• Chinese Journal of Lasers
  • Vol. 51, Issue 10, 1002304 (2024)
Yi Ma1 and Yingchun Guan1,2,*
Author Affiliations
  • 1School of Mechanical Engineering and Automation, Beihang University, Beijing 100083, China
  • 2National Engineering Laboratory of Additive Manufacturing for Large Metallic Components, Beihang University, Beijing 100191, China
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    DOI: 10.3788/CJL240428 Cite this Article Set citation alerts
    Yi Ma, Yingchun Guan. Research and Application Progress in Laser Additive Manufacturing of Heterogeneous Metals (Invited)[J]. Chinese Journal of Lasers, 2024, 51(10): 1002304 Copy Citation Text show less
    Aerospace applications of Cu/Ni heterogeneous metal systems. (a) GRCop-42(Cu-Cr-Nb)/HR-1(Fe-Ni-Cr) combustion chamber formed by LDED[39]; (b) Cu-based/Ni-based injector formed by LPBF[39]; (c) coupled thrust assembly formed by LDED[39]; (d) injector structure and heterogeneous alloy connecting interface[39]; (e) GRCop-42 combustion chamber formed by LPBF[40]; (f) nickel-based cooling nozzle formed by BP-DED[40]; (g) coupled bimetallic structure[40]; (h) C18150/Inconel 625 rocket nozzle formed by SLM+LDED[41]; (i) CuNi2SiCr/Inconel 625 rocket nozzle formed by LDED[41]; (j) Cu-based/Ni-based bimetallic heat exchanger formed by SLM[41]; (k) Cu-based/Ni-based bimetallic combustion chamber formed by SLM[42]
    Fig. 1. Aerospace applications of Cu/Ni heterogeneous metal systems. (a) GRCop-42(Cu-Cr-Nb)/HR-1(Fe-Ni-Cr) combustion chamber formed by LDED[39]; (b) Cu-based/Ni-based injector formed by LPBF[39]; (c) coupled thrust assembly formed by LDED[39]; (d) injector structure and heterogeneous alloy connecting interface[39]; (e) GRCop-42 combustion chamber formed by LPBF[40]; (f) nickel-based cooling nozzle formed by BP-DED[40]; (g) coupled bimetallic structure[40]; (h) C18150/Inconel 625 rocket nozzle formed by SLM+LDED[41]; (i) CuNi2SiCr/Inconel 625 rocket nozzle formed by LDED[41]; (j) Cu-based/Ni-based bimetallic heat exchanger formed by SLM[41]; (k) Cu-based/Ni-based bimetallic combustion chamber formed by SLM[42]
    Aerospace applications of Fe-based heterogeneous metal systems. (a) CW106C/1.2709 steel large caliber engine nozzle formed byLPBF[43]; (b) 316L/aluminum-based bronze rocket engine nozzle formed byLDED[44]; (c) IN718/SS316L heat exchanger formed bySLM[45]; (d) CuCrZr/316L heat exchanger formed bySLM[46]
    Fig. 2. Aerospace applications of Fe-based heterogeneous metal systems. (a) CW106C/1.2709 steel large caliber engine nozzle formed byLPBF[43]; (b) 316L/aluminum-based bronze rocket engine nozzle formed byLDED[44]; (c) IN718/SS316L heat exchanger formed bySLM[45]; (d) CuCrZr/316L heat exchanger formed bySLM[46]
    Aerospace applications of Ti-based heterogeneous metal systems. (a) Ti6Al4V/Nb coupled rocket nozzle component formed by LDED[47]; (b) Ti6Al4V/Ti48Al2Cr2Nb turbine blade disk formed by LDED[48]
    Fig. 3. Aerospace applications of Ti-based heterogeneous metal systems. (a) Ti6Al4V/Nb coupled rocket nozzle component formed by LDED[47]; (b) Ti6Al4V/Ti48Al2Cr2Nb turbine blade disk formed by LDED[48]
    LDED equipment for heterogeneous metal additive manufacturing. (a) Schematic of the working principle of LDED for heterogeneous metal additive manufacturing[56]; (b) dual hopper LDED system[57]; (c) LASERTEC 6600 additive-subtractive composite manufacturing equipment[58]; (d) schematic of LMD static powder mixer equipment[59]
    Fig. 4. LDED equipment for heterogeneous metal additive manufacturing. (a) Schematic of the working principle of LDED for heterogeneous metal additive manufacturing[56]; (b) dual hopper LDED system[57]; (c) LASERTEC 6600 additive-subtractive composite manufacturing equipment[58]; (d) schematic of LMD static powder mixer equipment[59]
    LPBF equipment for heterogeneous metal additive manufacturing. (a) Dual feeder LPBF equipment[60]; (b) zoning system for LPBF equipment[61]; (c) ultrasonic powder spreading device for LPBF[62]; (d) electrostatic powder spreading device for LPBF[44]; (e) blade-ultrasonic powder spreading equipment for LPBF[63]
