• Acta Physica Sinica
  • Vol. 68, Issue 20, 204204-1 (2019)
Zhen Wang, Yan-Jun Du, Yan-Jun Ding, and Zhi-Min Peng*
DOI: 10.7498/aps.68.20191062 Cite this Article
Zhen Wang, Yan-Jun Du, Yan-Jun Ding, Zhi-Min Peng. Wavelength-scanned cavity ring down spectroscopy based on Fourier transform[J]. Acta Physica Sinica, 2019, 68(20): 204204-1 Copy Citation Text show less
The system schematic diagram of FTS-CRDS and CW-CRDS. LC, laser current and temperature controller; FI, fiber isolator; AOM, acousto-optic modulator; APD, avalanche photodiode; DDG, digital delay generator; PZT, piezoelectric transducer; WM, wavelength meter; DAQ, data acquisition system; WM, wavelength meter.FTS-CRDS与CW-CRDS方法的系统原理图 LC, 激光电流和温度控制器; FI, 光纤隔离器; AOM, 声光调制器; APD, 雪崩光电二极管; DDG, 数字延迟发生器; PZT, 压电换能器; DAQ, 数据采集系统; WM, 波长计
Fig. 1. The system schematic diagram of FTS-CRDS and CW-CRDS. LC, laser current and temperature controller; FI, fiber isolator; AOM, acousto-optic modulator; APD, avalanche photodiode; DDG, digital delay generator; PZT, piezoelectric transducer; WM, wavelength meter; DAQ, data acquisition system; WM, wavelength meter.FTS-CRDS与CW-CRDS方法的系统原理图 LC, 激光电流和温度控制器; FI, 光纤隔离器; AOM, 声光调制器; APD, 雪崩光电二极管; DDG, 数字延迟发生器; PZT, 压电换能器; DAQ, 数据采集系统; WM, 波长计
(a) Instantaneous laser current (blue) and instantaneous ring-down time (black), τ(t); (b) wavelength (red) and etalon signal (black). Note that the (a) and (b) figure shows an example with only 4 of 100 the circles.(a) 激光电流(蓝色)及周期性的衰减常数(黑色); (b) 激光电流(蓝色), 激光波长(黑色), 标准具信号(红色); 图中仅展示了100个周期中的4个
Fig. 2. (a) Instantaneous laser current (blue) and instantaneous ring-down time (black), τ(t); (b) wavelength (red) and etalon signal (black). Note that the (a) and (b) figure shows an example with only 4 of 100 the circles. (a) 激光电流(蓝色)及周期性的衰减常数(黑色); (b) 激光电流(蓝色), 激光波长(黑色), 标准具信号(红色); 图中仅展示了100个周期中的4个
The amplitude spectrum of τ(t) and the periodic noises (~5.5, ~11, ~19 and ~21 Hz).τ(t)的傅里叶幅值谱及周期性噪声(~5.5, ~11, ~19和~21 Hz)
Fig. 3. The amplitude spectrum of τ(t) and the periodic noises (~5.5, ~11, ~19 and ~21 Hz). τ(t)的傅里叶幅值谱及周期性噪声(~5.5, ~11, ~19和~21 Hz)
(a) Ring-down time measured by CW-CRDS, nd is the number of measurements per current, white points represent out-of-range data; (b) ring-down time measured by FTS-CRDS, np is the number of cycles; the x axis represents laser current with the range of 74−86 mA.(a) CW-CRDS测量的衰荡时间, nd为每个电流点的测量次数, 白色点表示超出色阶范围; (b) FTS-CRDS方法测量的衰荡时间, np为所测周期数; 横轴均为激光电流, 为了更清晰地显示谱线中心区域, 这里仅显示了74−86 mA的数据
Fig. 4. (a) Ring-down time measured by CW-CRDS, nd is the number of measurements per current, white points represent out-of-range data; (b) ring-down time measured by FTS-CRDS, np is the number of cycles; the x axis represents laser current with the range of 74−86 mA. (a) CW-CRDS测量的衰荡时间, nd为每个电流点的测量次数, 白色点表示超出色阶范围; (b) FTS-CRDS方法测量的衰荡时间, np为所测周期数; 横轴均为激光电流, 为了更清晰地显示谱线中心区域, 这里仅显示了74−86 mA的数据
The absorption spectra (black dotted line) of CO measured by the two methods and the best fit of Voigt profile (red) and Galatry profile (blue): (a) CW-CRDS; (b) FTS-CRDS; the x and y-axes scales of the residuals obtained by the two methods are the same在相同条件下, 两种方法测量的CO吸收光谱(黑色虚线)及VP(红线)和GP(蓝线)拟合 (a) CW-CRDS; (b) FTS-CRDS; 两幅图的x轴和y轴的尺度相同
Fig. 5. The absorption spectra (black dotted line) of CO measured by the two methods and the best fit of Voigt profile (red) and Galatry profile (blue): (a) CW-CRDS; (b) FTS-CRDS; the x and y-axes scales of the residuals obtained by the two methods are the same 在相同条件下, 两种方法测量的CO吸收光谱(黑色虚线)及VP(红线)和GP(蓝线)拟合 (a) CW-CRDS; (b) FTS-CRDS; 两幅图的x轴和y轴的尺度相同
The measured spectral parameters for various pressures (CW-CRDS (red), FTS-CRDS (black): (a) γc (hollow triangle); (b) β (hollow square), γ2 (hollow triangle).不同压力下所测得的光谱参数(CW-CRDS所测结果为红色, FTS-CRDS为黑色) (a) γc (空心圆); (b) β (空心方框), γ2 (空心三角)
Fig. 6. The measured spectral parameters for various pressures (CW-CRDS (red), FTS-CRDS (black): (a) γc (hollow triangle); (b) β (hollow square), γ2 (hollow triangle). 不同压力下所测得的光谱参数(CW-CRDS所测结果为红色, FTS-CRDS为黑色) (a) γc (空心圆); (b) β (空心方框), γ2 (空心三角)
v0/cm–1E''/cm–1Transitionϕγc (T0)/10–2 cm–1·atm–1β (T0)/10–2 cm–1·atm–1γ2 (T0)/10–2 cm–1·atm–1
CWFTSHTCWFTSCWFTS
注: γc, 碰撞展宽系数; β, Dicke收敛系数; γ2, 速度依赖的碰撞展宽系数; FTS和CW分别代表FTS-CRDS和CW-CRDS, HT表示HITRAN; a表示相同温度(T = 288 K)下HITRAN[30]的数据, 空气为背景气; b不确定度 0%—1%; c不确定度 5%—15%; d不确定度 15%—30%.
6371.29957.670R(5)VP6.26b6.29b6.29a
GP6.43b6.51b2.84d2.92c
RP6.47b6.54b2.57d2.60c
SDVP6.50b6.59b0.87d0.85c
6374.40680.735R(6)VP6.10b6.11b6.12a
GP6.20b6.25b2.65d2.77c
RP6.25b6.29b2.38d2.39c
SDVP6.26b6.33b0.69d0.79c
Table 1.

Measured spectral parameters and uncertainties by CW-CRDS and FTS-CRDS.

FTS-CRDS和CW-CRDS测量的光谱参数及其不确定度

Zhen Wang, Yan-Jun Du, Yan-Jun Ding, Zhi-Min Peng. Wavelength-scanned cavity ring down spectroscopy based on Fourier transform[J]. Acta Physica Sinica, 2019, 68(20): 204204-1
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