Author Affiliations
Chongqing Municipal Level Key Laboratory of Photoelectric Information Sensing and Transmission Technology, College of Optoelectronic Engineering, Chongqing University of Posts and Telecommunications, Chongqing 400065, Chinashow less
Fig. 1. Experimental setup of orthogonal RDP-LIBS
Fig. 2. Coptis Chinensis. (a) Purchased real objects; (b) samples after preparation
Fig. 3. Spectral intensities and SBRs of four characteristic spectral lines versus detection delay. (a) Fe I; (b) CN; (c) Ca II; (d) Al I
Fig. 4. Spectral intensities and SBRs of four characteristic spectral lines versus pulse interval under different energy groups. (a)(b) Fe I; (c)(d) CN; (e)(f) Ca II; (g)(h) Al I
Fig. 5. Spectral intensities and SBRs of four characteristic spectral lines versus pulse interval (E1=15 mJ, E2=35 mJ, T1=1.5 μs). (a) Fe I; (b) CN; (c) Ca II; (d) Al I
Fig. 6. Signal intensity comparison for SP-LIBS and RDP-LIBS
Fig. 7. Boltzmann linear fitting of Ca II spectral line of Coptis Chinensis samples. (a) RDP-LIBS; (b) SP-LIBS
Fig. 8. Electron excitation temperature of plasma versus detection delay
Fig. 9. Electron number density of plasma versus detection delay
Characteristic spectral line | Enhancement factor | RSD of SP-LIBS /% | RSD of RDP-LIBS /% |
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Fe I 358.17 nm | 4.0 | 13.5 | 11.1 | CN 388.34 nm | 5.5 | 9.1 | 6.1 | Ca II 393.37 nm | 10.0 | 10.3 | 8.7 | Al I 396.15 nm | 3.5 | 21.0 | 11.3 |
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Table 1. Enhancement factor of spectral intensity and RSD for four characteristic spectral lines
Wavelength λ/nm | Transition parameter | Weight factor ofup level gk | Transitionprobability Aki /s-1 | Energy /eV |
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Ek | Ei |
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317.93 | 3p64d 2D5/2→3p64p 2P3/2 | 6 | 3.6×108 | 7.049150 | 3.150984 | 370.60 | 3p65s 2S1/2→3p64p 2P1/2 | 2 | 8.8×107 | 6.467875 | 3.123349 | 373.69 | 3p65s 2S1/2→3p64p 2P3/2 | 2 | 1.7×108 | 6.467875 | 3.150984 | 393.37 | 3p64p 2P3/2→3p64s 2S1/2 | 4 | 1.47×108 | 3.150984 | 0 | 396.85 | 3p64p 2P1/2→3p64s 2S1/2 | 2 | 1.4×108 | 3.123349 | 0 |
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Table 2. Spectral parameters of Ca II spectral line used for Boltzmann fitting