• Journal of Radiation Research and Radiation Processing
  • Vol. 41, Issue 1, 010202 (2023)
Qingru LIANG1, Zhenyan JI2, Chunlei DONG2, Fan ZHANG2, Zhe XING2、**, Yarui AN1, and Guozhong WU2、3、*
Author Affiliations
  • 1University of Shanghai Science and Technology, Shanghai 200093, China
  • 2Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  • 3Shanghai Tech University, Shanghai 200031, China
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    DOI: 10.11889/j.1000-3436.2022-0107 Cite this Article
    Qingru LIANG, Zhenyan JI, Chunlei DONG, Fan ZHANG, Zhe XING, Yarui AN, Guozhong WU. Epoxy-functionalized polyethylene-octene prepared by γ-ray radiation and its application in polyamide 6 toughening modification[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(1): 010202 Copy Citation Text show less
    Flow chart of POE-g-PGMA preparation
    Fig. 1. Flow chart of POE-g-PGMA preparation
    FTIR Spectra of POE, non-irradiated-POE-GMA and irradiated-POE-g-PGMA
    Fig. 2. FTIR Spectra of POE, non-irradiated-POE-GMA and irradiated-POE-g-PGMA
    Fracture-surface morphologies of PA6 and PA6/POE blends with different POE-g-PGMA contents: (a) PA6; (b) G0;(c) G1; (d) G2; (e) G3
    Fig. 3. Fracture-surface morphologies of PA6 and PA6/POE blends with different POE-g-PGMA contents: (a) PA6; (b) G0;(c) G1; (d) G2; (e) G3
    Schematic diagram of mechanical specimens and mechanical property curves of blends with different POE-g-PGMA contents: (a) tensile test specimens; (b) tested tensile test specimena; (c) tensile strength and elongation at break curve; (d) flexural strength and notched impact strength curve
    Fig. 4. Schematic diagram of mechanical specimens and mechanical property curves of blends with different POE-g-PGMA contents: (a) tensile test specimens; (b) tested tensile test specimena; (c) tensile strength and elongation at break curve; (d) flexural strength and notched impact strength curve
    DSC curves of PA6 and PA6/POE blends with different POE-g-PGMA contents: (a) melting curves; (b) crystallization curves (color online)
    Fig. 5. DSC curves of PA6 and PA6/POE blends with different POE-g-PGMA contents: (a) melting curves; (b) crystallization curves (color online)
    TG curves of PA6 and PA6/POE blends with different POE-g-PGMA contents (color online)
    Fig. 6. TG curves of PA6 and PA6/POE blends with different POE-g-PGMA contents (color online)
    Interface compatibility diagram of PA6/POE blends with different POE-g-PGMA contents: (a) pure POE, (b) pure POE-g-PGMA, (c) pure PA6, (d) the uncompatibilized G0 blend, and (e) the compatibilized G2 blend
    Fig. 7. Interface compatibility diagram of PA6/POE blends with different POE-g-PGMA contents: (a) pure POE, (b) pure POE-g-PGMA, (c) pure PA6, (d) the uncompatibilized G0 blend, and (e) the compatibilized G2 blend
    Hygroscopic coefficient as a function of POE-g-PGMA content in PA6/POE blends: (a) 0~768 h hygroscopic coefficient curve; (b) hygroscopic coefficient curve of different POE-g-PGMA contents at 768 h
    Fig. 8. Hygroscopic coefficient as a function of POE-g-PGMA content in PA6/POE blends: (a) 0~768 h hygroscopic coefficient curve; (b) hygroscopic coefficient curve of different POE-g-PGMA contents at 768 h

    样品

    Sample description

    PA6

    / %

    POE

    / %

    POE-g-PGMA

    / %

    PA610000
    POE01000
    PA6/POE/PG090100

    PA6/POE/PG1

    PA6/POE/PG2

    PA6/POE/PG3

    90

    90

    90

    10

    10

    10

    1

    2

    3

    Table 1. Composition of the samples
    样品 Sample

    Tm

    / °C

    Tc

    / °C

    Hm

    / (J·g-1)

    Hc

    / (J·g-1)

    Crystallinity/%

    Tloss,5%

    / ℃

    PA6221.47167.8260.7356.3724.50382
    POE-----438
    G0221.56185.8952.8962.4427.14400
    G1221.98185.3248.3960.2126.17399
    G2221.40186.4852.0666.6628.97401
    G3221.45185.1446.8255.8824.28405
    Table 2. Thermal properties of the blends from DSC
    Qingru LIANG, Zhenyan JI, Chunlei DONG, Fan ZHANG, Zhe XING, Yarui AN, Guozhong WU. Epoxy-functionalized polyethylene-octene prepared by γ-ray radiation and its application in polyamide 6 toughening modification[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(1): 010202
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