Degradation of patulin and effect of flavor component in apple juice by glow discharge plasma (GDP)

Zhaodi LI; Ting WANG; Wan LI; Hongsheng TANG; Haitao LONG; Weibing XU; Lumei PU

doi:10.11889/j.1000-3436.2023-0048

序号

No.

CAS号

CAS No.

化合物

Compounds

分子式

Chemical formula

相对分子质量

Relative mole-

cular mass

相对含量

Relative content / %

醇类Alcohols

71-36-3

正丁醇 1-Butanol

C₄H₁₀O

74.12

–

0.3

78-70-6

芳樟醇 Linalool

C₁₀H₁₈O

154.25

0.09

0.13

0.17

–

111-87-5

辛醇 1-Octanol

C₈H₁₈O

130.23

–

0.11

–

0.05

–

34995-77-2

反-Α,Α-5-三甲基-5-

乙烯基四氢化-2-呋喃甲醇

Tetrahydro-alpha,alpha,5-

trimethyl-5-vinylfuran-2-methanol

C₁₀H₁₈O₂

170.25

–

0.04

–

15356-70-4

DL-薄荷醇 D,1-menthol

C₁₀H₂₀O

156.27

0.06

–

5989-33-3

顺-Alpha,Alpha-5-三甲基-5-乙烯基四氢化呋喃-2-甲醇

Cis-alpha,alpha,5-trimethyl-5-vinyltetrahydrofuran-2-methanol

C₁₀H₁₈O₂

170.25

–

0.10

0.09

137-32-6

2-甲基丁醇 2-methyl-1-butano

C₅H₁₂O

88.15

2.34

3.29

3.11

3.43

3.67

111-27-3

正己醇 1-Hexanol

C₆H₁₄O

102.17

3.76

5.09

5.21

5.24

5.49

104-76-7

2-乙基乙醇 2-Ethylhexanol

C₈H₁₈O

130.23

0.19

0.18

–

03913-2-8

2-丁基-1-辛醇 2-Butyl-1-octanol

C₁₂H₂₆O

186.33

0.04

–

619-1-2

二氢香芹醇 Dihydrocarvol

C₁₀H₁₈O

154.25

–

0.10

–

6909-21-3

[1S，3R，5S，6R，（-）-胡萝卜素-5-醇

[1S,3R,5S,6R,(-)]-Carane-5-ol

C₁₀H₁₈O

154.25

0.11

–

总计 Total

6.59

8.94

8.49

8.82

9.55

醛类Aldehyde

66-25-1

正己醛Hexanal

C₆H₁₂O

100.16

6.17

6.41

6.06

8.79

3.48

6728-26-3

反式-2-己烯醛 Trans-Hex-2-enal

C₆H₁₀O

98.14

0.13

–

112-31-2

癸醛 Decyl aldehyde

C₁₀H₂₀O

156.27

0.32

0.21

0.13

0.17

0.24

15764-16-6

2,4-二甲基苯甲醛

2,4-Dimethylbenzaldehyde

C₉H₁₀O

134.18

–

0.06

–

0.04

–

112-54-9

十二醛 Dodecyl aldehyde

C₁₂H₂₄O

184.32

–

0.04

0.06

0.04

–

17540-75-9

6-溴吲哚-3-甲醛

-Bromo indole-3-formaldehyde

C₁₈H₃₀O

262.43

–

0.05

1620-98-0

3,5-二叔丁基-4-羟基苯甲醛

3,5-Di-tert-butyl-4-hydroxybenzaldehyde

C₁₅H₂₂O₂

234.33

–

0.08

–

124-13-0

正辛醛 Octanal

C₈H₁₆O

128.21

–

0.16

0.09

0.08

23074-10-4

5-乙基-2-糠醛

5-Ethyl-2-furfural

C₇H₈O₂

124.14

–

0.05

0.14

–

2548-87-0

E-2-辛烯醛 (E)-2-Octenal

C₈H₁₄O

126.20

–

0.33

0.28

20407-84-5

反-2-十二烯醛 (E)-dodec-2-enal

C₁₂H₂₂O

182.30

–