    Fig. 5. LPBF equipment for heterogeneous metal additive manufacturing. (a) Dual feeder LPBF equipment[60]; (b) zoning system for LPBF equipment[61]; (c) ultrasonic powder spreading device for LPBF[62]; (d) electrostatic powder spreading device for LPBF[44]; (e) blade-ultrasonic powder spreading equipment for LPBF[63]
    Hybrid manufacturing cases. (a)(b)Schematic diagram of LMD-WAAM hybrid fabrication of IN625/SUS304L gradient material and macroscopic photographs of formed component[68]; (c) 17-4 PH/AISI 316L componentformed by LPBF-WAAM[69]; (d) LPBF-LDED equipment, and QCr0.8 copper alloy/S06 stainless steel heterometal connection through the intermediate layer In718[70]
    Fig. 6. Hybrid manufacturing cases. (a)(b)Schematic diagram of LMD-WAAM hybrid fabrication of IN625/SUS304L gradient material and macroscopic photographs of formed component[68]; (c) 17-4 PH/AISI 316L componentformed by LPBF-WAAM[69]; (d) LPBF-LDED equipment, and QCr0.8 copper alloy/S06 stainless steel heterometal connection through the intermediate layer In718[70]
    Factors affecting the quality of heterogeneous metal interfaces and solutions. (a1)(a2) Porosity/lack of fusion[74] and related solutions; (b1)(b2) cracks[75] and related solutions; (c1)(c2) harmful phases[38] and related solutions; (d1)(d2) residual stresses[76] and related solutions
    Fig. 7. Factors affecting the quality of heterogeneous metal interfaces and solutions. (a1)(a2) Porosity/lack of fusion[74] and related solutions; (b1)(b2) cracks[75] and related solutions; (c1)(c2) harmful phases[38] and related solutions; (d1)(d2) residual stresses[76] and related solutions
    Heterogeneous metal joining strategies and cases. (a) Schematic diagrams of the four types of joining strategies[77]; (b) LPBF direct joining of Cu10Sn/Ti6Al4V and its interface[19]; (c) finger-crossed 316L/CuSn10 interfacial structure and samples formed by SLM[81]; (d) bionic SS316L/IN625 interface structure formed by LDED[82]; (e) Ti6Al4V/SS316 stainless steel heterometal connection through the intermediate layer Cu10Sn using SLM[79]; (f) inconel 718/Ti64 heterometal connection through VC-Inconel 718-Ti64 combination bonding layer using LENS[80]; (g) martensitic stainless steel/austenitic stainless steel connection through gradient layer using LENS[78]
    Fig. 8. Heterogeneous metal joining strategies and cases. (a) Schematic diagrams of the four types of joining strategies[77]; (b) LPBF direct joining of Cu10Sn/Ti6Al4V and its interface[19]; (c) finger-crossed 316L/CuSn10 interfacial structure and samples formed by SLM[81]; (d) bionic SS316L/IN625 interface structure formed by LDED[82]; (e) Ti6Al4V/SS316 stainless steel heterometal connection through the intermediate layer Cu10Sn using SLM[79]; (f) inconel 718/Ti64 heterometal connection through VC-Inconel 718-Ti64 combination bonding layer using LENS[80]; (g) martensitic stainless steel/austenitic stainless steel connection through gradient layer using LENS[78]
    Influence of process parameters on the microstructure and properties of heterogeneous metal components. (a) Variation of the relative density of LMD-formed GH4169/K417G heterogeneous metal components with laser power[76]; (b) LMD parameter optimization strategy and IN625/304L heterogeneous metal components prepared under the optimal parameters[90]; (c) Ti6Al4V/AlSi10Mg heterogeneous metal interfaces formed by LPBF under different process parameters[30]; (d) NiTi/CuSn10 heterogeneous metal interfaces formed by SLM under different process parameters[12]
    Fig. 9. Influence of process parameters on the microstructure and properties of heterogeneous metal components. (a) Variation of the relative density of LMD-formed GH4169/K417G heterogeneous metal components with laser power[76]; (b) LMD parameter optimization strategy and IN625/304L heterogeneous metal components prepared under the optimal parameters[90]; (c) Ti6Al4V/AlSi10Mg heterogeneous metal interfaces formed by LPBF under different process parameters[30]; (d) NiTi/CuSn10 heterogeneous metal interfaces formed by SLM under different process parameters[12]
