Fig. 1. A sketch of the simulation system.
Fig. 2. The number of the adsorbed segment of the free polymer mad as a function of the adsorption energy ε for different d, where Nf = 50 and Nb = 10. The inset presents the dependence of the ratio mad/mads on ε for different Nf and d.
Fig. 3. The mean square radius of the free polymer
as a function of
ε, where
Nf = 50 and
Nb = 10. The inset presents the dependence of the minimum of
,
, on
d.
Fig. 4. The distribution of the segment of the free polymer and the polymer brush, φpandφb, in the z direction for three different ε, where Nf = 50, Nb = 10 and d = 12.
Fig. 5. The evolution of the mean square displacement of the center of mass of the free polymer (Δr)2 for different ε, where Nf = 50, Nb = 10 and d = 10.
Fig. 6. The dependence of β on ε for different d, where Nf = 50 and Nb = 10. The inset presents the dependence of the diffusion coefficient D on Nf at small ε = 1.
Fig. 7. The evolution of the number of the adsorbed segment of the free polymer (mfa) and that of the number the segment of polymer brush contacting with the free polymer (mfb), where Nf = 50, Nb = 10, d = 10 and ε = 3. The insets: (a) The evolution of the relaxation function qfa(t) and qfb(t); (b) the dependence of the adsorption time τfa of the free polymer and the relaxation time of the number of segment of brush contacting with the free polymer τfb on the adsorption energy ε, where Nf = 50, Nb = 10 and d = 10.