Fig. 1. Schematic diagram about the position of a confined charge (q = ) relative to the polymer chain, d shows the distance between the charge and the right chain-end; the curve describes the distribution of the induced electric field E along the polymer chain with the case of d = 3 nm, where the minus sign means that the direction of the electric field is opposite to that of the chain. 受限正电荷 (电荷量为 )相对于聚合物链的位置, d为电荷与链右端点的距离; 曲线为d = 3 nm时电场强度沿分子链的分布, 负号表示电场的方向与分子链的正方向相反

Fig. 2. Time evolution about the lattice configuration of an exciton in a polymer chain driven by a nonuniform electric field with d = 3 nm, where the exciton is initially generated at a central position of n_c = 30. 激子在非均匀电场(d = 3 nm)驱动下沿聚合物链超快输运对应的晶格动力学演化, 其初始产生时的中心位置为n_c = 30

Fig. 3. Variation of the driving force F as a function of the time. The inset presents the polarized positive charges and negative charges in the exciton at the time t = 1000 fs. 非均匀电场诱导激子输运的驱动力F随时间的变化; 插图为t = 1000 fs时激子内极化的正电荷与负电荷的分布

Fig. 4. Time evolution of the exciton center n_c along the polymer chain driven by different nonuniform electric fields, which can be modulated by changing the value of d. 不同非均匀电场(通过改变d调控)驱动下激子中心位置n_c随时间的演化

Fig. 5. Schematic diagram of two coupled polymer chains with a linear interchain packing configuration, where d_n indicates the distance between the vertical-neighbor sites. 线性排列构型的耦合双分子链, d_n为分子链垂直最近邻格点间的距离

Fig. 6. Time evolution about the lattice configuration of an exciton in two coupled polymer chains driven by the nonuniform configuration field with a linear coefficient k = 0.03. 激子在线性链间构型场 (k = 0.03)驱动下在分子间扩展及沿分子链输运的晶格动力学演化, 激子初始产生在第1条分子链上, 中心位置为n_c = 30

Fig. 7. Distribution of the driving force F along polymer chains driven by a linear configuration with k = 0.03. The inset presents the dependence of the exciton creation energy upon the interchain distance d_n. 线性构型场(k = 0.03)诱导的激子驱动力F沿分子链的分布, 插图为激子产生能 随链间距离d_n的变化

Fig. 8. Time evolution of the exciton center n_c along polymer chains driven by different configuration fields, which can be modulated by changing the value of k. 不同线性分子排列构型场(通过改变k调控)下激子中心位置n_c随时间的演化