    Development and application of online monitoring technology for LAM preparation of heterogeneous metals. (a)(b) Schematic diagram of the integrated high-speed imaging device of the LMD equipment and high-speed imaging pictures of the Cu deposition process[99]; (c) LDED system with integrated monitoring and sensing device[100]; (d)(e) schematic diagram of the in-situ X-ray imaging device integrated into the LPBF system and the photos of the Inconel 718/316L forming process captured under different processing parameters[101]; (f) schematic diagram of integrated optical device for LDED systems[102]
    Fig. 10. Development and application of online monitoring technology for LAM preparation of heterogeneous metals. (a)(b) Schematic diagram of the integrated high-speed imaging device of the LMD equipment and high-speed imaging pictures of the Cu deposition process[99]; (c) LDED system with integrated monitoring and sensing device[100]; (d)(e) schematic diagram of the in-situ X-ray imaging device integrated into the LPBF system and the photos of the Inconel 718/316L forming process captured under different processing parameters[101]; (f) schematic diagram of integrated optical device for LDED systems[102]
    Development and application of simulation technique for LAM preparation of heterogeneous metals. (a) LDED modeling adaptive mesh and boundary conditions for thermal analysis[103]; (b) machine learning flowchart for SLM parameter optimization[104]; (c) simulation of powder bed temperature distribution with different gradient IN718 components during LPBF manufacturing of IN718/Ti6Al4V[105]; (d) simulation of deformation and stress distribution in LDED manufacturing of Cu/SS304L[83]
    Fig. 11. Development and application of simulation technique for LAM preparation of heterogeneous metals. (a) LDED modeling adaptive mesh and boundary conditions for thermal analysis[103]; (b) machine learning flowchart for SLM parameter optimization[104]; (c) simulation of powder bed temperature distribution with different gradient IN718 components during LPBF manufacturing of IN718/Ti6Al4V[105]; (d) simulation of deformation and stress distribution in LDED manufacturing of Cu/SS304L[83]
    Effect of pretreatment on microstructure and properties of heterogeneous metal components. (a)‒(c) Preheating process of LDED in the manufacture of Inconel 625/Ti6Al4V gradient materials and the comparison of the effect of forming samples with or without preheating[110]; (d)(e) comparison of microstructures of CuBe/H13 formed by LMD with or without preheating[111]; (f)‒(h) hardness, relative density, and microstructure of GH4169/K417G samples formed by LMD with or without preheating[76]
    Fig. 12. Effect of pretreatment on microstructure and properties of heterogeneous metal components. (a)‒(c) Preheating process of LDED in the manufacture of Inconel 625/Ti6Al4V gradient materials and the comparison of the effect of forming samples with or without preheating[110]; (d)(e) comparison of microstructures of CuBe/H13 formed by LMD with or without preheating[111]; (f)‒(h) hardness, relative density, and microstructure of GH4169/K417G samples formed by LMD with or without preheating[76]
    Effect of post-treatment on microstructure and properties of heterogeneous metal components. (a)(b) The effect of heat treatment on the microstructure and mechanical properties of LPBF-formed 316L/Inconel 718 components[112]; (c) the effect of heat treatment on the hardness of LPBF-formed maraging steel/Co-Cr-Mo alloy components[113]; (d) the effect of hot isostatic pressing on the microstructure and hardness of LPBF-formed Ti/Ti64 components[114]
    Fig. 13. Effect of post-treatment on microstructure and properties of heterogeneous metal components. (a)(b) The effect of heat treatment on the microstructure and mechanical properties of LPBF-formed 316L/Inconel 718 components[112]; (c) the effect of heat treatment on the hardness of LPBF-formed maraging steel/Co-Cr-Mo alloy components[113]; (d) the effect of hot isostatic pressing on the microstructure and hardness of LPBF-formed Ti/Ti64 components[114]
    Material systemMaterial propertyApplicationTypical heterogeneous metal system
    Cu/Ni

