• Acta Physica Sinica
  • Vol. 68, Issue 9, 098101-1 (2019)
Yong Li1, Ying Wang1, Shang-Sheng Li2, Zong-Bao Li1、*, Kai-Wu Luo1, Mao-Wu Ran1, and Mou-Sheng Song1
Author Affiliations
  • 1Department of Physics and Electrical Engineering, Tongren University, Tongren 554300, China
  • 2School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China
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    DOI: 10.7498/aps.68.20190133 Cite this Article
    Yong Li, Ying Wang, Shang-Sheng Li, Zong-Bao Li, Kai-Wu Luo, Mao-Wu Ran, Mou-Sheng Song. Synthesis of diamond co-doped with B and S under high pressure and high temperature and electrical properties of the synthesized diamond[J]. Acta Physica Sinica, 2019, 68(9): 098101-1 Copy Citation Text show less
    Schematic of the cell for diamond synthesis (1, conductive ring; 2, graphite sheet; 3, NaCl tube; 4, ceramic cylinder and cover; 5, graphite heater; 6, catalyst; 7, carbon source; 8, insulation tube; 9, seed crystal; 10, pyrophyllite).金刚石合成腔体示意图(1, 钢帽; 2, 石墨片; 3, 氯化钠管; 4, 陶瓷堵头; 5, 石墨加热管; 6, 触媒; 7, 碳源; 8, 绝缘管; 9, 晶种; 10, 叶蜡石)
    Fig. 1. Schematic of the cell for diamond synthesis (1, conductive ring; 2, graphite sheet; 3, NaCl tube; 4, ceramic cylinder and cover; 5, graphite heater; 6, catalyst; 7, carbon source; 8, insulation tube; 9, seed crystal; 10, pyrophyllite).金刚石合成腔体示意图(1, 钢帽; 2, 石墨片; 3, 氯化钠管; 4, 陶瓷堵头; 5, 石墨加热管; 6, 触媒; 7, 碳源; 8, 绝缘管; 9, 晶种; 10, 叶蜡石)
    Optical images of diamond synthesized in FeNiMnCo-C system.FeNiMnCo-C体系中所合成的金刚石光学照片
    Fig. 2. Optical images of diamond synthesized in FeNiMnCo-C system.FeNiMnCo-C体系中所合成的金刚石光学照片
    FTIR spectra of diamond co-doped with B and S: (a) With 1.2% B and 2.0% S additives; (b) with 0.8% B and 2.0% S additives.硼硫协同掺杂金刚石的红外光谱 (a)添加1.2%硼和添加2.0%硫; (b)添加0.8%硼和添加2.0%硫
    Fig. 3. FTIR spectra of diamond co-doped with B and S: (a) With 1.2% B and 2.0% S additives; (b) with 0.8% B and 2.0% S additives.硼硫协同掺杂金刚石的红外光谱 (a)添加1.2%硼和添加2.0%硫; (b)添加0.8%硼和添加2.0%硫
    Band structures of the synthesized diamond: (a) Without B or S additive; (b) with 2.0% S additive; (c) with 1.2% B and 2.0% S additives; (d) with 0.8% B and 2.0% S additives.金刚石能带结构 (a)未添加硼与硫; (b)添加2.0%硫; (c)添加1.2%硼和2.0%硫; (d)添加0.8%硼和2.0%硫
    Fig. 4. Band structures of the synthesized diamond: (a) Without B or S additive; (b) with 2.0% S additive; (c) with 1.2% B and 2.0% S additives; (d) with 0.8% B and 2.0% S additives.金刚石能带结构 (a)未添加硼与硫; (b)添加2.0%硫; (c)添加1.2%硼和2.0%硫; (d)添加0.8%硼和2.0%硫
    SampleB/%S/%温度/℃颜色
    (a)1280黄色
    (b)2.01280黄色
    (c)1.21280黄黑色
    (d)1.22.01300黑色
    (e)0.82.01290黄色
    Table 1. Parameters of the synthetic experiments of diamond performed at 6.5 GPa in the FeNiMnCo-C system.
    Sample电阻率/Ω·cm载流子浓度/cm–3迁移率/cm–2·V–1·s–1Hall系数
    (a)> 10 8
    (b)4.417 × 1065.383 × 109262.853–1.151 × 109
    (c)3.665 × 1031.364 × 101612.54.586 × 104
    (d)8.5106.652 × 1014760.8706.475 × 103
    (e)1.262 × 1068.738 × 101056.680–7.153 × 107
    Table 2. Electrical performance parameters of the diamond samples measured at room temperature ((a) without B or S additives, (b) with 2.0 wt.% S additive, (c) with 1.2% B additive, (d) with 1.2% B and 2.0% S additives, (e) with 0.8% B and 2.0% S additives).
    Yong Li, Ying Wang, Shang-Sheng Li, Zong-Bao Li, Kai-Wu Luo, Mao-Wu Ran, Mou-Sheng Song. Synthesis of diamond co-doped with B and S under high pressure and high temperature and electrical properties of the synthesized diamond[J]. Acta Physica Sinica, 2019, 68(9): 098101-1
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