0.71

529-20-4

2-甲基甲苯甲醛

2-Methylbenzaldehyde

C₈H₈O

120.15

–

0.08

–

620-23-5

3-甲基苯甲醛

3-Methyl-benzaldehyd

C₈H₈O

120.15

–

0.21

124-19-6

壬醛 1-Nonanal

C₉H₁₈O

142.24

–

0.37

–

505-57-7

2-己烯醛 hex-2-enal

C₆H₁₀O

98.14

13.18

13.71

12.01

10.47

7.58

620-2-0

5-甲基呋喃醛

5-Methyl furfural

C₆H₆O₂

110.11

–

0.86

1.74

2.98

5.72

28785-6-0

4-丙基苯甲醛

4-Propylbenzaldehyde

C₁₀H₁₂O

148.20

–

0.04

0.06

–

75853-51-9

13-甲基十四醛

13-Methyltetradecanal

C₁₅H₃₀O

226.40

0.08

–

总计 Total

19.88

21.7

20.35

23.13

18.35

酯类Esters

123-86-4

乙酸丁酯 Butyl acetate

C₆H₁₂O₂

116.16

10.92

10.27

9.98

8.79

5.55

624-41-9

2-甲基丁基乙酸酯

2-Methylbutyl acetate

C₇H₁₄O₂

130.18

25.34

24.51

22.94

20.81

13.01

105-66-8

丁酸丙酯 Propyl butyrate

C₇H₁₄O₂

130.18

1.07

0.92

0.78

0.69

13.01

109-21-7

丁酸丁酯 Butyl butyrate

C₈H₁₆O₂

144.21

–

2.20

1.44

1.08

25415-84-3

丁酸2-乙基己酯

2-Ethylhexyl butanoate

C₁₂H₂₄O₂

200.32

–

0.22

–

2438-20-2

丙酸2-甲基丁酯

2-Methylbutyl propionate

C₈H₁₆O₂

144.21

–

0.07

–

109-21-7

丁酸丁酯 Butyl butyrate

C₈H₁₆O₂

144.21

3.26

2.41

–

5048-26-0

乙酸5-己烯基酯

5-Hexen-1-ol, 1-acetate

C₈H₁₄O₂

142.20

0.18

0.15

–

142-92-7

乙酸正己酯 Hexyl acetate

C₈H₁₆O₂

144.21

15.52

11.40

–

7.89

5.28

590-1-2

丙酸丁酯 Butyl propionate

C₇H₁₄O₂

130.18

0.39

0.35

0.39

–

628-63-7

乙酸戊酯 Amyl acetate

C₇H₁₄O₂

130.18

1.45

1.40

1.25

1.13

0.9

37064-20-3

2-甲基丁酸丙酯

2-Methyl-butanoicacipropylester

C₈H₁₆O₂

144.21

0.32

0.21

0.17

–

539-90-2

丁酸异丁酯 Isobutyl butyrate

C₈H₁₆O₂

144.21

–

0.08

–

112-32-3

甲酸辛酯 1-octylformate

C₉H₁₈O₂

158.24

–

0.09

–

37064-20-3

2-甲基丁酸丙酯

2-Methylbutyric acid propyl ester

C₈H₁₆O₂

144.21

–

1.02

–

2445-69-4

异丁酸异戊酯

2-Methylpropanoic acid 2-methylbutyl ester

C₉H₁₈O₂

158.24

–

0.18

–

6846-50-0

2,2,4-三甲基-1,3-戊二醇二异丁酸酯 Bisisobutyric acid 2,2,4-trimethyl-1,3-pentanediyl

C₁₆H₃₀O₄

286.41

0.13

–

110-27-0

肉豆蔻酸异丙酯

Isopropyl myristate

C₁₇H₃₄O₂

270.45

0.50

0.23

0.19

0.24

0.28

15706-73-7

3-甲基丁酸丁酯

Butyl 2-methylbutyrate

C₉H₁₈O₂

158.24

1.45

–

51115-64-1

丁酸-2-甲基丁酯

2-Methylbutyl butyrate

C₉H₁₈O₂

158.24

0.21

–

626-77-7

