• Chinese Journal of Lasers
  • Vol. 51, Issue 10, 1002302 (2024)
Shujing Shi1, Zhuo Li1、2、*, Chen Yang2, Ziheng Zeng2, Xu Cheng1、2, Haibo Tang1、2, and Huaming Wang1、2
Author Affiliations
  • 1Ningbo Institute of Technology, Beihang University, Ningbo 315800, Zhejiang , China
  • 2National Engineering Laboratory of Additive Manufacturing for Large Metallic Components, Beihang University, Beijing 100191, China
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    DOI: 10.3788/CJL231577 Cite this Article Set citation alerts
    Shujing Shi, Zhuo Li, Chen Yang, Ziheng Zeng, Xu Cheng, Haibo Tang, Huaming Wang. Research Progress on Crack Control and Composition Design of γ′ Phase Strengthened Nickel‑Based Superalloys Suitable for Laser Additive Manufacturing (Invited)[J]. Chinese Journal of Lasers, 2024, 51(10): 1002302 Copy Citation Text show less
    Material‒structure‒performance integrated LAM technology in multifunctional design and manufacturing[7]
    Fig. 1. Material‒structure‒performance integrated LAM technology in multifunctional design and manufacturing[7]
    Morphology and cracking mechanism of solidification crack in LAM nickel-based superalloys. (a) Correlation between solid phase fraction and solidification cracking index (SCI)[24]; (b) schematic diagram of cracking mechanism[25]; (c) solidification crack in CM247LC alloy[24]; (d) solidification crack in IN939 alloy[24]
    Fig. 2. Morphology and cracking mechanism of solidification crack in LAM nickel-based superalloys. (a) Correlation between solid phase fraction and solidification cracking index (SCI)[24]; (b) schematic diagram of cracking mechanism[25]; (c) solidification crack in CM247LC alloy[24]; (d) solidification crack in IN939 alloy[24]
    Morphology and cracking mechanism of liquation crack in LAM nickel-based superalloys. (a) Constitutional liquation[1,24];
    Fig. 3. Morphology and cracking mechanism of liquation crack in LAM nickel-based superalloys. (a) Constitutional liquation[1,24];
    Differential scanning calorimetry curves and morphology of ABD-850AM, CM247LC and IN939 alloys[24]
    Fig. 4. Differential scanning calorimetry curves and morphology of ABD-850AM, CM247LC and IN939 alloys[24]
    DDC and its relationship with temperature in LAM nickel-based superalloys. (a) Morphology of DDC in IN738 alloy[34];
    Fig. 5. DDC and its relationship with temperature in LAM nickel-based superalloys. (a) Morphology of DDC in IN738 alloy[34];
    Calculation and design of formable new γ' phase strengthened nickel-based superalloys. (a) Relationship between SAC risk and Al, Ti+Nb+Ta contents[24]; (b) γ' phase morphology and size in different generations of nickel-based single crystal superalloys[40]; (c) relationship between mole fraction of γ' phase and SAC merit index[24]; (d) relationship between creep life and SAC merit index[24]
    Fig. 6. Calculation and design of formable new γ' phase strengthened nickel-based superalloys. (a) Relationship between SAC risk and Al, Ti+Nb+Ta contents[24]; (b) γ' phase morphology and size in different generations of nickel-based single crystal superalloys[40]; (c) relationship between mole fraction of γ' phase and SAC merit index[24]; (d) relationship between creep life and SAC merit index[24]
    Relationship between the integrity of LAM component and process parameters and alloy composition[9,37]. (a) Defects caused by incompatibility between laser process parameters and alloy composition; (b) influence of composition optimization on solidification characteristics and formability of alloys
