Characterization Techniques of Dissolved Organic Pollutants in Wastewater by Three-Dimensional Fluorescent Spectroscopy and Its Application in Environmental Analysis

Jun SHI; Zhi-gang WANG; Ke FENG

doi:10.3969/j.issn.1673-6141.2011.04.001

[1] Owen D M, Amy G L, Chowdhury Z K. NOM characterization and treatability [J]. Journal of American Water Works Association, 1995, 87(1): 46-63.

[2] Leenheer J A, Croue J P. Characterizing aquatic dissolved organic matter [J]. Environmental Science & Technology, 2003, 37(1): 18-36.

[3] Swietlik J, Dsbrowska A, Raczyk-Stanislawiak U, et al. Reactivity of natural organic matter fractions with chlorine dioxide and ozone [J]. Water Research, 2004, 38(3): 547-558.

[4] Zhao Zhengye, Xiao Xianming, Li Li, et al. Effect on trihalomethane forming for different molecular weight dissolved organic matter in water resource [J]. Chinese Journal of Enviromental Science, 2002, 23(6): 140-144(in Chinese).

[5] Wu F C, Cai Y R, Evans D, et al. Complexation between Hg(II) and dissolved organic matter in stream waters: an application of fluorescence spectroscopy [J]. Biogeochemistry, 2004, 71(3): 339-351.

[6] Fu Pingqing, Liu Congqiang, Wu Fengchang. Three-dimensional excitation emission matrix fluorescence spectroscopic characterization of the complexation between Mercury(Ⅱ) and dissolved organic matter [J]. Environmental Science, 2004, 25(6): 140-144(in Chinese).

[7] Einsiedl F, Hertkorn N, Wolf M, et al. Rapid biotic molecular transformation of fulvic acids in a karst aquifer [J]. Geochimica et Cosmochimica Acta, 2007, 71(22): 5474-5482.

[8] Opsahl S, Benner R. Photochemical reactivity of dissolved lignin in river and ocean waters [J]. Limnology Oceanography, 1998, 43(6): 1297-1303.

[9] Li Hongbin, Liu Wenqing, Wang Zhigang, et al. Concentration calibration of multi-component analysis based on three-dimensional fluorescence spectroscopy [J]. Chinese Journal of Quantum Electronics, 2007, 24(3): 306-310(in Chinese).

[10] Baker A. Fluorescence excitation-emission matrix characterization of river waters impacted by a tissue mill effluent [J]. Environmental Science & Technology, 2002, 36(7): 13-77.

[11] Wolfe M F, Olsen H E, Tjeerdema R S. Induction of stress proteins in Isochrysis galbana exposed to crude oil and chemically dispersed crude oil preparation [J]. Marine Environmental Research, 1996, 42(1-6): 405.

[12] Leenheer J A, Wershaw R L, Brown G K, Reddy M M. Characterization and diagenesis of strong-acid carboxyl groups in humic substances [J]. 2003, 18(3): 471-482.

[13] Zhong Runsheng, Zhang Xihui, Guan Yuntao, et al. Three-dimensional fluorescence fingerprint for source determination of dissolved organic matters in polluted river [J]. Spectroscopy and Spectral Analysis, 2008, 26(2): 13-18(in Chinese).

[14] Yang Y, Zhang D. Concentration effect on the fluorescence spectra of humic substances [J]. Communications in Soil Science and Plant Analysis, 1995, 26(15-16): 2333-2349.

[15] Vodacek A, Philpot W D. Environmental effects on laser-induced fluorescence spectra of natural waters [J]. Remote Sensing of Environment, 1987, 21(1): 83-95.

[16] Lanne R W P M. Influence of pH on the fluorescence of dissolved organic matter [J]. Mar. Chem., 1982, 11(4): 395-401.

[17] Vodacek A, Philpot W D. Environmental effects on laser-induced fluorescence spectra of natural waters [J]. Remote Sensing of Environment, 1987, 21(1): 83-95.

[18] Mobed J J, Hemmingsen S L, Autry J L, et al. Fluorescence characterization of IHSS humic substances: total luminescence spectra with absorbance correction [J]. Environmental Science & Technology, 1996, 30(10): 3061-3065.

[19] Henderson R K, Baker A, Murphy K R, et al. Fluorescence as a potential monitoring tool for recycled water systems: a review [J]. Water Research, 2009, 49(3): 863-881.

[20] Senesi N. Molecular and quantitative aspects of the chemistry of fulvic acid and its interactions with metal ions and organnic chemicals: partⅡ [J]. The Fluorescence Spectroscopy Approach, 1990, 23(2): 77-106.

[21] Coble P G. Characterization of marine and terrestrial DOM in seawater using excitation-emission matrix spectroscopy [J]. Marine Chemistry, 1996, 51(4): 325-346.

[22] Senesi N, Miano T M, Provenzano M R, et al. Characterization, differentiation, and classification of humic substances by fluorescence spectroscopy [J]. Soil Science, 1991, 152(4): 259-271.

[23] Chen R F, Bada J L. The fluorescence of dissolved organic matter in seawater [J]. Marine Chemistry, 1992, 37(3-4): 191-221.

