• Acta Physica Sinica
  • Vol. 68, Issue 21, 217701-1 (2019)
Li-Feng Zhu1, Wen-Yuan Pan1, Yan Xie1, Bo-Ping Zhang1、*, Yang Yin1, and Gao-Lei Zhao2、*
Author Affiliations
  • 1School of Material Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
  • 2Institute of Acoustics, Chinese Academy of Sciences, Beijing 100190, China
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    DOI: 10.7498/aps.68.20190996 Cite this Article
    Li-Feng Zhu, Wen-Yuan Pan, Yan Xie, Bo-Ping Zhang, Yang Yin, Gao-Lei Zhao. Effect of regulation of defect ion on ferroelectric photovoltaic characteristics of BiFeO3-BaTiO3 based perovskite materials [J]. Acta Physica Sinica, 2019, 68(21): 217701-1 Copy Citation Text show less
    X-ray diffraction patterns of BFM0.02–xT0.02+x-BT ceramics with different x content (0 ≤ x ≤ 0.02) in a selected 2θ range of 20°—70° (a), 38°—40° and 43.5°—46.5° (b).BFM0.02–xT0.02+x-BT (0 ≤ x ≤ 0.02)基陶瓷的XRD图谱 (a) 20°—70°; (b) 38°—40°, 43.5°—46.5°
    Fig. 1. X-ray diffraction patterns of BFM0.02–xT0.02+x-BT ceramics with different x content (0 ≤ x ≤ 0.02) in a selected 2θ range of 20°—70° (a), 38°—40° and 43.5°—46.5° (b). BFM0.02–xT0.02+x-BT (0 ≤ x ≤ 0.02)基陶瓷的XRD图谱 (a) 20°—70°; (b) 38°—40°, 43.5°—46.5°
    SEM images of the fracture surface for BFM0.02–xT0.02+x-BT ceramics with different x content (0 ≤ x ≤ 0.02).BFM0.02–xT0.02+x-BT陶瓷样品的SEM形貌图
    Fig. 2. SEM images of the fracture surface for BFM0.02–xT0.02+x-BT ceramics with different x content (0 ≤ x ≤ 0.02). BFM0.02–xT0.02+x-BT陶瓷样品的SEM形貌图
    Ferroelectric hysteresis loops (a), the variation of polarization (Pr) and electric field (EC) (b), leakage current density (I)-electric field (E) (c), as well as the piezoelectric coefficient d33, planar mode eletromechanical coupling coefficient kp (d) as a function of x for BFM0.02–xT0.02+x-BT (0 ≤ x ≤ 0.02).BFM0.02–xT0.02+x-BT陶瓷样品的(a)电滞回线, (b)剩余极化Pr和矫顽场EC随含量x的变化, (c)漏电流I-E曲线, 以及(d)压电性能d33和kp随含量x的变化
    Fig. 3. Ferroelectric hysteresis loops (a), the variation of polarization (Pr) and electric field (EC) (b), leakage current density (I)-electric field (E) (c), as well as the piezoelectric coefficient d33, planar mode eletromechanical coupling coefficient kp (d) as a function of x for BFM0.02–xT0.02+x-BT (0 ≤ x ≤ 0.02). BFM0.02–xT0.02+x-BT陶瓷样品的(a)电滞回线, (b)剩余极化Pr和矫顽场EC随含量x的变化, (c)漏电流I-E曲线, 以及(d)压电性能d33kp随含量x的变化
    UV-vis-NIR absorption spectra of the BFM0.02–xT0.02+x-BT ceramics with different x content (0 ≤ x ≤ 0.02).BFM0.02–xT0.02+x-BT铁电陶瓷的光吸收谱图
    Fig. 4. UV-vis-NIR absorption spectra of the BFM0.02–xT0.02+x-BT ceramics with different x content (0 ≤ x ≤ 0.02). BFM0.02–xT0.02+x-BT铁电陶瓷的光吸收谱图
    Plots of (αhν)1/2 versus hν for the BFM0.02–xT0.02+x-BT ceramics with different x content: (a) x= 0; (b) x = 0.005; (c) x = 0.01; (d) x = 0.02.BFM0.02–xT0.02+x-BT铁电陶瓷的(αhν)1/2-(hν)曲线 (a) x = 0; (b) x = 0.005; (c) x = 0.01; (d) x = 0.02
    Fig. 5. Plots of (αhν)1/2 versus for the BFM0.02–xT0.02+x-BT ceramics with different x content: (a) x= 0; (b) x = 0.005; (c) x = 0.01; (d) x = 0.02. BFM0.02–xT0.02+x-BT铁电陶瓷的(αhν)1/2-()曲线 (a) x = 0; (b) x = 0.005; (c) x = 0.01; (d) x = 0.02
    J-t characteristics of BFMT-BT ceramics, which are polarized at different voltage: (I) V = 0 kV; (II) V = 1 kV; (III) V = 2 kV; (IV) V = 3 kV.BFMT-BT铁电陶瓷的光电流密度-时间(J-t)曲线图, 其中(I)区为未极化; (II)区为1 kV下极化; (III)区为2 kV下极化; (IV)区为3 kV下极化
    Fig. 6. J-t characteristics of BFMT-BT ceramics, which are polarized at different voltage: (I) V = 0 kV; (II) V = 1 kV; (III) V = 2 kV; (IV) V = 3 kV. BFMT-BT铁电陶瓷的光电流密度-时间(J-t)曲线图, 其中(I)区为未极化; (II)区为1 kV下极化; (III)区为2 kV下极化; (IV)区为3 kV下极化
    J-V characteristics of BFM0.02–xT0.02+x-BT ceramics with different x content: (a) x = 0; (b) x = 0.005; (c) x = 0.01; (d) x = 0.02BFM0.02–xT0.02+x-BT铁电陶瓷的光电流密度-电压(J-V)曲线图 (a) x = 0; (b) x = 0.005; (c) x = 0.01; (d) x = 0.02
    Fig. 7. J-V characteristics of BFM0.02–xT0.02+x-BT ceramics with different x content: (a) x = 0; (b) x = 0.005; (c) x = 0.01; (d) x = 0.02 BFM0.02–xT0.02+x-BT铁电陶瓷的光电流密度-电压(J-V)曲线图 (a) x = 0; (b) x = 0.005; (c) x = 0.01; (d) x = 0.02
    Schematic diagram of photovoltaic effect for BFM0.02–xT0.02+x-BT ceramics, non-polarization and dark condition (a), non-polarization and light condition (b), polarization and dark condition (c), as well as polarization and light condition (d), respectively.BFM0.02–xT0.02+x-BT铁电陶瓷光伏效应原理图 (a)未极化、无光条件; (b)未极化、有光条件; (c)极化、无光条件; (d)极化、光照条件
    Fig. 8. Schematic diagram of photovoltaic effect for BFM0.02–xT0.02+x-BT ceramics, non-polarization and dark condition (a), non-polarization and light condition (b), polarization and dark condition (c), as well as polarization and light condition (d), respectively. BFM0.02–xT0.02+x-BT铁电陶瓷光伏效应原理图 (a)未极化、无光条件; (b)未极化、有光条件; (c)极化、无光条件; (d)极化、光照条件
    Li-Feng Zhu, Wen-Yuan Pan, Yan Xie, Bo-Ping Zhang, Yang Yin, Gao-Lei Zhao. Effect of regulation of defect ion on ferroelectric photovoltaic characteristics of BiFeO3-BaTiO3 based perovskite materials [J]. Acta Physica Sinica, 2019, 68(21): 217701-1
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