In this study, a hybrid algorithm combining genetic algorithm (GA) with back propagation (BP) neural network (GA-BP) was proposed for extracting the characteristics of multi-peak Brillouin scattering spectrum. Simulations and experimental results show that the GA-BP hybrid algorithm can accurately identify the position and amount of peaks in multi-peak Brillouin scattering spectrum. Moreover, the proposed algorithm obtains a fitting degree of 0.9923 and a mean square error of 0.0094. Therefore, the GA-BP hybrid algorithm possesses a good fitting precision and is suitable for extracting the characteristics of multi-peak Brillouin scattering spectrum.