Atomization of droplets is ubiquitous in many natural and industrial processes, such as falling rain drops, inkjet printing, fuel injection in automotive and gas-turbine engines. Acoustic irradiation provides a very effective method of atomizing fluid. However, the acoustic atomization of acoustically levitated droplet is seldom studied. To assess the possibility of achieving ultrafine atomization, we, in this paper, systematically study the atomization of an acoustically levitated droplet placed in a hot gas of a flame. High speed camera is utilized to investigate the atomization characteristics of various droplets with diameters ranging from 0.5 mm to 3.5 mm.The experimental results show that the sound pressure of the resonance acoustic field has the ability to atomize the droplet when it is suddenly bathed in hot gas. Here the heating acts as a switch to convert the droplet surface from an acoustic isolator to conductor by heating the surface to strong evaporation. The presence of a high concentration of vapor molecules surrounding the droplet caused the acoustic field to change, thus, a much larger pressure gradient is established along the droplet surface, resulting in the atomization of droplet from the equator. Furthermore, Faraday wave stimulation and discretization on the film cause the droplet to further disintegrate when the droplet diameter is large enough. The atomization consists of three different styles, i.e. rim spray (RS), film disintegration (FD) and normal sputtering (NS). When exposed to hot gas, the droplets with equivalent diameter D₀ < 2.8 mm are depleted with RS until the whole mass is atomization. A thin rim is extruded at the equator and then splashed in the equator plane, the spray speed is around 9.5 m/s. Larger droplets end with the sudden FD of liquid film of the residual mass after the the RS has been consumed up. When the thickness of the rim and buckled film decrease to half of wave length, Faraday wave emerges, resulting in the vertical droplet ejection and the disintegration of the thin films. And the droplets with D₀ > 3.2 mm undergo further film buckling, forming a closed bubble due to the Helmholtz resonator effect and NS at the bottom. This sound driven atomization of droplets enriches the understanding of fluid mechanism in multi-physical fields, and may provide new ideas for relative application research.