The separation and removal of fission products and the recovery of carrier molten salt during nuclear fuel reprocessing in molten salt reactors reduces waste and facilitates useful substance recycling.

This study aims to separate and remove the rare earth (RE) fission products and recovery of carrier molten salts.

Firstly, high temperature precipitation reactions of rare earth (RE = Ce, Nd, Sm, Eu, Y, Yb) and thorium fluorides were studied in LiF-BeF₂ melt using sodium sulfide hydate (Na₂S·5H₂O) as the precipitant. Their removal ratios were subsequently compared under different conditions. Then, a combined precipitation distillation method was employed to further heat the precipitated mixed salt to 950 °C and distilled under vacuum conditions at a pressure of 10 Pa for 20 min. The content and removal ratio of rare earth Nd, as well as contents of oxygen and sulfur, in condensed collected salts were investigated after using above improved precipitation-distillation processing. Finally, further analysis of the composition of sediment was conducted using X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS) and Energy Dispersive Spectrometer (EDS).

The results demonstrate that RE removal ratios are less than 90% when the RE to precipitant ratio is 1:2 at 600 ℃ whilst the RE Nd content in the salt collected by condensation is reduced to 1.39×10^-4 g?g^-1, and its removal ratio is increased to 99.6% with further improved precipitation-distillation processing. Simultaneously, the oxygen and sulfur contents are 8.5×10^-5 g?g^-1 and 1.50×10^-4 g?g^-1, respectively. Analysis results of XRD, XPS and EDS indicate that the sediment mainly consists of RE sulfide and sulfur oxide.

This study confirms the feasibility of separating RE from waste salt using the sulfide precipitation method and that over 99% RE separation efficiency can be achieved using precipitation-distillation combined treatment. Therefore, this provides a reference method for purifying waste salt and realizing molten salt reuse.