Fig. 1. The system schematic diagram of FTS-CRDS and CW-CRDS. LC, laser current and temperature controller; FI, fiber isolator; AOM, acousto-optic modulator; APD, avalanche photodiode; DDG, digital delay generator; PZT, piezoelectric transducer; WM, wavelength meter; DAQ, data acquisition system; WM, wavelength meter.FTS-CRDS与CW-CRDS方法的系统原理图 LC, 激光电流和温度控制器; FI, 光纤隔离器; AOM, 声光调制器; APD, 雪崩光电二极管; DDG, 数字延迟发生器; PZT, 压电换能器; DAQ, 数据采集系统; WM, 波长计
Fig. 2. (a) Instantaneous laser current (blue) and instantaneous ring-down time (black), τ(t); (b) wavelength (red) and etalon signal (black). Note that the (a) and (b) figure shows an example with only 4 of 100 the circles.
(a) 激光电流(蓝色)及周期性的衰减常数(黑色); (b) 激光电流(蓝色), 激光波长(黑色), 标准具信号(红色); 图中仅展示了100个周期中的4个
Fig. 3. The amplitude spectrum of τ(t) and the periodic noises (~5.5, ~11, ~19 and ~21 Hz).
τ(t)的傅里叶幅值谱及周期性噪声(~5.5, ~11, ~19和~21 Hz)
Fig. 4. (a) Ring-down time measured by CW-CRDS, nd is the number of measurements per current, white points represent out-of-range data; (b) ring-down time measured by FTS-CRDS, np is the number of cycles; the x axis represents laser current with the range of 74−86 mA.
(a) CW-CRDS测量的衰荡时间, nd为每个电流点的测量次数, 白色点表示超出色阶范围; (b) FTS-CRDS方法测量的衰荡时间, np为所测周期数; 横轴均为激光电流, 为了更清晰地显示谱线中心区域, 这里仅显示了74−86 mA的数据
Fig. 5. The absorption spectra (black dotted line) of CO measured by the two methods and the best fit of Voigt profile (red) and Galatry profile (blue): (a) CW-CRDS; (b) FTS-CRDS; the x and y-axes scales of the residuals obtained by the two methods are the same
在相同条件下, 两种方法测量的CO吸收光谱(黑色虚线)及VP(红线)和GP(蓝线)拟合 (a) CW-CRDS; (b) FTS-CRDS; 两幅图的x轴和y轴的尺度相同
Fig. 6. The measured spectral parameters for various pressures (CW-CRDS (red), FTS-CRDS (black): (a) γc (hollow triangle); (b) β (hollow square), γ2 (hollow triangle).
不同压力下所测得的光谱参数(CW-CRDS所测结果为红色, FTS-CRDS为黑色) (a) γc (空心圆); (b) β (空心方框), γ2 (空心三角)
v0/cm–1 | E''/cm–1 | Transition | ϕ | γc (T0)/10–2 cm–1·atm–1 | | β (T0)/10–2 cm–1·atm–1 | | γ2 (T0)/10–2 cm–1·atm–1 | CW | FTS | HT | | CW | FTS | | CW | FTS | 注: γc, 碰撞展宽系数; β, Dicke收敛系数; γ2, 速度依赖的碰撞展宽系数; FTS和CW分别代表FTS-CRDS和CW-CRDS, HT表示HITRAN; a表示相同温度(T = 288 K)下HITRAN[30]的数据, 空气为背景气; b不确定度 0%—1%; c不确定度 5%—15%; d不确定度 15%—30%.
| 6371.299 | 57.670 | R(5) | VP | 6.26b | 6.29b | 6.29a | | — | — | | — | — | GP | 6.43b | 6.51b | | 2.84d | 2.92c | | — | — | RP | 6.47b | 6.54b | | 2.57d | 2.60c | | — | — | SDVP | 6.50b | 6.59b | | — | — | | 0.87d | 0.85c | 6374.406 | 80.735 | R(6) | VP | 6.10b | 6.11b | 6.12a | | — | — | | — | — | GP | 6.20b | 6.25b | | 2.65d | 2.77c | | — | — | RP | 6.25b | 6.29b | | 2.38d | 2.39c | | — | — | SDVP | 6.26b | 6.33b | | — | — | | 0.69d | 0.79c |
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Table 1. Measured spectral parameters and uncertainties by CW-CRDS and FTS-CRDS.
FTS-CRDS和CW-CRDS测量的光谱参数及其不确定度