Author Affiliations
1Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China2University of Chinese Academy of Sciences, Beijing 100049, China3School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, Chinashow less
Fig. 1. Synthetic route for NWF-bif
Fig. 2. FTIR spectra of NWF samples before and after modification
Fig. 3. TG and DTG curves of NWF samples before and after modification (color online)
Fig. 4. Water contact angles of NWF samples before and after modification
Fig. 5. SEM images of (a) PE/PP NWF, (b) NWF-g-P(AN-co-AA), (c) NWF-bif, and (d) Au@NWF-bif
Fig. 6. Effect of pH on the Au(Ⅲ) adsorption (initial concentration, 25 mg/L; sorbent dosage, 0.1 g/L; time, 240 h )(color online)
Fig. 7. (a) Effect of adsorption time on Au(Ⅲ) adsorption capacity; fitting results of (b) pseudo-first-order and (c) pseudo-second-order models (initial concentration, 25 mg/L; sorbent dosage, 0.1 g/L; pH, 2)
Fig. 8. (a) Adsorption isotherm curve of NWF-bif to Au(III); Fitting results of (b) Langmuir and (c) Freundlich isotherm models (sorbent dosage, 0.1 g/L; time, 240 h; pH, 2)
Fig. 9. Selectivity of NWF-bif in mixed metal ion solution (initial concentration of each ion, 10 mg/L; sorbent dosage, 1 g/L; time, 120 h; pH, 2)
Fig. 10. Optical photos of Au@NWF-bif before and after high-temperature treatment
Fig. 11. Elements distribution of NWF-bif before and after Au(III) adsorption
Fig. 12. (a) XPS spectra of NWF-bif before and after adsorption; (b) Au 4f fine spectra of Au@NWF-bif; (c) XRD spectra of pristine PE/PP NWF, NWF-bif, and Au@NWF-bif; (d) O 1s, (e) N 1s, and (f) S 2p XPS fine spectra of NWF-bif before and after adsorption
准一级动力学模型 Pseudo-first-order model | 准二级动力学模型 Pseudo-second-order model |
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Qe / mg·g-1 | k1 / h-1 | Qecal / mg·g-1 | R12 | k2×10-4 / g·(mg·h)-1 | Qecal / mg·g-1 | R22 | 125.15 | 0.03 | 184.78 | 0.985 | 1.32 | 153.85 | 0.996 |
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Table 1. Fitting parameters of kinetic models
Langmuir等温模型 Langmuir isotherm model | Freundlich等温模型 Freundlich isotherm model |
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T/ K | Qm/ (mg·g-1) | KL/ (L·mg-1) | RL2 | T/ K | KF/ (g(1-1/n)·(g·L1/n)-1) | 1/n | RF2 | 298 | 135.32 | 0.85 | 1.000 | 298 | 33.89 | 0.33 | 0.882 |
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Table 2. Fitting parameters of isotherm models
金属离子 Heavy metal ions | Au(III) | Cr(VI) | Pt(IV) | Cd(II) | Co(II) | Pb(II) |
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分配系数Kdistribution coefficient | 63.73 | 1.16 | 0.58 | 0.11 | 0.10 | 0.03 | 选择系数βselectivity coefficient | / | 55.00 | 110.78 | 571.60 | 653.54 | 2 429.17 |
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Table 3. Distribution coefficient (K) of tested metal ions and selectivity coefficient (β) of Au(III)