Author Affiliations
1Key Laboratory of Transparent and Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, China2Key Laboratory for Laser Plasmas (Ministry of Education), Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240, China3Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900, China4University of Chinese Academy of Sciences, Beijing 100049, Chinashow less
Fig. 1. Room-temperature absorption spectra of (a) the 0.5% Nd:CaF2 crystal, which is 484–1000 nm and (b) the 0.5% Nd, 10% Y:CaF2 crystal, which is 767-835 nm.
Fig. 2. Room temperature emission spectra of the 0.5% Nd:CaF2 and 0.5% Nd, 10% Y:CaF2 crystals.
Fig. 3. (a) The room-temperature absorption spectra of the Nd3+I49/2→F45/2+H29/2 transition. (b) The absorption cross section at 790 and 797 nm for x (x=0.4%, 0.5%, 0.6%, 0.8%) Nd, 10% Y:CaF2 crystals.
Fig. 4. Room-temperature emission spectra of x(x=0.4%,0.5%,0.6%,0.8%) Nd, 10% Y:CaF2 crystals.
Fig. 5. Schematic of the CW laser setup: LD, laser diode; LS=L=500 mm; OC: output coupler with a transmission of 2%.
Fig. 6. Laser output power versus absorbed pump power curves for x(x=0.4%,0.5%,0.6%,0.8%) Nd, 10% Y:CaF2 crystals.
Crystal | () | () | () | (nm) | (nm) | (μs) | (μs) | (%) | () |
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| 1.1082 | 3.6337 | 4.3470 | 1062 | 33.21 | 1091 | 17.99 | 1.65 | 2.28 | | 0.1585 | 3.2329 | 3.5231 | 1054 | 28.03 | 657.47 | 361.27 | 54.95 | 4.27 |
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Table 1. Judd–Ofelt Parameters Ω2, Ω4, Ω6, Maximum Emission Peak (λem), FWHM (Δλ), Radiative Emission Lifetime (τrad), Fluorescence Lifetime (τexp), Fluorescence Quantum Efficiency (η) and Maximum Emission Cross Section (σem) for 0.5% Nd:CaF2 and 0.5% Nd, 10% Y:CaF2 Crystals
Crystal | () | () | () | (nm) | (nm) | (μs) | (μs) | (%) | () |
---|
| 0.6077 | 2.8032 | 3.0639 | 1054 | 29.99 | 795.09 | 350.62 | 46.19 | 3.36 | | 0.1585 | 3.2329 | 3.5231 | 1054 | 28.51 | 657.47 | 361.27 | 54.95 | 4.27 | | 0.4121 | 2.2806 | 4.0231 | 1054 | 28.96 | 693.22 | 359.40 | 51.85 | 3.99 | | 0.3477 | 2.9516 | 3.5851 | 1054 | 29.98 | 677.26 | 320.97 | 47.39 | 3.94 |
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Table 2. Spectroscopic Properties of x(x=0.4%,0.5%,0.6%,0.8%) Nd, 10% Y:CaF2 Crystals