Author Affiliations
1Department of Physics and Electrical Engineering, Tongren University, Tongren 554300, China2School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, Chinashow less
Fig. 1. Schematic of the cell for diamond synthesis (1, conductive ring; 2, graphite sheet; 3, NaCl tube; 4, ceramic cylinder and cover; 5, graphite heater; 6, catalyst; 7, carbon source; 8, insulation tube; 9, seed crystal; 10, pyrophyllite).金刚石合成腔体示意图(1, 钢帽; 2, 石墨片; 3, 氯化钠管; 4, 陶瓷堵头; 5, 石墨加热管; 6, 触媒; 7, 碳源; 8, 绝缘管; 9, 晶种; 10, 叶蜡石)
Fig. 2. Optical images of diamond synthesized in FeNiMnCo-C system.FeNiMnCo-C体系中所合成的金刚石光学照片
Fig. 3. FTIR spectra of diamond co-doped with B and S: (a) With 1.2% B and 2.0% S additives; (b) with 0.8% B and 2.0% S additives.硼硫协同掺杂金刚石的红外光谱 (a)添加1.2%硼和添加2.0%硫; (b)添加0.8%硼和添加2.0%硫
Fig. 4. Band structures of the synthesized diamond: (a) Without B or S additive; (b) with 2.0% S additive; (c) with 1.2% B and 2.0% S additives; (d) with 0.8% B and 2.0% S additives.金刚石能带结构 (a)未添加硼与硫; (b)添加2.0%硫; (c)添加1.2%硼和2.0%硫; (d)添加0.8%硼和2.0%硫
Sample | B/% | S/% | 温度/℃ | 颜色 | (a) | — | — | 1280 | 黄色 | (b) | — | 2.0 | 1280 | 黄色 | (c) | 1.2 | — | 1280 | 黄黑色 | (d) | 1.2 | 2.0 | 1300 | 黑色 | (e) | 0.8 | 2.0 | 1290 | 黄色 |
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Table 1. Parameters of the synthetic experiments of diamond performed at 6.5 GPa in the FeNiMnCo-C system.
Sample | 电阻率/Ω·cm | 载流子浓度/cm–3 | 迁移率/cm–2·V–1·s–1 | Hall系数 | (a) | > 10 8 | — | — | — | (b) | 4.417 × 106 | 5.383 × 109 | 262.853 | –1.151 × 109 | (c) | 3.665 × 103 | 1.364 × 1016 | 12.5 | 4.586 × 104 | (d) | 8.510 | 6.652 × 1014 | 760.870 | 6.475 × 103 | (e) | 1.262 × 106 | 8.738 × 1010 | 56.680 | –7.153 × 107 |
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Table 2. Electrical performance parameters of the diamond samples measured at room temperature ((a) without B or S additives, (b) with 2.0 wt.% S additive, (c) with 1.2% B additive, (d) with 1.2% B and 2.0% S additives, (e) with 0.8% B and 2.0% S additives).