己酸丙酯 Caproic acid propyl ester

C₉H₁₈O₂

158.24

0.43

0.15

68039-26-9

2-甲基丁酸戊酯

2-Methyl-butanoicacipentylester

C₁₀H₂₀O₂

172.26

0.06

–

02349-7-7

异丁酸己酯 Hexyl isobutyrate

C₁₀H₂₀O₂

172.26

0.07

–

2639-63-6

丁酸己酯 Hexyl butyrate

C₁₀H₂₀O₂

172.26

2.58

–

0.21

0.12

–

10032-15-2

异戊酸己酯 Hexyl 2-methylbutyrate

C₁₁H₂₂O₂

186.29

1.99

0.14

0.13

–

626-77-7

己酸丙酯 Caproic acid propyl ester

C₉H₁₈O₂

158.24

–

0.12

–

77-68-9

3-羟基-2,2,4-三甲基戊基异丁酸酯

3-Hydroxy-2,2,4-trimethylpentyl isobutyrate

C₁₂H₂₄O₃

216.32

0.07

0.05

0.04

–

2601-13-0

2-甲基丁基己酸酯

2-Methylbutyl caproate

C₁₁H₂₂O₂

186.29

0.11

–

4887-30-3

辛基己酸酯

Caproic acid octyl ester

C₁₄H₂₈O₂

228.37

0.12

–

6378-65-0

己酸己酯 Hexyl hexanoate

C₁₂H₂₄O₂

200.32

0.98

–

84-69-5

邻苯二甲酸二异丁酯

Diisobutyl phthalate

C₁₆H₂₂O₄

278.34

0.28

0.05

0.04

0.05

–

84-74-2

邻苯二甲酸二丁酯

Dibutyl phthalate

C₁₆H₂₂O₄

278.34

0.07

–

70969-70-9

己酸-3,5,5-三甲基-2-乙基酯 2-Ethylhexyl 3,5,5-trimethylhexanoate

C₁₇H₃₄O₂

270.45

0.33

–

609-8-5

甲基丙二酸二乙酯

Diethyl methylmalonate

C₈H₁₄O₄

174.19

–

0.04

–

总计 Total

67.83

53.94

38.75

41.55

39.11

酮类Ketones

585-74-0

3-甲基苯乙酮

3-Methylacetophenone

C₉H₁₀O

134.18

–

0.18

118-93-4

2-羟基苯乙酮

2-Hydroxyacetophenone

C₈H₈O₂

136.15

–

0.29

93-55-0

苯丙酮 Propiophenone

C₉H₁₀O

134.18

–

0.11

98-86-2

苯乙酮 Acetophenone

C₈H₈O

120.15

–

0.07

0.18

0.33

0.73

13019-20-0

2-甲基-3-庚酮

2-methylheptan-3-one

C₈H₁₆O

128.21

–

1.6

110-93-0

6-甲基-5-庚烯-2-酮

6-Methyl-5-hepten-2-one

C₈H₁₄O

126.20

–

0.06

–

37112-31-5

左旋葡萄糖酮

Levoglucone

C₆H₆O₃

126.11

–

0.05

0.06

–

93-55-0

苯丙酮 Propiophenone

C₉H₁₀O

134.18

–

0.06

–

689-67-8

6,10-二甲基-5,9-十一双烯-2-酮

6,10-Dimethyl-5,9-undecadien-2-one

C₁₃H₂₂O

194.31

–

0.04

0.03

0.04

0.06

10396-80-2

2,6-二(叔丁基)-4-羟基-4-甲基-2,5-环己二烯-1-酮

2,6-Di(tert-butyl)-4-hydroxy-4-methyl-2,5-cyclohexadien-1-one

C₁₅H₂₄O₂

236.35

0.62

0.24

0.16

0.11

81944-8-3

反式 -3-丁内酯-4,5-

二氢异苯并呋喃-1（3H）-酮

Trans-3-butanolactone-4,5-dihydroisobenzofuran-1 (3H)-one

C₁₂H₁₄O₂

190.24

0.89

0.85

0.22

–

10408-15-8

2-甲基-1-庚烯-6-酮

2-Methyl-1-heptene-6-one

C₈H₁₄O

126.20

–

0.07

136230-43-8

