• Acta Physica Sinica
  • Vol. 69, Issue 9, 098801-1 (2020)
Han Xu*, Lu Zhang, and Zheng Dang
Author Affiliations
  • Department of Building Environment and Energy Engineering, Xi’an Jiaotong University, Xi’an 710049, China
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    DOI: 10.7498/aps.69.20191697 Cite this Article
    Han Xu, Lu Zhang, Zheng Dang. Coupling mechanism of mass transport and electrochemical reaction within patterned anode of solid oxide fuel cell[J]. Acta Physica Sinica, 2020, 69(9): 098801-1 Copy Citation Text show less

    Abstract

    Patterned electrodes are widely used in the development of novel electrodes of solid oxide fuel cells (SOFCs) because of their well-controlled geometries, distinguishable catalytically active sites and simple transport paths. In the existing studies the patterned electrodes are usually adopted to reveal relevant reaction mechanisms and to investigate the electrochemical characteristics of new materials of SOFCs, however, the effects of electrode geometry are not taken into consideration. In the present paper, a lattice Boltzmann model for simulating the charge transport and electrochemical reaction in an SOFC patterned anode is established, and the key dimensionless parameters governing the above electrode process are deduced. This model is then used to investigate the effects of the key dimensionless parameters on the electrochemical performance of a patterned anode. More importantly, the influences of the patterned anode geometry on the coupling of the charge transport and electrochemical reaction are unraveled. According to the sensitivity of the electrode performance to the dimensionless parameters, a dimensionless phase map, which is divided into maximum area, transition area and minimum area, is built. It is concluded that the transition area, in which the electrode performance varies dramatically with the parameters of design and operation, is regarded as the optimal range for studying the relevant reaction mechanism. Meanwhile, it is found that although the electron transport does not restrict the electrode performance, the moderate decrease of the height-to-width ratio of electronic conductor is capable of enlarging the transition area, which is beneficial to revealing the relevant reaction mechanism. Conversely, the ion transport is the rate-limiting step, however, the transition area remains unchanged under different ionic conductor geometries. The present numerical method and conclusions could offer guidance for rationally designing and operating the patterned electrodes.
    Han Xu, Lu Zhang, Zheng Dang. Coupling mechanism of mass transport and electrochemical reaction within patterned anode of solid oxide fuel cell[J]. Acta Physica Sinica, 2020, 69(9): 098801-1
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