Min-Qiang Gai, Ying Wang, Shi-Lie Pan. Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F2[J]. Acta Physica Sinica, 2019, 68(2): 024208-1

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- Acta Physica Sinica
- Vol. 68, Issue 2, 024208-1 (2019)

Fig. 1. Crystal structure model of KBBF family.KBBF族晶体结构模型

Fig. 2. Second harmonic generation evolution from KBBF to Pb2BO3I.
从KBBF 到Pb2BO3I的倍频效应演进
![Ball-and-stick representations of NH4Be2BO3F2(ABBF)[79,80].NH4Be2BO3F2 (ABBF)晶体结构模型[79,80]](/Images/icon/loading.gif)
![Ball-and-stick representations of AZn2BO3X2 (A = K, Rb, NH4) series[63−81]: (a) NH4Zn2BO3Cl2; (b) KZn2BO3Cl2; (c) RbZn2BO3Cl2.AZn2BO3X2 (A = K, Rb, NH4)系列晶体结构模型[63−81] (a) NH4Zn2BO3Cl2; (b) KZn2BO3Cl2; (c) RbZn2BO3Cl2](/Images/icon/loading.gif)
Fig. 4. Ball-and-stick representations of A Zn2BO3X 2 (A = K, Rb, NH4) series[63−81]: (a) NH4Zn2BO3Cl2; (b) KZn2BO3Cl2; (c) RbZn2BO3Cl2.
A Zn2BO3X 2 (A = K, Rb, NH4)系列晶体结构模型[63−81] (a) NH4Zn2BO3Cl2; (b) KZn2BO3Cl2; (c) RbZn2BO3Cl2
![Ball-and-stick representations of KABO series[50−52]: (a) K2Al2B2O7; (b) -Rb2Al2B2O7.KABO系列晶体结构模型[50−52] (a) K2Al2B2O7; (b) -Rb2Al2B2O7](/Images/icon/loading.gif)
Fig. 5. Ball-and-stick representations of KABO series[50−52]: (a) K2Al2B2O7; (b)
-Rb2Al2B2O7.
KABO系列晶体结构模型[50−52] (a) K2Al2B2O7; (b)
-Rb2Al2B2O7
![Ball-and-stick representations of Ba3Mg3(BO3)3F3[87]: (a) Sr2Be2B2O7; (b) Ba3Mg3(BO3)3F3.Ba3Mg3(BO3)3F3晶体结构模型[87] (a) Sr2Be2B2O7; (b) Ba3Mg3(BO3)3F3](/Images/icon/loading.gif)
Fig. 6. Ball-and-stick representations of Ba3Mg3(BO3)3F3[87]: (a) Sr2Be2B2O7; (b) Ba3Mg3(BO3)3F3.
Ba3Mg3(BO3)3F3晶体结构模型[87] (a) Sr2Be2B2O7; (b) Ba3Mg3(BO3)3F3

Fig. 7. Ball-and-stick representations of Sr2Be2B2O7 and BaAl2B2O7.
Sr2Be2B2O7和BaAl2B2O7晶体结构模型

Fig. 8. Ball-and-stick representations of K3Sr3Li2Al4B6O20F and K3Ba3Li2Al4B6O20F (KBLABF).
K3Sr3Li2Al4B6O20F和K3Ba3Li2Al4B6O20F (KBLABF)的晶体结构模型
![Relationship of active group balance of fluorooxoborates among bandgap, NLO coefficient and birefringence[68].氟化硼酸盐的活性基团平衡“倍频效应-透过范围-双折射率”的关系[68]](/Images/icon/loading.gif)
Fig. 9. Relationship of active group balance of fluorooxoborates among bandgap, NLO coefficient and birefringence[68].
氟化硼酸盐的活性基团平衡“倍频效应-透过范围-双折射率”的关系[68]
![Crystal structures of the MB4O6F family[92].MB4O6F族氟化硼酸盐的晶体结构[92]](/Images/icon/loading.gif)

Fig. 11. Crystal structures of the series borates contain B—O covalent bond.层间由B—O共价键连接的系列硼酸盐晶体结构
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Table 1.
Cmparison of structural and optical properties of some deep-UV NLO materials of KBBF family with adjacent layers connected by ionic bond and hydrogen bond.
层间含有离子键和氢键连接的类KBBF结构硼酸盐深紫外NLO材料的结构和光学性能比较
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Table 2.
Comparison of structural and optical properties of some deep-UV NLO materials of SBBO family.
SBBO型硼酸盐深紫外NLO材料的结构和光学性能比较
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Table 3.
Comparison of structural and optical properties of some fluorooxoborates deep-UV NLO materials.
部分氟化硼酸盐深紫外NLO材料的结构和光学性能比较
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Table 4.
Comparison of structural and optical properties of some deep-UV NLO materials of KBBF family with adjacent layers connected by rigid B—O groups.
层间含有B—O共价键连接的类KBBF结构硼酸盐深紫外NLO材料的结构和光学性能比较
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