronous delivery of heterogeneous alloy powder; (b) micro-morphology of Ti6Al4V powder; (c) particle size distribution of Ti6Al4V powder; (d) micro-morphology of Ni55.5Ti44.5 powder; (e) particle size distribution of Ni55.5Ti44.5 powder
    Gradient compositional design of Ti6Al4V/NiTi heterogeneous alloy prepared by in-situ additive manufacturing
    Fig. 2. Gradient compositional design of Ti6Al4V/NiTi heterogeneous alloy prepared by in-situ additive manufacturing
    XRD spectra and macroscopic morphology of Ti6Al4V/NiTi composites thin-walled samples with 11 compositional ratios. (a) XRD spectra; (b) macroscopic morphology
    Fig. 3. XRD spectra and macroscopic morphology of Ti6Al4V/NiTi composites thin-walled samples with 11 compositional ratios. (a) XRD spectra; (b) macroscopic morphology
    Microstructures of Ti6Al4V/NiTi composites thin-walled samples with different composition ratios
    Fig. 4. Microstructures of Ti6Al4V/NiTi composites thin-walled samples with different composition ratios
    Elemental mass fraction changing of Ti6Al4V/NiTi thin-walled samples with different composition ratios
    Fig. 5. Elemental mass fraction changing of Ti6Al4V/NiTi thin-walled samples with different composition ratios
    In-situ gradient additive manufacturing of Ti6Al4V/NiTi heterogeneous functional materials. (a) Macroscopic morphology of formed part; (b) planer surface and partial enlargement of gradient transition zone of formed sample
    Fig. 6. In-situ gradient additive manufacturing of Ti6Al4V/NiTi heterogeneous functional materials. (a) Macroscopic morphology of formed part; (b) planer surface and partial enlargement of gradient transition zone of formed sample
    EDS line scan results near Ti6Al4V/NiTi gradient alloy interfaces. (a) Interfaces 1 and 2; (b) interface 3; (c) interface 4; (d) interface 5
    Fig. 7. EDS line scan results near Ti6Al4V/NiTi gradient alloy interfaces. (a) Interfaces 1 and 2; (b) interface 3; (c) interface 4; (d) interface 5
    Schematic diagram of microhardness measurement points and distribution of measurement results for Ti6Al4V/NiTi gradient alloy. (a) Schematic diagram of sampling measurement points; (b) distribution of microhardness measurement results
    Fig. 8. Schematic diagram of microhardness measurement points and distribution of measurement results for Ti6Al4V/NiTi gradient alloy. (a) Schematic diagram of sampling measurement points; (b) distribution of microhardness measurement results
    No.Ingredient ratio (mass fraction)P /WS /(mm/s)F /(g/min)

    FTi6Al4V /

    (g/min)

    FNiTi /

    (g/min)

    Interlayerlift /mmNumber ofprint layersSubstrate
    1100%Ti6Al4V12928.795.195.190.5618Ti6Al4V
    290%Ti6Al4V+10%NiTi12928.795.585.020.560.5318Ti6Al4V
    380%Ti6Al4V+20%NiTi12928.796.034.821.210.5418Ti6Al4V
    470%Ti6Al4V+30%NiTi12928.796.554.591.970.5618Ti6Al4V
    560%Ti6Al4V+40%NiTi12928.797.184.312.870.6116Ti6Al4V
    650%Ti6Al4V+50%NiTi12928.797.933.973.970.7514NiTi
    740%Ti6Al4V+60%NiTi12928.798.873.555.320.7812NiTi
    830%Ti6Al4V+70%NiTi12928.7910.053.027.040.7912NiTi
    920%Ti6Al4V+80%NiTi12928.7911.602.329.280.8512NiTi
    1010%Ti6Al4V+90%NiTi12928.7913.721.3712.350.9610NiTi
    11100%NiTi12928.7916.7816.781.268NiTi
    Table 1. Process parameters corresponding to different composition ratios
    SEM morphologyPositionAtomic fraction /%Possible phase
    TiNiAlV
    Region A46.352.41.00.3
    Point A147.451.80.50.3NiTi+Ni3Ti
    Point A246.752.80.30.2NiTi+Ni3Ti
    Region B48.350.80.70.2
    Point B148.151.00.50.4NiTi
    Region C49.549.40.80.3
    Point C155.542.01.31.2NiTi+NiTi2
    Region D53.544.71.00.8
    Point D153.743.91.50.9NiTi+NiTi2
    Region E54.543.11.31.1
    Point E153.943.91.30.8NiTi+NiTi2
    Region F262.134.81.81.3
    Point F261.535.32.01.2NiTi2
    Region F61.035.82.11.1
    Point F160.636.22.01.2NiTi2
    Region G61.235.62.21.1
    Point G161.735.71.61.0NiTi2
    Region H83.88.84.72.7
    Point H182.99.34.43.5α-Ti+NiTi2
    Region I90.70.15.24.0
    Point I191.005.33.7α-Ti+β-Ti
    Table 2. SEM observation and EDS analysis of Ti6Al4V/NiTi gradient alloy
    Jiali Gao, Xu Wang, Yunbo Hao, Zhiqiang Wang, Kai Zhao. In-Situ Gradient Additive Forming and Interfacial Microstructure Evolution of Ti6Al4V/NiTi Heterogeneous Functional Material (Invited)[J]. Chinese Journal of Lasers, 2024, 51(10): 1002313
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