Research on light scattering from a large chiral sphere shows that the rainbow phenomenon is different from that of an isotropic sphere. A chiral sphere with certain chirality generates three first-order rainbows. In this Letter, we present a geometric optics interpretation for the phenomenon and make a calculation of the rainbow angles. The ray traces inside the sphere are determined by the reflection and refraction laws of light at the achiral–chiral interface and the chiral–achiral interface. The calculated rainbow angles achieve good agreements with those obtained by the analytical solutions. The effects of chirality and the refractive index of the sphere on rainbow angles are analyzed.