• NUCLEAR TECHNIQUES
  • Vol. 48, Issue 2, 020301 (2025)
Jianlu PEI*, Shuwei LIANG, Zhongxin LIN, Jiayu LI..., Jianli CHEN, Ming HAN, Jianrong HOU and Yongguo LI|Show fewer author(s)
Author Affiliations
  • CNNC Key Laboratory of Radioactive Gas Purification Technology, China Institute for Radiation Protection, Taiyuan 030006, China
  • show less
    DOI: 10.11889/j.0253-3219.2025.hjs.48.240247 Cite this Article
    Jianlu PEI, Shuwei LIANG, Zhongxin LIN, Jiayu LI, Jianli CHEN, Ming HAN, Jianrong HOU, Yongguo LI. Study on catalytic oxidation of low concentration 14CH4 by non-thermal plasma[J]. NUCLEAR TECHNIQUES, 2025, 48(2): 020301 Copy Citation Text show less
    Diagram of 14CH4 plasma-catalytic experimental system
    Fig. 1. Diagram of 14CH4 plasma-catalytic experimental system
    Typical Lissajous figure
    Fig. 2. Typical Lissajous figure
    Lissajous figures and current-voltage waveforms corresponding to different discharge voltages
    Fig. 3. Lissajous figures and current-voltage waveforms corresponding to different discharge voltages
    Variation of plasma discharge power with discharge voltage
    Fig. 4. Variation of plasma discharge power with discharge voltage
    Effect of discharge voltages on CH4 processing efficiency (a) and CO2 selectivity (b) before and after plasma introduction into the catalysts (color online)
    Fig. 5. Effect of discharge voltages on CH4 processing efficiency (a) and CO2 selectivity (b) before and after plasma introduction into the catalysts (color online)
    Effect of gas flow rate on CH4 processing efficiency (a) and CO2 selectivity (b) before and after plasma introduction into the catalysts (color online)
    Fig. 6. Effect of gas flow rate on CH4 processing efficiency (a) and CO2 selectivity (b) before and after plasma introduction into the catalysts (color online)
    Effect of reaction temperature on CH4 processing efficiency (a) and CO2 selectivity (b) before and after plasma introduction into the catalysts (color online)
    Fig. 7. Effect of reaction temperature on CH4 processing efficiency (a) and CO2 selectivity (b) before and after plasma introduction into the catalysts (color online)
    Isothermal N2 adsorption and desorption curves and pore size distribution of catalyst before and after the reaction (color online)
    Fig. 8. Isothermal N2 adsorption and desorption curves and pore size distribution of catalyst before and after the reaction (color online)
    XRD patterns of the catalyst before and after the reaction (color online)
    Fig. 9. XRD patterns of the catalyst before and after the reaction (color online)
    XPS patterns of the catalyst before and after the reaction (color online)
    Fig. 10. XPS patterns of the catalyst before and after the reaction (color online)
    Mechanism of plasma-catalysis oxidation of CH4
    Fig. 11. Mechanism of plasma-catalysis oxidation of CH4

    样品

    Sample

    比表面积

    SBET / cm3·g-1

    孔容

    Vpore / cm3·g-1

    平均孔径

    Average pore size / nm

    催化剂-使用前Catalyst-before use154.80.4626.548
    催化剂-使用后Catalyst-after use165.10.4666.556
    Table 1. Characterisation of the pore structure of the catalyst before and after the reaction
    Jianlu PEI, Shuwei LIANG, Zhongxin LIN, Jiayu LI, Jianli CHEN, Ming HAN, Jianrong HOU, Yongguo LI. Study on catalytic oxidation of low concentration 14CH4 by non-thermal plasma[J]. NUCLEAR TECHNIQUES, 2025, 48(2): 020301
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