• Journal of Radiation Research and Radiation Processing
  • Vol. 41, Issue 6, 060201 (2023)
Xinxin FENG1、2, Xuanzhi MAO1、2, Mingxing ZHANG1, Lijun HU1, Hongwei HAN1, Zhe XING1, Rong LI1、*, and Guozhong WU1、3、**
Author Affiliations
  • 1Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  • 2University of Chinese Academy of Sciences, Beijing 100049, China
  • 3School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China
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    DOI: 10.11889/j.1000-3436.2023-0071 Cite this Article
    Xinxin FENG, Xuanzhi MAO, Mingxing ZHANG, Lijun HU, Hongwei HAN, Zhe XING, Rong LI, Guozhong WU. Synthesis of functional nonwoven fabric using radiation grafting for the selective adsorption of Au(Ⅲ) in an acidic solution[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(6): 060201 Copy Citation Text show less
    Synthetic route for NWF-bif
    Fig. 1. Synthetic route for NWF-bif
    FTIR spectra of NWF samples before and after modification
    Fig. 2. FTIR spectra of NWF samples before and after modification
    TG and DTG curves of NWF samples before and after modification (color online)
    Fig. 3. TG and DTG curves of NWF samples before and after modification (color online)
    Water contact angles of NWF samples before and after modification
    Fig. 4. Water contact angles of NWF samples before and after modification
    SEM images of (a) PE/PP NWF, (b) NWF-g-P(AN-co-AA), (c) NWF-bif, and (d) Au@NWF-bif
    Fig. 5. SEM images of (a) PE/PP NWF, (b) NWF-g-P(AN-co-AA), (c) NWF-bif, and (d) Au@NWF-bif
    Effect of pH on the Au(Ⅲ) adsorption (initial concentration, 25 mg/L; sorbent dosage, 0.1 g/L; time, 240 h )(color online)
    Fig. 6. Effect of pH on the Au(Ⅲ) adsorption (initial concentration, 25 mg/L; sorbent dosage, 0.1 g/L; time, 240 h )(color online)
    (a) Effect of adsorption time on Au(Ⅲ) adsorption capacity; fitting results of (b) pseudo-first-order and (c) pseudo-second-order models (initial concentration, 25 mg/L; sorbent dosage, 0.1 g/L; pH, 2)
    Fig. 7. (a) Effect of adsorption time on Au(Ⅲ) adsorption capacity; fitting results of (b) pseudo-first-order and (c) pseudo-second-order models (initial concentration, 25 mg/L; sorbent dosage, 0.1 g/L; pH, 2)
    (a) Adsorption isotherm curve of NWF-bif to Au(III); Fitting results of (b) Langmuir and (c) Freundlich isotherm models (sorbent dosage, 0.1 g/L; time, 240 h; pH, 2)
    Fig. 8. (a) Adsorption isotherm curve of NWF-bif to Au(III); Fitting results of (b) Langmuir and (c) Freundlich isotherm models (sorbent dosage, 0.1 g/L; time, 240 h; pH, 2)
    Selectivity of NWF-bif in mixed metal ion solution (initial concentration of each ion, 10 mg/L; sorbent dosage, 1 g/L; time, 120 h; pH, 2)
    Fig. 9. Selectivity of NWF-bif in mixed metal ion solution (initial concentration of each ion, 10 mg/L; sorbent dosage, 1 g/L; time, 120 h; pH, 2)
    Optical photos of Au@NWF-bif before and after high-temperature treatment
    Fig. 10. Optical photos of Au@NWF-bif before and after high-temperature treatment
    Elements distribution of NWF-bif before and after Au(III) adsorption
    Fig. 11. Elements distribution of NWF-bif before and after Au(III) adsorption
    (a) XPS spectra of NWF-bif before and after adsorption; (b) Au 4f fine spectra of Au@NWF-bif; (c) XRD spectra of pristine PE/PP NWF, NWF-bif, and Au@NWF-bif; (d) O 1s, (e) N 1s, and (f) S 2p XPS fine spectra of NWF-bif before and after adsorption
    Fig. 12. (a) XPS spectra of NWF-bif before and after adsorption; (b) Au 4f fine spectra of Au@NWF-bif; (c) XRD spectra of pristine PE/PP NWF, NWF-bif, and Au@NWF-bif; (d) O 1s, (e) N 1s, and (f) S 2p XPS fine spectra of NWF-bif before and after adsorption
    准一级动力学模型 Pseudo-first-order model准二级动力学模型 Pseudo-second-order model
    Qe / mg·g-1k1 / h-1Qecal / mg·g-1R12k2×10-4 / g·(mg·h)-1Qecal / mg·g-1R22
    125.150.03184.780.9851.32153.850.996
    Table 1. Fitting parameters of kinetic models
    Langmuir等温模型 Langmuir isotherm modelFreundlich等温模型 Freundlich isotherm model
    T/ KQm/ (mg·g-1)KL/ (L·mg-1)RL2T/ KKF/ (g(1-1/n)·(g·L1/n)-1)1/nRF2
    298135.320.851.00029833.890.330.882
    Table 2. Fitting parameters of isotherm models
    金属离子 Heavy metal ionsAu(III)Cr(VI)Pt(IV)Cd(II)Co(II)Pb(II)
    分配系数Kdistribution coefficient63.731.160.580.110.100.03
    选择系数βselectivity coefficient/55.00110.78571.60653.542 429.17
    Table 3. Distribution coefficient (K) of tested metal ions and selectivity coefficient (β) of Au(III)
    Xinxin FENG, Xuanzhi MAO, Mingxing ZHANG, Lijun HU, Hongwei HAN, Zhe XING, Rong LI, Guozhong WU. Synthesis of functional nonwoven fabric using radiation grafting for the selective adsorption of Au(Ⅲ) in an acidic solution[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(6): 060201
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