Fig. 1. Intermetallic compounds with lanthanides or actinides form the majority of heavy fermion materials.重费米子材料大多是含有镧系或锕系元素的金属间化合物
Fig. 2. (a) A schematic illustration of the crystal structure of CeCu
2Si
2; (b) and (c) evidences for superconductivity in CeCu
2Si
2 from resistivity and heat capacity, respectively
[3]; (d) temperature-pressure phase diagram of CeCu
2Si
2 and CeCu
2(Si
1–xGe
x)
2, suggesting two separate superconducting domes
[8].
(a) CeCu
2Si
2结构示意图; (b), (c)超导电性在电阻和比热上的体现
[3]; (d) 压力诱导的双超导相
[8] Fig. 3. (a) Schematic illustrations of crystalline structures in Ce
nMmIn
3n+2m(
M = Co, Rh, Ir;
n,
m are integers) (
M = Rh for example); (b) a schematic pressure-temperature phase diagram of CeIn
3 and CeRhIn
5[24].
(a) Ce
nMmIn
3n+2m(
M = Co, Rh, Ir;
n,
m为整数)体系的晶体结构 (以
M = Rh为例); (b) CeIn
3和CeRhIn
5的压力-温度相图示意图
[24] Fig. 4. (a) Magnetic field (
B)-temperature (
T) phase diagram of YbRh
2Si
2 and YbRh
2(Si
0.95Ge
0.05)
2[43]; (b)
B-
T phase diagram of YbRh
2Si
2 at lower temperature, suggesting a superconducting region
[47].
(a) YbRh
2Si
2和YbRh
2(Si
0.95Ge
0.05)
2的
B-T相图
[43]; (b) 极低温下的YbRh
2Si
2的
B-T相图
[47] Fig. 5. (a), (b) Schematic illustrations of the crystalline structure of UBe
13 and UPt
3, respectively; (c) superconducting phase diagram of UBe
13 as a function of Th-doping
[53]; (d) magnetic field–temperature superconducting phase diagram of UPt
3[58].
(a) UBe
13结构示意图; (b) UPt
3结构示意图; (c) Th掺杂的UBe
13相图
[53]; (d) UPt
3的超导相图
[58] Fig. 6. Temperature dependence of the magnetic penetration depth Δ
λ[10] (a) and specific heat
Ce/
T[11](b) of CeCu
2Si
2, both showing a fully gapped behavior at the lowest temperature.
重费米子超导体CeCu
2Si
2的(a)磁场穿透深度Δ
λ[10]和(b)低温比热系数
Ce/
T[11], 两者在低温都呈指数衰减
Fig. 7. Heavy fermion superconductors and quantum phase diagrams: (a) CePd
2Si
2, superconductivity (SC) near an antiferromagnetic quantum critical point(QCP)
[19]; (b) UCoGe, SC near a ferromagnetic QCP
[87]; (c) PrTi
2Al
20, SC coexists with multipolar order and gets enhanced near its QCP
[89]; (d) β-YbAlB
4, SC far away from an antiferromagnetic QCP
[90].
重费米子超导体超导相和量子相变 (a) CePd
2Si
2, 超导出现在反铁磁量子临界点附近
[19]; (b) UCoGe, 超导出现在铁磁量子相变附近
[87]; (c) PrTi
2Al
20, 超导与多极矩序
[89]; (d) β-YbAlB
4, 超导远离反铁磁量子临界点
[90] Fig. 8. Schematic phase diagrams for itinerant quantum critical point (QCP) (a) and local QCP (b), respectively, proposed in one theoretical model. The
x-axis denotes nonthermal tuning parameters
δ,
y-axis is the temperature
T.
TN is the antiferromagnetic ordering temperature,
denotes the volume change of Fermi surface and
T0 is the temperature regime where kondo lattice forms
[99].
巡游量子临界点(a)和局域量子临界点(b)的理论相图 图中的横坐标是非热力的调控参量
δ, 纵坐标表示温度
T, 调控参量
δ可以调节RKKY作用和Kondo作用的相对强度; 图(a)显示量子临界点伴随近藤效应的塌陷, 导致费米面在此发生跳变; 而在图(b)中, 近藤效应发生在反铁磁态内部, 费米面在量子临界点连续变化;
TN代表反铁磁转变温度,
TFL表示费米液体的温度上限,
标记小费米面到大费米面的转变,
T0代表近藤晶格形成的过渡区间
[99] Fig. 9. Experimental phase diagram of CeRhIn
5 tuned by pressure
[100] (a) and magnetic field
[35] (b); (c) the proposed zero-temperature pressure-field global phase diagram
[35].
CeRhIn
5在(a)压力
[100]和(b) 磁场调制下的相图
[35]; (c) 可能的零温压力-磁场相图
[35] Fig. 10. (a) Temperature dependence of resistivity for a possible topological Kondo insulator SmB
6, where a clear plateau is observed at low temperature
[116]; (b) band inversion and surface Dirac cone of SmB
6, from band-structure calculation
[128].
