Chao Wang, Yan-Li Zhou, Fan Wu, Ying-Cai Chen. Monte Carlo simulation on the adsorption of polymer chains on polymer brushes [J]. Acta Physica Sinica, 2020, 69(16): 168201-1

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- Acta Physica Sinica
- Vol. 69, Issue 16, 168201-1 (2020)

Fig. 1. A sketch of the simulation system.

Fig. 2. The number of the adsorbed segment of the free polymer m ad as a function of the adsorption energy ε for different d , where N f = 50 and N b = 10. The inset presents the dependence of the ratio m ad/m ads on ε for different N f and d .

Fig. 3. The mean square radius of the free polymer
as a function of ε , where N f = 50 and N b = 10. The inset presents the dependence of the minimum of
,
, on d .




Fig. 4. The distribution of the segment of the free polymer and the polymer brush, φ pandφ b, in the z direction for three different ε , where N f = 50, N b = 10 and d = 12.

Fig. 5. The evolution of the mean square displacement of the center of mass of the free polymer (Δr )2 for different ε , where N f = 50, N b = 10 and d = 10.

Fig. 6. The dependence of β on ε for different d , where N f = 50 and N b = 10. The inset presents the dependence of the diffusion coefficient D on N f at small ε = 1.

Fig. 7. The evolution of the number of the adsorbed segment of the free polymer (m fa) and that of the number the segment of polymer brush contacting with the free polymer (m fb), where N f = 50, N b = 10, d = 10 and ε = 3. The insets: (a) The evolution of the relaxation function q fa(t ) and q fb(t ); (b) the dependence of the adsorption time τ fa of the free polymer and the relaxation time of the number of segment of brush contacting with the free polymer τ fb on the adsorption energy ε , where N f = 50, N b = 10 and d = 10.
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