• Acta Photonica Sinica
  • Vol. 53, Issue 3, 0304001 (2024)
Yao LI*, Fenqiang WANG, Ailing WANG, Jun LAN..., Hu LIU, Liangpeng LIU, Pengjie ZHANG, Huizhou WU, Ruixia NIU and Xuying ZHANG|Show fewer author(s)
Author Affiliations
  • School of Electronics and Information Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China
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    DOI: 10.3788/gzxb20245303.0304001 Cite this Article
    Yao LI, Fenqiang WANG, Ailing WANG, Jun LAN, Hu LIU, Liangpeng LIU, Pengjie ZHANG, Huizhou WU, Ruixia NIU, Xuying ZHANG. High-performance Photomultiplication-type Organic Photodetector Based on Double-donor Ternary Bulk Heterojunction[J]. Acta Photonica Sinica, 2024, 53(3): 0304001 Copy Citation Text show less
    Schematic diagram of molecular structure, device structure and material energy level of active layer materials
    Fig. 1. Schematic diagram of molecular structure, device structure and material energy level of active layer materials
    Absorption spectrum of ternary blend film
    Fig. 2. Absorption spectrum of ternary blend film
    Dark current density-voltage (JD-V) curve of the device
    Fig. 3. Dark current density-voltage (JD-V) curve of the device
    Photocurrent density-voltage (JL-V) curve of the device under 1 mW/cm2 illumination
    Fig. 4. Photocurrent density-voltage (JL-V) curve of the device under 1 mW/cm2 illumination
    Current density-voltage (J-V) curves of devices with doping mass ratio of P3HT∶PTB7-Th∶IEICO-4F (60∶40∶1, wt/wt/wt) under dark conditions and illumination at a wavelength of 520 nm
    Fig. 5. Current density-voltage (J-V) curves of devices with doping mass ratio of P3HT∶PTB7-Th∶IEICO-4F (60∶40∶1, wt/wt/wt) under dark conditions and illumination at a wavelength of 520 nm
    EQE of the device under -15 V bias voltage
    Fig. 6. EQE of the device under -15 V bias voltage
    Responsivity and specific detectivity of the device under -15 V bias
    Fig. 7. Responsivity and specific detectivity of the device under -15 V bias
    EQE of devices with optimal mass ratio under different bias voltages
    Fig. 8. EQE of devices with optimal mass ratio under different bias voltages
    Jph-Pin curves of devices with optimal mass ratio at different bias voltages and 520 nm
    Fig. 9. Jph-Pin curves of devices with optimal mass ratio at different bias voltages and 520 nm
    Schematic diagram of the charge transport of the device and three electron traps in the active layer
    Fig. 10. Schematic diagram of the charge transport of the device and three electron traps in the active layer
    Mobility of the device and photoluminescence spectrum of the active layer
    Fig. 11. Mobility of the device and photoluminescence spectrum of the active layer
    λ/nmR/(A·W-1D*/Jones
    -5 V-10 V-12 V-15 V-5 V-10 V-12 V-15V
    4505.3278.06170.25965.803.26×10122.00×10133.35×10131.19×1014
    5208.56113.95217.25733.355.24×10122.91×10134.27×10139.06×1013
    65512.55140.17293.14998.687.67×10123.58×10135.76×10131.23×1014
    85011.66114.73217.81641.917.15×10122.93×10134.28×10137.93×1013
    9500.295.7915.4757.811.81×10111.48×10123.04×10127.14×1012
    Table 1. Responsivity and specific detectivity of optimal mass ratio devices at different bias voltages and wavelengths
    YearDevice structureWavelength/nmEQE at Bias

    R (A∙W-1

    at Bias

    D* (Jones)at BiasRef.
    2018ITO/PEDOT∶PSS/P3HT∶PTB7-Th∶PC71BM (50∶50∶1, wt/wt/wt)/Al850<500% at -50 V<2×1011 at -10 V9
    2018ITO/PFN-OX/P3HT∶PTB7-Th∶PC61BM (40∶60∶1)/Al850<100% at -10 V<1×1011 at -10 V10
    2020ITO/PEDOT∶PSS/PBDB-T∶IEICO-4F (100∶3, wt/wt)/Al850

    400% at

    -20 V

    0.44×1012 at -10 V19
    2021ITO/ZnO/P3HT∶IEICO (100∶1, wt/wt)/Al850<100% at -15 V<1 at -15 V<1×1012 at -15 V20
    2023ITO/PEDOT∶PSS/P3HT∶PTB7-Th∶IEICO-4F(60∶40∶1, wt/wt/wt)/Al850938.22% at -15 V641.91 at -15 V7.93×1013 at -15 VThis work
    Table 2. Comparison of performance parameters between optimal mass ratio devices and current mainstream devices
    Yao LI, Fenqiang WANG, Ailing WANG, Jun LAN, Hu LIU, Liangpeng LIU, Pengjie ZHANG, Huizhou WU, Ruixia NIU, Xuying ZHANG. High-performance Photomultiplication-type Organic Photodetector Based on Double-donor Ternary Bulk Heterojunction[J]. Acta Photonica Sinica, 2024, 53(3): 0304001
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