The original materials matching of optical fiber image bundle should be optimized to get better light and imaging propagation. The material of the large radius cation was employed such as PbO as fiber core, the low refractive materials SiO2 and B2O3 as cladding layer and the high acid-leaching rate material such as BaO as the acid-leaching layer. The matching of physico-chemical and optical performance among fiber core, cladding layer and acid-leaching glass materials were analyzed and designed. The optical and calorifics performances of three glass materials were tested and analyzed by the experiments such as differential thermal analyzing and spectrum transmission rate testing, then the original materials formula of the acid-leaching optical fiber image bundle were desined optimally. The result shows that the matching performance is the best when the contents of 45% PbO, 60% SiO2 and 40%(B2O3 +BaO)or over the contents are led in the fiber core, cladding layer and acid-leaching glass individually.