    Fig. 7. Relationship between the integrity of LAM component and process parameters and alloy composition[9,37]. (a) Defects caused by incompatibility between laser process parameters and alloy composition; (b) influence of composition optimization on solidification characteristics and formability of alloys
    Inhibitory effect of composition modification on crack in nickel-based superalloys. (a) Mechanism of reduced cracking sensitivity in new γ' phase strengthened MAD542 alloy[41]; (b) influence of Zr content on crack density, size and quantity of carbide and ΔT of IN738LC alloy[45]
    Fig. 8. Inhibitory effect of composition modification on crack in nickel-based superalloys. (a) Mechanism of reduced cracking sensitivity in new γ' phase strengthened MAD542 alloy[41]; (b) influence of Zr content on crack density, size and quantity of carbide and ΔT of IN738LC alloy[45]
    Inhibitory effect of adding nanoparticles on crack in nickel-based superalloys. (a) Influence of 2.5% TiC on grain morphology and solute enrichment in IN738LC alloy[51]; (b) influence of 0.1% GNPs on grain morphology and dislocation distribution in K418 alloy[52]
    Fig. 9. Inhibitory effect of adding nanoparticles on crack in nickel-based superalloys. (a) Influence of 2.5% TiC on grain morphology and solute enrichment in IN738LC alloy[51]; (b) influence of 0.1% GNPs on grain morphology and dislocation distribution in K418 alloy[52]
    Defect control and mechanical properties of LAM IN738LC alloy[18]. (a) Formability of IN738LC alloy under different laser powers and scanning speeds; (b) LPBF process map of IN738LC alloy; (c) influence of post-processing on tensile properties of as-printed samples at room temperature; (d) jet turbine blade fabricated by LPBF
    Fig. 10. Defect control and mechanical properties of LAM IN738LC alloy[18]. (a) Formability of IN738LC alloy under different laser powers and scanning speeds; (b) LPBF process map of IN738LC alloy; (c) influence of post-processing on tensile properties of as-printed samples at room temperature; (d) jet turbine blade fabricated by LPBF
    Thermodynamics-guided LAM superalloy design process[72]. (a) Interdendritic composition segregation measured by APT; (b) influence of partitioning behavior of alloy element on Tsolidus; (c) influence of alloy element on driving forces of phase formation, and a schematic diagram of the whole design process
    Fig. 11. Thermodynamics-guided LAM superalloy design process[72]. (a) Interdendritic composition segregation measured by APT; (b) influence of partitioning behavior of alloy element on Tsolidus; (c) influence of alloy element on driving forces of phase formation, and a schematic diagram of the whole design process
    Prediction of crack susceptibility in LAM nickel-based superalloy[76]. (a) Construction process of ML model; (b) fitting performance of ML models on training sets; (c) comprehensive influence of elements on crack susceptibility evaluated by ML prediction model
    Fig. 12. Prediction of crack susceptibility in LAM nickel-based superalloy[76]. (a) Construction process of ML model; (b) fitting performance of ML models on training sets; (c) comprehensive influence of elements on crack susceptibility evaluated by ML prediction model
    Relationship between composition and formability of nickel-based superalloys. (a) Formability of nickel-based superalloys represented by the contents of Al+Ti and Cr+Co[38]; (b) composition distribution of formable/unformable superalloys in Cr¯‒Al¯ system
    Fig. 13. Relationship between composition and formability of nickel-based superalloys. (a) Formability of nickel-based superalloys represented by the contents of Al+Ti and Cr+Co[38]; (b) composition distribution of formable/unformable superalloys in Cr¯Al¯ system
