• Journal of Inorganic Materials
  • Vol. 37, Issue 7, 773 (2022)
Shun ZOU1、2, Xiyun HE1、*, Xia ZENG1, Pingsun QIU1, Liang LING1, and Dazhi SUN2、*
Author Affiliations
  • 11. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 22. College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China
  • show less
    DOI: 10.15541/jim20210603 Cite this Article
    Shun ZOU, Xiyun HE, Xia ZENG, Pingsun QIU, Liang LING, Dazhi SUN. Microstructure and Properties of Bi-doped Yttrium Iron Garnet Magneto-optical Ceramics Prepared by Hot-pressing Sintering Process[J]. Journal of Inorganic Materials, 2022, 37(7): 773 Copy Citation Text show less

    Abstract

    Yttrium iron garnet (Y3Fe5O12, YIG) materials with excellent magnetic and magneto-optical performances have been widely used in various fields such as the microwave communication, laser technology and optical fiber communication. Ion doping is considered as an effective method to improve the magneto-optical performance of YIG materials. In this study, Bi3+ with appropriate ion radius were selected to modify YIG ceramics to improve the magneto-optical properties of the materials. A series of BixY3-xFe5O12 (x=0, 0.3, 0.6, 0.9) ceramics were prepared by the hot-pressing sintering process with the solid-state reaction. Phase structure, micro-morphology, infrared transmittance, magnetic and magneto-optical properties of the sintered BixY3-xFe5O12 (x=0, 0.3, 0.6, 0.9) ceramics were investigated. All sintered Bi3+-doped YIG ceramic samples exhibit the pure garnet phase structure with dense microstructure, and the grain size increases with Bi3+ doping. The infrared transmittance of the sample is good, but it decreases with the increase of Bi3+ doping content. The Faraday rotation angle of the YIG ceramic sample changes linearly with the Bi3+ content increase. When the Bi3+ content increases about 1% (in atom), Faraday rotation angle changes about -49.0 (°)/cm and -30.2 (°)/cm at 1064 nm and 1550 nm wavelengths, respectively. Faraday rotation angles of Bi0.6Y2.4Fe5O12 ceramic sample at wavelengths of 1064 nm and 1550 nm are -703.3 (°)/cm and -461.5 (°)/cm, respectively, which are much higher than that of the undoped YIG ceramics (277.6 (°)/cm and 172.0 (°)/cm, respectively). The magneto-optical performance of YIG ceramics is enhanced obviously by the Bi3+ doping.
    Shun ZOU, Xiyun HE, Xia ZENG, Pingsun QIU, Liang LING, Dazhi SUN. Microstructure and Properties of Bi-doped Yttrium Iron Garnet Magneto-optical Ceramics Prepared by Hot-pressing Sintering Process[J]. Journal of Inorganic Materials, 2022, 37(7): 773
    Download Citation