(a) 拓扑近藤绝缘体SmB
6的电阻随温度变化测量结果
[116], 在低温, 电阻的上升趋势逐渐饱和, 形成一个平台; (b) 能带计算表明, SmB
6的能带结构中存在能带反转, 从而导致了表面狄拉克锥的出现
[128] Fig. 11. Topological properties of the low temperature heavy fermion state in YbPtBi
[133]: (a)
T3-behavior of the low temperature specific heat
Cp/
T in different fields; (b) topological Hall effect at low temperatures.
YbPtBi在低温重费米子态的拓扑性质
[133] (a) 电子比热
Cp正比于温度
T的三次方; (b) 拓扑霍尔效应
Fig. 12. (a) Pressure-temperature phase diagram of URu
2Si
2[146]; (b) magnetic field- temperature phase diagram of CePdAl
[150]; (c) Q-phase of CeCoIn
5, by neutron scattering measurements
[151].
(a) URu
2Si
2材料在压力下的相图
[146], 隐藏序相逐渐被抑制, 转变为反铁磁序, 同时超导相消失; (b) CePdAl材料的磁场-温度相图
[150], 在某一磁场区间内, 比热测量结果表明其熵出现极大增加; (c) CeCoIn
5中子散射结果表明其超导上临界磁场附近存在一个特殊的Q相
[151] 类型 | 化合物 | Tc/K
| γ/mJ·mol–1·K–2 | Hc2 (0)/T
| CeT2X2 | CeCu2Si2 | 0.64 | 1000 | 0.45//a | CeCu2Ge2 | 0.64 (10 GPa) | | 2//a | CePd2Si2 | 0.5 (2.7 GPa) | 65 | 0.7//a 1.3//c | CeAu2Si2 | 2.5 (22.5 GPa) | | | CeNi2Ge2 | 0.3 | 350 | | CeRh2Si2 | 0.35 (0.9 GPa) | 23 | | CeTX3 | CeRhSi3 | 1.05 (2.6 GPa) | 110 | 7 | CeIrSi3 | 1.59 (2.6 GPa) | 120 | 30 | CeNiGe3 | 0.48 (6.8 GPa) | 34 | 2 | CeCoGe3 | 0.7 (5.5 GPa) | 32 | 22 | CeIrGe3 | 1.6 (24 GPa) | 80 | 17 | CemTnIn3m+2n | CeIn3 | 0.25 (2.5 GPa) | 370 | 0.45 | CeCoIn5 | 2.3 | 300 | 11.6—11.9//a 4.95//c | CeRhIn5 | 1.9 (1.77 GPa) | 50 | 10.2//c | CeIrIn5 | 0.4 | 700 | 0.53 | CePt2In7 | 2.3 (3.1 GPa) | 340 | 15 | Ce2CoIn8 | 0.4 | 460 | | Ce2RhIn8 | 2.0 (2.3 GPa) | 400 | 5.36 | Ce2PdIn8 | 0.68 | 550 | | Ce3PdIn11 | 0.42 | 290 | 2.8 | 其他铈基 | CePt3Si
| 0.75 | 390 | 5 | CePd5Al2 | 0.57 (10.8 GPa) | 56 | 0.25 | 镨基 | PrOs4Sb12 | 1.85 | 500 | 2.3 | PrTi2Al20 | 0.2 | 100 | 0.006 | PrV2Al20 | 0.05 | 90 | 0.014 | 镱基 | YbRh2Si2 | 0.002 | | | β-YbAlB4 | 0.08 | 130 | 0.03 | 铀基 | UIr | 0.14 (2.6 GPa) | 48.5 | 0.026 | UGe2 | 0.7 (1.2 GPa) | 100 | 1.4 | UBe13 | 0.9 | 1000 | 9 | UPt3 | 0.55, 0.48 | 422 | 2.8//a | UCoGe | 0.66 | 55 | 5//a | URhGe | 0.25 | 160 | 2//a | UNi2Al3 | 1.0 | 120 | 1.6 | UPd2Al3 | 2.0 | 150 | 0.8 | URu2Si2 | 1.5 | 65.5 | 10 | 镎基 | NpPd5Al2 | 5.0 | 200 | 3.7//a | 钚基 | PuCoGa5 | 18.0 | 77 | 74 | PuCoIn5 | 2.5 | 200 | 32//a, 10//c | PuRhGa5 | 9 | 80-150 | 25//ab | PuRhIn5 | 1.7 | 350 | 23//ab |
|
Table 1. A summary of heavy fermion superconductors (Tc is superconducting transition temperature, γ is specific heat coefficient, Hc2(0) is the upper critical field).
重费米子超导材料(超导转变温度Tc, 比热系数γ, 上临界场Hc2(0))