    Thermal conductivity/heat resistance/

    high strength

    Aerospace thrust components/integrated circuit

    Inconel 718/GRCop8411

    NiTi/CuSn1012

    Inconel 718/ CuCr0.813

    Cu/FeHigh stiffness/electrical conductivity/thermal conductivity/wear resistanceNuclear industry/power generation industry/automobile industry

    316L/CuSn1014

    316L/C5240015

    316L/CuCrZr16

    Cu/TiHeat resistance/high specific strengthAerospace heat exchanger

    Ti6Al4V/Cu17

    Ti6Al4V/CuNi2SiCr18

    Cu10Sn/Ti6Al4V19

    Cu/AlElectrical/thermal conductivity/low densityEnergy conduction/cooling device/solar collectorAlSi10Mg/C1840020
    Ni/FeHigh strength/corrosion resistance/oxidation resistanceGas turbine/power generation equipment/heat exchanger

    316 L/Inconel 71821

    316L/Inconel 62522

    SS420/Inconel 71823

    Ni/TiBiocompatibility/wear resistance/high specific strength/heat resistanceAerospace thermal protection system/orthopedic implants

    Inconel 718/Ti6Al4V24

    TC4/Inconel 62525

    NiTi/Ti6Al4V26

    Fe/TiHigh specific strength/corrosion resistanceAerospace engines/load-bearing componentsTi6Al4V/316L27
    Fe/AlHigh strength/corrosion resistance/lightweightAutomotive manufacturing/aerospace hydraulic systems/space launch systems

    316L/AlSi10Mg28

    316L/Al29

    Ti/AlLightweight/ductility and malleability/high strengthAerospace and automotive structural component

    Ti6Al4V/AlSi10Mg30

    AA2024/Ti6Al4V31

    Ti6Al4V/Al12Si32

    Co/TiBiocompatibility/high strengthMedical implantCoCrMo/Ti6Al4V33
    Co/NiCorrosion resistance/high strengthNuclear industry/petrochemical industry

    CoCrMo/Inconel 71834

    CoCrMo/Inconel 62535

    Co/FeHeat resistance/wear resistance/high toughnessMachining tools and mold manufacturingSS316L/CoCrMo36
    W/CuElectrical/thermal conductivity/resistance to plasma radiationIntegrated circuit radiator/electrode/nuclear industryCu10Sn/W37
    W/FeDuctility and malleability/resistance to plasma radiation/high strengthNuclear industryW/316L38
    Table 1. Typical heterogeneous metal systems and their properties and applications
    TechniqueAdvantageLimitationSolution
    LPBF

