• Journal of Radiation Research and Radiation Processing
  • Vol. 41, Issue 4, 040202 (2023)
Wenhui YU1,2, Jialong TIAN2,3, Jiang PAN2, Chenchen JIANG2..., Zhenming QI2, Chuanfeng ZANG1 and Chunxia WANG2,*|Show fewer author(s)
Author Affiliations
  • 1School of Textile and Garment, Nantong University, Nantong 226019, China
  • 2School of Textile and Garment, Yancheng Institute of Technology, Yancheng 224001, China
  • 3School of Textile and Garment, Xi'an Polytechnic University, Xi'an 710000, China
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    DOI: 10.11889/j.1000-3436.2022-0133 Cite this Article
    Wenhui YU, Jialong TIAN, Jiang PAN, Chenchen JIANG, Zhenming QI, Chuanfeng ZANG, Chunxia WANG. Preparation of reactive flame retardant dimethly allylphosphonate and its grafting onto cotton fabric via ultraviolet light irradiation[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(4): 040202 Copy Citation Text show less
    Synthesis of DA
    Fig. 1. Synthesis of DA
    Chemical reaction of cotton fabric and DA
    Fig. 2. Chemical reaction of cotton fabric and DA
    1HNMR spectrum of DA
    Fig. 3. 1HNMR spectrum of DA
    SEM images: (a) cotton fabric (×5 000); (b) flame resistant cotton fabric (×5 000); (c) char layer of flame resistant cotton fabric after burning (×5 000), and (d) char layer of flame resistant cotton fabric after burning (×500)
    Fig. 4. SEM images: (a) cotton fabric (×5 000); (b) flame resistant cotton fabric (×5 000); (c) char layer of flame resistant cotton fabric after burning (×5 000), and (d) char layer of flame resistant cotton fabric after burning (×500)
    EDS: (a) cotton fabric, (b) flame resistant cotton fabric (500 g/L) and (c) char layer of flame resistant cotton fabric after burning
    Fig. 5. EDS: (a) cotton fabric, (b) flame resistant cotton fabric (500 g/L) and (c) char layer of flame resistant cotton fabric after burning
    FTIR spectra: (a) DA; (b) cotton fabric; (c) flame resistant cotton fabric (500 g/L)
    Fig. 6. FTIR spectra: (a) DA; (b) cotton fabric; (c) flame resistant cotton fabric (500 g/L)
    Effects of DA mass concentration on WG and LOI of cotton fabric
    Fig. 7. Effects of DA mass concentration on WG and LOI of cotton fabric
    Effects of MBA mass concentration on WG and LOI of cotton fabric
    Fig. 8. Effects of MBA mass concentration on WG and LOI of cotton fabric
    Vertical burning photos: (a) cotton fabric; (b) flame resistant cotton fabric (300g/l); (c) flame resistant cotton fabric (400g/l); (d) flame resistant cotton fabric (500g/l)
    Fig. 9. Vertical burning photos: (a) cotton fabric; (b) flame resistant cotton fabric (300g/l); (c) flame resistant cotton fabric (400g/l); (d) flame resistant cotton fabric (500g/l)
    Effect of washing cycles on LOI of cotton fabric
    Fig. 10. Effect of washing cycles on LOI of cotton fabric
    TG and DTG curves of cotton fabric and flame resistant cotton fabric: (a) TG in N2, (b) DTG in N2, (c) TG in air and (d) DTG in air
    Fig. 11. TG and DTG curves of cotton fabric and flame resistant cotton fabric: (a) TG in N2, (b) DTG in N2, (c) TG in air and (d) DTG in air
    Effects of DA mass concentration on tensile breaking strength of cotton fabric
    Fig. 12. Effects of DA mass concentration on tensile breaking strength of cotton fabric

    样品

    Sample

    原棉

    Cotton fabric

    阻燃棉织物

    Flame resistant cotton

    fabric

    DA质量浓度 / (g‧L-1)

    DA mass concentration

    0300400500

    续燃时间 / s

    Afterflame time

    16.60.00.00.0

    阴燃时间 / s

    Afterglow time

    49.950.00.00.0

    炭长 / cm

    Char length

    >308.54.23.9
    Table 1. Vertical burning data of different DA mass concentration finishing cotton fabrics

    样品

    Samples

    气氛

    Atmosphere

    T5% / ℃Tmax1 / ℃Tmax2 / ℃

    600 ℃时的残余质量 / %

    Residual mass at 600 ℃

    棉织物

    Cotton fabric

    氮气

    N2

    26037814.28

    阻燃棉织物 (500 g/L)

    Flame resistant cotton fabric (500 g/L)

    9334434

    棉织物

    Cotton fabric

    空气

    Air

    2783284610.51

    阻燃棉织物 (500 g/L)

    Flame resistant cotton fabric (500 g/L)

    11928211.54
    Table 2. TG data of cotton fabrics in N2 and air
    Wenhui YU, Jialong TIAN, Jiang PAN, Chenchen JIANG, Zhenming QI, Chuanfeng ZANG, Chunxia WANG. Preparation of reactive flame retardant dimethly allylphosphonate and its grafting onto cotton fabric via ultraviolet light irradiation[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(4): 040202
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