• Chinese Journal of Lasers
  • Vol. 47, Issue 12, 1214001 (2020)
Zhang Xiansheng1, Chang Tianying1、*, Cui Hongliang2, Liu Lingyu1, and Li Yizhang1
Author Affiliations
  • 1Institute of Automation, Shandong Academy of Sciences, Jinan, Shandong 250014, China
  • 2Chongqing Institute of Green Intelligence, Chinese Academy of Sciences, Chongqing 400714, China
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    DOI: 10.3788/CJL202047.1214001 Cite this Article Set citation alerts
    Zhang Xiansheng, Chang Tianying, Cui Hongliang, Liu Lingyu, Li Yizhang. Terahertz Dielectric Spectra for Thermal Oxygen Aging of Natural Rubber[J]. Chinese Journal of Lasers, 2020, 47(12): 1214001 Copy Citation Text show less
    Structural diagram of poly-isoprene molecule and simplified vulcanization structure
    Fig. 1. Structural diagram of poly-isoprene molecule and simplified vulcanization structure
    Dielectric constant curves of unaged rubber sample
    Fig. 2. Dielectric constant curves of unaged rubber sample
    Partially aged samples
    Fig. 3. Partially aged samples
    Terahertz dielectric constant curves during thermal oxygen aging of samples. (a)Real part; (b) imaginary part
    Fig. 4. Terahertz dielectric constant curves during thermal oxygen aging of samples. (a)Real part; (b) imaginary part
    Dielectric constant curves at 1.0THz frequency point. (a) Real and imaginary parts of dielectric constant versus aging time; (b) average slope of real part curve of dielectric constant versus aging time
    Fig. 5. Dielectric constant curves at 1.0THz frequency point. (a) Real and imaginary parts of dielectric constant versus aging time; (b) average slope of real part curve of dielectric constant versus aging time
    Fitted imaginary parts of dielectric constants
    Fig. 6. Fitted imaginary parts of dielectric constants
    Distribution of resonant frequency points obtained by fitting
    Fig. 7. Distribution of resonant frequency points obtained by fitting
    Real part of dielectric constant at zero frequency, real part of dielectric constant at optical frequency, and dielectric strength
    Fig. 8. Real part of dielectric constant at zero frequency, real part of dielectric constant at optical frequency, and dielectric strength
    SamplePHRChemical formula
    Natural rubber100C5H8
    Zinc oxide5ZnO
    Stearic acid1C18H36O2
    1H-benzo[d]imidazole-2-thiol1C7H6N2S
    Poly(1,2-dihydro-2,2,4-trimethyl-quinoline)1(C12H15N)n
    Carbon black40C
    Dicumyl peroxide2C18H22O18
    Di(morpholin-4-yl) disulphide1.5C8H16N2O2S2
    N-cyclohexylbenzo[d]thiazole-2-sulfonamide1.5C13H16N2O2S2
    Tetramethylthiuram disulfide1C6H12N2S4
    Hexamethylene tetramine4C6H12N4
    Table 1. Ingredients of samples and their contents
    Zhang Xiansheng, Chang Tianying, Cui Hongliang, Liu Lingyu, Li Yizhang. Terahertz Dielectric Spectra for Thermal Oxygen Aging of Natural Rubber[J]. Chinese Journal of Lasers, 2020, 47(12): 1214001
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