Author Affiliations
Institute of Laser Engineering, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, Chinashow less
Fig. 1. Schematics of laser-induced chemical reduction for hierarchical silver micro-nanostructures by dielectric microsphere focusing. (a) Self-assembly of dielectric microspheres on the surface of PDMS film; (b)‒(c) dielectric microspheres were embedded into the uncured PDMS film; (d)‒(e) preparation of AgNPs/AgMRs/MS SERS substrates by laser-chemical reduction; (f) Raman detection
Fig. 2. Regulation of dielectric microsphere diameter (D) on the structure of AgNPs/AgMRs
Fig. 3. SEM micrographs of hierarchical silver micro-nanostructure surfaces under different photochemical parameters. (a) Evolution of hierarchical silver micro-nanostructure with ∶ and irradiation time; (b) evolution of hierarchical silver nanostructure with laser irradiation power and irradiation time
Fig. 4. SERS performance of hierarchical AgNPs/AgMRs/MS hybrid structures. (a)‒(c) Regulation of the photochemical parameters ∶, irradiation power, and microsphere diameter on Raman intensity of MB at 1624 cm-1; (d)‒(g) Raman detection limit of MB, MG, 4-NBT, and CV on hierarchical AgNPs/AgMRs/MS hybrid structures SERS substrate; (h) repeatability of hierarchical AgNPs/AgMRs/MS hybrid structures; (i) histogram of intensity distribution of Raman characteristic peaks at 1396 cm-1 and 1624 cm-1 for MB molecules
Fig. 5. Raman detection limit of MB molecules on different substrates. (a) Si substrate; (b) PDMS substrate; (c) MS substrate; (d) PDMS/MS substrate; (e) AgNPs substrate; (f) AgNPs/MS substrate
Fig. 6. Numerical simulation of focusing effect and directional antenna effect of AgMRs/MS structure. (a) Optical field intensity distribution of the AgMRs/MS structure; (b) focused optical field intensity distribution curve of the AgMRs/MS structure; (c) optical field intensity distributions of directional antenna effect via the free space, MS and AgMRs/MS structures; (d) far-field emission polar plot of directional antenna effect via the free space, MS and AgMRs/MS structure
Data source | Region | Characteristic size /nm |
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D=9 μm | D=14 μm | D=17 μm | D=21 μm |
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Experiment | 1 2 3 4 5 6 | 1209±61 | 790.5±80.9 87.0±10.0 | 334.5±32.5 685.2±36.1 97.0±11.7 133.5±15.9 | 267.1±23.4 423.9±28.9 862.4±51.3 70.6±15.7 98.2±13.3 121.4±20.1 | Simulation | 1 2 3 4 5 6 | 1126 | 519.8 82.2 | 328.9 712.8 79.9 126.1 | 342.1 479.3 890.2 94.9 90.5 134.7 |
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Table 1. Experimental and simulated characteristic size of AgMRs under dielectric microspheres with different diameters