Due to the widely application of Pcs in the fields, such as the communication, medical treatment, chemical industry and so on, therefore, it have been a hot research topic over several decades by scientists. However, along with the human society development and the progress in science and technology, the new phthalocyanine with novle characteristics is still the goal of the scientists. In this dissertion, the synthetic methods of the phthlocyanine are improved. The 4,8,15,22-tetra［3,3-bis(p-hydroxyphenyl)phthalide］ phthalocyanines were synthesized and characterized. Using 3-［3,3-bis(p-hydroxyphenyl) phthalide］ 2,3-dicyanonitrobenzene and copper acetate monohydrate, dehydrate nicle acetate as starting materials in n-pentanol, DBU as a catalyst, to synthesize 4,8,15,22-tetra［3,3-bis(p-hydroxyphenyl) phthalide］ phthalocyanines. The phthalocyanines were characterized, then the results proved that compounds were the target products. And the relevant ultraviolet spectrum, fluorescence spectroscopy and optical luminescence spectroscopy properties were studied.