    1) High forming accuracy

    2) Higher quality of interface bonding

    1) Lower processing efficiency50

    2) Difficult to control the precise distribution of powder51

    3) Cross-contamination issue with powders52

    4) Intra-layer heterogeneous material composition connectivity is limited53

    1) Hybrid manufacturing

    2) Development of new powder spreading device

    3) Developing multi-beam and large-area equipment

    4) Upgrade of powder recycling unit

    LDED

    1) High degree of processing freedom

    2) Wide selection of raw materials

    3) High processing efficiency

    4) Good flexibility in powder feeding

    1) Lower forming accuracy54

    2) Intra-layer heterogeneous material composition connectivity is limited55

    1) Integration of additive and subtractive manufacturing processes

    2) Hybrid manufacturing

    3) Improvement of powder feeding and mixing device

    Table 2. Advantages, limitations, and solutions of traditional LPBF and LDED techniques in heterogeneous metal manufacturing
    Equipment Optimization StrategyTechniqueMaterialAdvantage/effectReference
    Blade-based dual powder recoaterLPBFNi/TiCracks and brittle phases exist at the interfacial joints; such technique is difficult to realize the deposition of heterogeneous materials in the same layer and are limited in the applicable material systems, with poor forming quality60
    Ultrasonic assisted powder spreadingLPBFW/316LHeterogeneous metals are well bonded; such technique has high powder layup accuracy and design freedom, but is very inefficient65
    Electrostatic powder spreadingLPBFSuch technique has a high degree of design freedom and powder feeding efficiency, but is prone to powder layer contamination problems63
    Blade + ultrasonic hybrid powder spreadingLPBF316L/Cu10SnGood metallurgical bonding of heterogeneous metals; such technique combines high precision and efficiency66
    Dual powder feederLDEDAISI 316L/ AISI H13Individual transportation of dissimilar powders and successful bonding of heterogeneous metals are realized57
    Static mixing deviceLDED316L/CuImproved powder mixing homogeneity for the preparation of functional gradient layers59
    Integration of additive and subtractive manufacturingLDEDImproved efficiency and precision of heterogeneous metal forming58
    Equipment improvementLPBF

    AISI 316L/

    Ni-based high-temperature alloy

    Preparation of intra-layer bimetallic samples realized61
    LPBFAISI 316L-18Ni (300)Preparation of intra-layer bimetallic samples realized67
    Table 3. Development and advantages of heterogeneous metal additive manufacturing equipment for LPBF and LDED
    Technology integration strategyMaterialAdvantage/effectReference
    LMD-WAAMSUS304L/IN625Combines the high efficiency of WAAM with the flexibility of LMD/Good metallurgical bonding of heterogeneous materials with high mechanical properties68
    LPBF-WAAM17-4 PH/ AISI 316LHybrid manufacturing facilitates the preparation of complex and large cross-section structures/Heterogeneous interfaces are well bonded and have high mechanical properties69
    LPBF-LDEDQCr0.8/In718/S06 stainless steelCombines the high precision of LPBF with the flexibility of LDED/Heterogeneous interfaces are well bonded and defect-free70
    WAAM-LDEDER70S6/Inconel 625Combines the high efficiency of WAAM with the flexibility of LDED/Heterogeneous interfaces are well bonded and have high mechanical properties71
    LPBF-LDEDSS316L/IN625Integration of LPBF for high forming accuracy and LDED for fast deposition/Good heterogeneous interface bonding72
    SLM-CS(cold spraying)Al/Ti6Al4VCS avoids defects associated with the melting process, SLM offers high forming accuracy/Better bonding at heterogeneous interfaces, and inhibits the generation of brittle phases73
    Table 4. Hybrid manufacturing processes for heterogeneous metals and their advantages
    Connection strategyMaterialTechniqueEffectReference
    Direct connectionCu10Sn/Ti6Al4VLPBFInterface delamination, bonding failure19
    Cu/SS 304LLDEDHigh residual stresses at the interface, poor bonding effect83
    Gradient layer connection

    Martensitic stainless steel/

    Austenitic stainless steel

    LENSGood metallurgical bonding, improved mechanical properties78
    316L/IN718LPBFGood metallurgical bonding, good mechanical properties84
    AISI 316L/Fe35MnLPBFGood metallurgical bonding, mechanical properties vary with composition gradation85
    316L/Inconel 625LDEDGood metallurgical bonding, uniform microstructure at the interface22
    Ti6Al4V/NiTiLDEDDefect-free interface structure and good mechanical properties86
    Intermediate layer connection

    316L/HOVADUR K220/

    Ti-6Al-4V

    SLMGood metallurgical bonding79
    Cu10Sn/316L/WLPBFGood metallurgical bonding37
    TC4/Cu/IN718LDEDInhibits the creation of defects, good interfacial bonding87
    IN625/Cu/TC4LDEDGood metallurgical bonding88
    Ti6Al4V/Cu/Al-Cu-MgLPBFGood metallurgical bonding, no visible defects89
    Compositional bond layer connection

    Inconel 718/VC mixture/

    Ti6Al4V

    LENSNo cracks in the interface, successful bonding80
    Interface shape design316L/CuSn10SLMGood metallurgical bonding, improved mechanical properties81
    316L/IN625LDEDGood bonding, improved mechanical properties82
    Table 5. Joining strategies and forming effects of heterogeneous metals
    MaterialTechnique

