Titanium dioxide-double-walled carbon nanotubes (TiO2-DWCNTs) with DWCNTs/TiO2 of 20 wt.% is prepared by a conventional sol-gel method. Doping the TiO2-DWCNTs in TiO2 photoanode, a flexible dyesensitized solar cell (DSSC) is fabricated. The sample is characterized by scanning electron microscopy, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) absorption, ultraviolet-visible spectroscopy (UVvis) absorption spectra，electrochemical impedance spectroscopy (EIS) technique and photovoltaic measurement. It is found that adding a certain amount of TiO2-DWCNTs can efficiently decrease the resistance of charge transport, improve dye adsorption. Under an optimal condition, a flexible DSSC contained with 0.50 wt.% TiO2-DWCNTs achieves a light-to-electric energy conversion efficiency of 3.89% under a simulate solar light irradiation of 100mW.cm-2.