10-甲基-3,4,5,8,9,10-六氢-2H-氧辛-2-酮 10-Methyl-3,4,5,8,9,10-hexahydro-2H-oxecin-2-one

C₈H₁₄O

126.20

–

0.05

122-0-9

对甲基苯乙酮

Methylacetophenone

C₉H₁₀O

134.18

–

0.08

0.02

总计 Total

1.51

1.2

0.64

0.74

3.22

其他 Others

271-89-6

2,3-苯并呋喃 Benzofuran

C₈H₆O

118.14

–

0.48

0.76

1197-40-6

2-(呋喃-2-基甲基)呋喃

2,2-Methylenebisfuran

C₉H₈O₂

148.16

–

0.10

0.06

–

13678-51-8

5-甲基-2-糠基呋喃

2-Furfuryl-5-methylfuran

C₁₀H₁₀O₂

162.19

–

0.05

0.11

0.22

13679-43-1

氰化四乙基铵

Tetraethyl ammonium cyanide

C₁₁H₁₂O₂

176.21

–

0.03

–

719-22-2

2,6-二叔丁基苯醌

2,6-Di-tert-butyl-p-benzoquinone

C₁₄H₂₀O₂

220.31

0.05

0.04

2460-77-7

2,5-二叔丁基-1,4-苯醌

2,5-Di-tert-butyl-1,4-benzoquinone

C₁₄H₂₀O₂

220.31

–

0.06

0.05

0.04

0.05

96-76-4

2,4-二叔丁基苯酚

2,4-Di-tert-butylphenol

C₁₄H₂₂O

206.32

–

0.12

128-37-0

2,6-二叔丁基对甲酚

2,6-Di-tert-butyl-4-methylphenol

C₁₅H₂₄O

220.35

3.72

1.14

0.94

1.27

0.66

72917-31-8

Z-亚丁基苯酞

(Z)-Butylidenephthalide

C₁₂H₁₂O₂

188.22

0.35

0.22

–

10522-34-6

2-甲基壬酯丙酸

Propanoic acid, 2-methyl-, nonyl ester

C₁₃H₂₆O₂

214.34

–

0.17

–

总计 Total

4.07

1.59

1.17

2.09

1.87

处理时间 / min

Processing time

亮度

Brightness

色调

Tone

色度

Chrominance

色差

Chromatism

苹果块Apple chunks

70.09±0.03

70.10±0.03

70.16±0.02

70.19±0.02

70.24±0.01

70.30±0.02

70.31±0.02

94.23±0.01

94.16±0.01

93.89±0.01

93.75±0.02

93.65±0.01

93.85±0.02

93.56±0.01

36.54±0.03

36.17±0.02

37.69±0.02

36.41±0.01

39.80±0.01

40.82±0.01

40.51±0.01

2.04±0.02

2.96±0.01

1.18±0.01

2.06±0.01

1.15±0.01

1.18±0.01

苹果汁Apple juice

62.12±0.02

64.90±0.03

65.12±0.02

65.37±0.01

65.73±0.01

67.59±0.02

69.53±0.01

95.33±0.01

94.83±0.01

94.09±0.01

93.05±0.02

92.95±0.01

92.82±0.02

90.47±0.01

30.89±0.03

34.61±0.03

35.27±0.03

36.46±0.03

36.77±0.03

37.80±0.03

37.85±0.03

3.32±0.02

4.09±0.02

4.24±0.01

5.47±0.01

5.74±0.01

5.83±0.01

Zhaodi LI, Ting WANG, Wan LI, Hongsheng TANG, Haitao LONG, Weibing XU, Lumei PU. Degradation of patulin and effect of flavor component in apple juice by glow discharge plasma (GDP)[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(6): 060403

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