Aiming at the urgent demand of the new generation of sonic logging tools for their core components, piezoelectricceramics, which have high Curie temperature, high voltage electrical coefficient and high stability, 0.06BiYbO3-0.94Pb(Zr0.48Ti0.52)O3(BY-PZT) ternary piezoceramics with addition of different oxide additives were prepared by traditional solid-state reaction method. The effects of oxide additives on the phase structures and electrical properties of the BY-PZT ternary piezoceramics were investigated. XRD and SEM analysis show that all samples are pure tetragonal perovskite structure. When doped with Cr2O3, the average grain size of the samples has a maximum value. Dielectric temperature spectrum and resonance spectrum analysis illustrated that doping of four kinds of oxide improved the temperature stability of dielectric properties respectively. The lanthanum-doped sample got the lowest temperature coefficient of dielectric constant (Tkε). The mechanical quality factor (Qm) has a maximum value when MnO2 are doped; but the samples doped with CeO2 have the best thermal depolarization resistance. The analysis of high temperature complex impedance (Cole-Cole) shows that Cr2O3 doping significantly improve the high temperature resistivity of the ceramic. It is found that the electrical conduction behavior of the ceramics at high temperature is dominated by the grain-boundary response. The lanthanum-doped sample has both high Curie temperature (TC=397 ℃) and high piezoelectric constant (d33=290 pC/N), and after annealed at 300 ℃ for 4 h, the d33 value of the sample still retains above 270 pC/N, which provides great promising for application in the high-temperature piezoelectric devices with an extreme operating temperature of 300 ℃.