    Laser

    power /W

    Scanning speed /(mm/s)Scanning space / overlap rate

    Layer

    thickness /μm

    Powder

    feeding rate

    Reference
    Ti6Al4V/ AlSi10MgLPBF31022000.123030
    Ti6Al4V/Inconel 625LMD150060050%6.0 g/min91
    Ti6Al4V/Ti48Al2Cr2NbLMD190074.96 g/min92
    Ti6Al4V/NiTiSLM906000.093026
    Ti6Al4V/IN718SLM3007000.055093
    316L/Co-Cr-MoLENS8006.676.0 g/min36
    316L/IN718LPBF955000.0842584
    316L/Hastelloy XLPBF952000.0453094
    316L/IN718LDED1000750%1 r/min95
    316L/TC4LMD1400650%2.5 r/min96
    Inconel 718/316LLPBF3009000.083097
    Inconel 718/CoCrMoLPBF22570034
    Inconel 718/SS420LDED9001523
    Inconel 625/316LLENS335183.8 g/min98
    Inconel 625/304LLMD6001050%8 g/min90
    GH4169/K417GLMD528440%18.9 mm3/s76
    NiTi/CuSn10SLM1202500.083012
    Table 6. Optimization/processing parameters for classical heterogeneous material
    Monitor signalMaterialTechniqueMonitoring deviceAdvantage/effectReference
    Optical signalCu, Al, Steel/Ti alloyLMDHigh-speed camera (optical imaging)Real-time monitoring of the melt pool dynamics, powder status and solidification characteristics, which can be adjusted accordingly99
    Ti/NbLDEDSpectrum collection deviceHigh precision monitoring of chemical composition/process status/serious defects100
    Inconel 718/316LLPBFHigh-speed X-ray imaging deviceIt can realize real-time monitoring of microstructure and defect evolution as well as thermal behavior of molten pool, and can adjust the process accordingly101
    316 L/AlSi10MgLMDCollimating lens + optical fiber (spectral collection)The relationship of spectral intensity-gradient composition evolution can be established to realize composition control in manufacturing process102
    Acoustic signalTi/NbLDEDMicrophonesFor laser-material interaction monitoring with high acquisition rates but poor monitoring accuracy100
    Table 7. Monitoring techniques for laser additive manufacturing of heterogeneous metals
    Forecast contentMaterialTechniqueModel/methodAdvantage/effectReference
    Thermal behavior + residual stressIN718/Ti6Al4VLDEDSequential coupled thermo-mechanical modelThe predicted results are qualitatively in agreement with the experimental results / thermal response, solidification behavior and residual stress sources can be predicted103
    Cu/SS304LLDEDThermo-mechanical Finite Element ModelingAccurate prediction of temperature and residual stress distribution can be achieved83
    IN718/Cu10SnLPBFMesoscopic modeling based on the VOF methodThe behavior of molten pool and solidification trajectory can be predicted105
    316L/Inconel 718LDEDFinite element simulationHigh simulation accuracy for effective analysis of thermal behavior during the forming process106
    TC4/TC11LMDFinite element simulationThe temperature field trend, period and peak temperature calculated by the model are in good agreement with the experiment, which verifies the validity of the model107
    Process parametersAlSi10Mg/316LSLMGaussian process regression (MO-GPR) modelingProcess parameter optimization can be significantly shortened104
    Fe/NiLDEDMathematical models constructed based on MATLABCorrelating laser process parameters to composition states108
    316L/CuSLMMultivariate Gaussian process modelCan be used for parameter prediction under different gradient composition changes109
    Table 8. Simulation and modeling techniques for laser additive manufacturing of heterogeneous metals
    Processing methodMaterialTechniqueEffectReference
    Substrate preheatingInconel 625/Ti6Al4VLDEDOptimized microstructure and improved forming quality110
    CuBe/H13LMDInhibit the formation of defects and improve mechanical properties111
    GH4169/K417GLMDReduced residual stresses and increased relative density of samples76
    Heat treatment316L/Inconel 718LPBFModulation of microstructure distribution to improve mechanical properties112
    Maraging steel/Co-Cr-MoLPBFElimination of residual stresses, improvement of interface quality and toughness113
    In718/316LLDEDThe strength and toughness of the components are improved115
    Hot isostatic pressureTi/Ti64LPBFElimination of residual stresses and improvement of mechanical properties114
    Table 9. Pre- and post-treatments for laser additive manufacturing of heterogeneous metals
    Yi Ma, Yingchun Guan. Research and Application Progress in Laser Additive Manufacturing of Heterogeneous Metals (Invited)[J]. Chinese Journal of Lasers, 2024, 51(10): 1002304
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