• Journal of Inorganic Materials
  • Vol. 36, Issue 1, 43 (2021)
Jiawei BAI1, Jing YANG1、*, Zhenfei LÜ1, and Xiaodong TANG1、2、*
Author Affiliations
  • 1Department of Electronic Science, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China
  • 2Key Laboratory of Polar Materials and Devices, Ministry of Education, East China Normal University, Shanghai 200241, China
  • show less
    DOI: 10.15541/jim20200088 Cite this Article
    Jiawei BAI, Jing YANG, Zhenfei LÜ, Xiaodong TANG. Magnetic and Dielectric Properties of Ti 4+-doped M-type Hexaferrite BaFe12-xTixO19 Ceramics [J]. Journal of Inorganic Materials, 2021, 36(1): 43 Copy Citation Text show less

    Abstract

    Hexaferrite system is expected to be applied in various kinds of multi-state memories, magnetoelectric sensors and other new microelectronic devices, due to its high temperature magnetoelectric coupling effect with low field. Not only the B-site doping of M-type hexaferrite BaFe12O19 with Ti 4+ ion can change its magnetic structure and magnetic properties, but also the defects, multivalent Fe ions, introduced by B-site non-epuivalent Ti doping, could affect its electric properties. In this study, M-type hexaferrite BaFe12-xTixO19 (x=0, 0.5, 1, 1.5) ceramics were prepared by solid phase sintering. The effects of Ti 4+ doping on the structural, magnetic and dielectric properties were studied. The results show that BaFe12-xTixO19 is in ferrimagnetic order with antiparallel spins. When the doping concentration of Ti 4+ ions is low, it tends to replace Fe 3+ ions with up-spin. And the magnetization decreases with the increase of Ti dopant. However, with the further increase of Ti 4+ doping, Fe 3+ ions with down-spin is also replaced, and the saturation magnetization increases with the increase of x. The introduction of Ti 4+ ions can also make the grains to be semiconductor, which results in the Maxwell-Wagner interface polarization behavior at the interfaces between semiconducting grains and grain-boundaries. Hence, M-type hexaferrite BaFe12-xTixO19 ceramics appear obvious low frequency dielectric enhancement accompanied by a Maxwell-Wagner dielectric relaxation.
    Jiawei BAI, Jing YANG, Zhenfei LÜ, Xiaodong TANG. Magnetic and Dielectric Properties of Ti 4+-doped M-type Hexaferrite BaFe12-xTixO19 Ceramics [J]. Journal of Inorganic Materials, 2021, 36(1): 43
    Download Citation