Magnetic Fe3O4@TiO2/ZnO catalysts were fabricated by loaded TiO2 and ZnO to magnetic Fe3O4@C nanoparticle fabricated by hydrothermal method. The morphology and structure of catalysts were characterized by scanning electron microscopy, infrared spectroscopy and UV-diffused reflectance spectrum. The diffused reflectance spectrum shows that the absorption edge of magnetic Fe3O4@TiO2/ZnO catalysts are red shifted, indicate that the catalysts absorb lights in the higher wavelength. And the increasing of energy gap, indicate that the hole-electron pairs have stronger redox capacity, and therefore they could more eficiently utilize lights for the photocatalytic purpose. The degradation of (Rhodamine B, RhB) for Fe3O4@TiO2/ZnO catalysts increase from 65.33% to 98.11% compared to magnetic Fe3O4@TiO2. The degradation of RhB for magnetic Fe3O4@TiO2/ZnO catalysts are still 92.05% after recycling 5 times. This indicates Fe3O4@TiO2/ZnO catalysts are easy to recycle and have good recycling stability.