    Cracking resistance and mechanical properties of MNiHEA alloy[93]. (a) Relationship between average SCI value and solidification cracking in the last solidification stage; (b) uniaxial tensile engineering stress-strain curves; (c) strengthening and toughening mechanisms of as-built and aged alloys
    Fig. 14. Cracking resistance and mechanical properties of MNiHEA alloy[93]. (a) Relationship between average SCI value and solidification cracking in the last solidification stage; (b) uniaxial tensile engineering stress-strain curves; (c) strengthening and toughening mechanisms of as-built and aged alloys
    Research on cracking behavior of LAM γ' phase strengthened nickel-based superalloys. (a) Summary of cracks causes and control methods[66]; (b) comparison of room-temperature tensile properties of representative formable and unformable superalloys before and after crack control[1]
    Fig. 15. Research on cracking behavior of LAM γ' phase strengthened nickel-based superalloys. (a) Summary of cracks causes and control methods[66]; (b) comparison of room-temperature tensile properties of representative formable and unformable superalloys before and after crack control[1]
    Alloy elementMetallurgical performance
    Co, Cr, Fe, Mo, W, Ta, ReSolid-solution strengthener
    W, Ta, Ti, Mo, Nb, HfCarbide formMC
    CrM7C3
    Cr, Mo, WM23C6
    Mo, W, NbM6C
    C, NCarbonitrides: M(CN)
    Al, Tiγ′-Ni3 (Al, Ti) phase
    CoSolvus temperature of γ′ phase
    Al, Ti, Nb, TaIntermetallics
    Al, Cr, Y, La, CeOxidation resistance
    La, ThHot corrosion resistance
    Cr, Co, SiSulfidation
    B, TaCreep resistance
    BRupture strength
    B, C, Zr, HfGrain refinement
    ReRetard γ′ coarsening
    Table 1. Effects of elements on the metallurgical performance of γ' phase strengthened nickel-based superalloys[16]
    AlloyCompositionCluster formula
    IN100Ni57.6Co12.6Al11.1Ti5.1V1.1Cr10.3 Mo2[Al‒Ni¯12Al¯1.8Cr¯2.1
    MAR-M247Ni62Co10.1Al12.3Ti1.2Ta1Cr9.8Mo0.4W3.2[Al‒Ni¯12Al¯1.5Cr¯2.2
    CMSX-4Ni63.6Co9.3Re1Al12.6Ti1.3Ta2.2Cr7.6Mo0.4W2[Al‒Ni¯12Al¯1.6Cr¯1.6
    René N5Ni63.3Co8.4Re1.1Al13.9Ta2.3Cr8.1Mo1.2W1.7[Al‒Ni¯12Al¯1.7Cr¯1.8
    René 142Ni60.7Co12.2Re0.9Al13.8Ta2.1Cr7.8Mo0.9W1.6[Al‒Ni¯12Al¯1.5Cr¯1.7
    IN738LCNi59.1Co8.3Fe0.2Al7.6Ti4.1Nb0.6Ta0.6Cr17.5Mo1.1W0.9[Al‒Ni¯12Al¯1.2Cr¯3.5
    U700Ni49.6Co17.4Fe1Al8.9Ti4.1Cr16Mo3[Al‒Ni¯12Al¯1.3Cr¯3.4
    René 80Ni59.5Co8.9Al6.4Ti6.1Cr15.3Mo2.5W1.3[Al‒Ni¯12Al¯1.1Cr¯3.3
    IN738Ni60.2Co8.2Al7.2Ti4Nb0.6Ta0.5Cr17.5Mo1W0.8[Al‒Ni¯12Al¯1.2Cr¯3.4
    K418Ni68.7Fe1Al12.6Ti0.8Nb1.2Cr13.2Mo2.5[Al‒Ni¯12Al¯1.5Cr¯2.7
    CM247LCNi67Co9Al12.4Ti0.9Ta1Cr6.8Mo0.3W2.6[Al‒Ni¯12Al¯1.3Cr¯1.5
    IN939Ni48.2Co17.9Al4Ti4.4Nb0.6Cr24.4W0.5[Al‒Ni¯12Al¯0.6Cr¯4.5
    RR1000Ni52.6Co17.8Al5.5Ti4.1Ta0.6Cr16.4Mo3[Al‒Ni¯12Al¯0.7Cr¯3.3
    WaspaloyNi56.5Co13.3Al2.7Ti3.6Cr21.3Mo2.6[Al‒Ni¯12Al¯0.1Cr¯4.1
    René 41Ni61.4Co10.8Al3.1Ti3.6Cr20.5Mo0.6[Al‒Ni¯12Al¯0.1Cr¯3.5
    Haynes 282Ni55.6Co9.8Fe1.6Al3.2Ti2.5Cr22.2Mo5.1[Al‒Ni¯12Cr¯4.9
    IN718Ni52.3Fe19.3Al1.1Ti1.1Nb3.2Cr21.2Mo1.8[(Al¯0.9Cr¯0.1)‒Ni¯12Cr¯3.8
    IN625Ni64Fe2.7Al0.4Ti0.3Nb2.3Cr24.8Mo5.5[(Al¯0.5Cr¯0.5)‒Ni¯12Cr¯5
    Hastelloy-XNi48.3Co1.4Fe19.3Al0.5Cr24.7Mo5.5W0.3[(Al¯0.1Cr¯0.9)‒Ni¯12Cr¯4.4
    Table 2. Composition and cluster formula analysis of nickel-based superalloys[44,82,84-86]
    Shujing Shi, Zhuo Li, Chen Yang, Ziheng Zeng, Xu Cheng, Haibo Tang, Huaming Wang. Research Progress on Crack Control and Composition Design of γ′ Phase Strengthened Nickel‑Based Superalloys Suitable for Laser Additive Manufacturing (Invited)[J]. Chinese Journal of Lasers, 2024, 51(10): 1002302
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