[24] De Souza Sierra M M, Donard O F X, Lamotte M, et al. Fluorescence spectroscopy of coastal and marine waters [J]. Marine Chemistry, 1994, 47(2): 127-144.

[25] Ghosh K, Schnizer M. Fluorescence excitation spectra of humic substances [J]. Canadian Journal Soil Science, 1980, 60(2): 373-379.

[26] Au K K, Penisson A C, Yang S, et al. Natural organic matter at oxide/water interfaces: complexation and conformation [J]. Geochimica et Cosmochimica Acta, 1999, 63(19-20): 2903-2917.

[27] Esteves da Silva J C G, Machado A A S C, Oliveira C J S, et al. Fluorescence quenching of anthropogenic fulvic acids by Cu(II), Fe(III) and UO [J]. Talanta, 1998, 45(6): 1155-1165.

[28] Ahmad S R, Reynolds D M. Monitoring of water quality using fluorescence technique: prospect of on-line process control [J]. Water Research, 1999, 33(9): 2069-2074.

[29] Yang Ce, Zhong Ningning, Shi Yulei, et al. Three-dimensional excitation emission matrix fluorescence spectroscopic characterization of dissolved organic matter in water of coal-mining area [J]. Spectroscopy and Spectral Analysis, 2008, 28(1): 174-177(in Chinese).

[30] Hao Ruixia, Cao Kexin, Deng Yiwen. Characterization of dissolved organic pollutants in wastewater by three-dimensional fluorescent spectroscopy [J]. Chinese Journal of Analysis Laboratory, 2007, 26(10): 41-45(in Chinese).

[31] Baker A, Inverarity R, Charlton M, et al. Detecting river pollution using fluorescence spectrophotometry: case studies from the Ouseburn, NE England [J]. Environmental Pollution, 2003, 124(1): 57-70.

[32] Baker A. Spectrophotometric discrimination of river dissolved organic matter [J]. Hydrological Processes, 2002, 16(16): 3203-3213.

[33] Hudson N, Baker A, Ward D, et al. Can fluorescence spectrometry be used as a surrogate for the biochemical oxygen demand (BOD) test in water quality assessment An example from South West England [J]. Science of the Total Environment, 2008, 391(1): 149-158.

[34] Lee S, Ahn K H. Monitoring of COD as an organic indicator in waste water and treated effluent by fluorescence excitation-emission (FEEM) matrix characterization [J]. Water Science and Technology, 2004, 50(8): 57-63.

[35] Cumberland S A, Baker A. The freshwater dissolved organic matter fluorescence-total organic carbon relationship [J]. Hydrological Processes, 2007, 21(16): 2093-2099.

[36] Baker A. Fluorescence excitation-emission matrix characterization of some sewage-impacted rivers [J]. Environmental Science and Technology, 2001, 35(5): 948-953.

[37] Hur J, Hwang S J, Shin J K. Using synchronous fluorescence technique as a water quality monitoring tool for an urban river [J]. Water, Air, and Soil Pollution, 2008, 191(1-4): 231-243.

[38] Reynolds D M, Ahmad S R. Rapid and direct determination of wastewater BOD values using a fluorescence technique [J]. Water Research, 1997, 31(8): 2012-2018.

[39] Reynolds D M, Ahmad S R. Rapid and direct determination of wastewater BOD values using a fluorescence technique [J]. Water Research, 1997, 31(8): 2012-2018.

[40] Ahmad S R, Reynolds D M. Synchronous fluorescence spectroscopy of wastewater and some potential constituents [J]. Water Research, 1995, 29(6): 1599-1602.

[41] Vasel J L, Praet E. On the use of fluorescence measurements to characterize wastewater [J]. Water Science and Technology, 2002, 45(4-5): 109-116.

[42] Wu J, Pons M N, Potier O. Wastewater fingerprinting by UV-visible and synchronous fluorescence spectroscopy [J]. Water Science and Technology, 2006, 53(4-5): 449-456.

[43] Baker A, Inverarity R, Charlton M, et al. Detecting river pollution using fluorescence spectrophotometry: case studies from the Ouseburn, NE England [J]. Environmental Pollution, 2003, 124(1): 57-70.

[44] Baker A. Fluorescence excitation-emission matrix characterization of some sewage-impacted rivers [J]. Environmental Science & Technology, 2001, 35(5): 948-953.

[45] Stedmon C A. Tracing dissolved organic matter in aquatic environments using a new approach to fluorescence spectroscopy [J]. Marine Chemistry, 2003, 23(2): 239-254.

[46] Zhao Yunying, Ma Yongan. Recent progress and development in oil spills identification by fluorescence spectroscopy [J]. Marine Environmental Science, 1997, 16(2): 30-35(in Chinese).

[47] Zhao Nanjing, Liu Wenqing, Liu Jianguo, et al. Study on characteristics of fluorescence spectra of dissolved organic matter with different water quality [J]. Spectroscopy and Spectral Analysis, 2005, 25(7): 1077-1079(in Chinese).

[48] Wang Zhigang, Liu Wenqing, Zhang Yujun, et al. Comparative research on determination of water integrated organic pollution index with three dimensional excitation-emission fluorescence spectroscopy and traditional wet chemical methods [J]. Spectroscopy and Spectral Analysis, 2007, 27(12): 2514-2516(in Chinese).

CLP Journals