• Acta Physica Sinica
  • Vol. 68, Issue 17, 178201-1 (2019)
Hong-Bin Yao, Xiang-Zhan Jiang, Chang-Hong Cao, and Wen-Liang Li*
DOI: 10.7498/aps.68.20190400 Cite this Article
Hong-Bin Yao, Xiang-Zhan Jiang, Chang-Hong Cao, Wen-Liang Li. Theoretical study of dissociation dynamics of HD+ and its quantum control with an intense laser field [J]. Acta Physica Sinica, 2019, 68(17): 178201-1 Copy Citation Text show less

Abstract

The dissociation dynamics of HD+ molecule in an intense field is investigated by using an accurate three-dimensional time-dependent wave packet approach. When the 790-nm laser pulse interacts with HD+ molecule, the lowest electronic 1sσ and 2pσ states are coupled. Due to the existence of the permanent electric dipole moment, the transitions in HD+ molecule involve the direct absorption of an odd and even number of photons, thereby opening different pathways for dissociation. The model of the photon-dressed states is presented to analyze the possible dissociation pathways of HD+ molecule. The laser-induced dissociation of HD+ molecule is mainly composed of the four pathways: the direct one-photon absorption, the net two-photon absorption, the direct two-photon absorption, and the direct two-photon absorption. To reveal the dissociation mechanism of HD+ molecule, the kinetic energy resolved spectra are calculated at the given laser intensities. It is found that the dissociation pathways are strongly dependent on laser intensity, especially for the net one-photon absorption dissociation and direct two-photon absorption dissociation. With further research, the dissociation pathways of HD+ are controlled by regulating the intensity of laser pulse. At a laser intensity of 4.0 × 1013 W/cm2, the kinetic energy resolved spectrum for the vibrational state ν = 3 includes the contributions from the net two-photon absorption dissociation and the direct two-photon absorption dissociation. For the vibrational state ν = 6, HD+ molecule is preferentially dissociated via the net one-photon absorption. However, the dissociation mechanism of HD+ molecule at the vibrational states ν = 3 and ν = 6 have significant changes as the laser intensity increases to 2.0 × 1014 W/cm2. For the vibrational state ν = 3, the branching ratio between the dissociation pathway of the net two-photon absorption and that of the direct two-photon absorption has a dramatic change with the increase of laser intensity. Compared with the kinetic energy resolved spectra at laser energy of 4.0 × 1013 W/cm2, the height of the dissociation peak from the net two-photon absorption decreases, and that of the direct two-photon absorption increases at laser intensity of 2.0 × 1014 W/cm2. For the vibrational state ν = 6, the dissociation process of the net one-photon absorption almost disappears at laser intensity of 2.0 × 1014 W/cm2, and it is replaced by the dissociation pathway of the direct two-photon absorption.
${\rm{i}}\frac{\partial }{{\partial t}}\psi ({{R}},{{r}},t) = [{H_0} + W(t)]\psi ({{R}},{{r}},t),$(1)

View in Article

${H_0} = {H_{\rm{n}}} + {H_{\rm{e}}},$(2)

View in Article

${H_{\rm{n}}} = {T_{\rm{n}}} + {V_{{\rm{nn}}}} = - \frac{1}{{2{\mu _{\rm{n}}}}}\frac{{{\partial ^2}}}{{\partial {R^2}}} + \frac{1}{R},$(3)

View in Article

$\begin{split} {H_{\rm{e}}} = & {T_{\rm{e}}} + {V_{{\rm{en}}}}\\ = & - \frac{1}{{2{\mu _{\rm{e}}}}}\left( {\frac{{{\partial ^2}}}{{\partial {\rho ^2}}} + \frac{1}{\rho }\frac{\partial }{{\partial \rho }} + \frac{{{\partial ^2}}}{{\partial {z^2}}}} \right)\\ & - \frac{1}{{\sqrt {{\rho ^2} + {{(z - {z_{\rm{p}}})}^2}} }} - \frac{1}{{\sqrt {{\rho ^2} + {{(z + {z_{\rm{d}}})}^2}} }}, \end{split}$(4)

View in Article

$W(t) = - E(t)\left( {\frac{{{m_{\rm{p}}} + {m_{\rm{d}}} + 2}}{{{m_{\rm{p}}} + {m_{\rm{d}}} + 1}}z - \frac{{{m_{\rm{d}}} - {m_{\rm{p}}}}}{{{m_{\rm{p}}} + {m_{\rm{d}}}}}R} \right),$(5)

View in Article

$f(t) = \exp \left[ { - {{\left( {\frac{t}{\tau }} \right)}^2}} \right],$(6)

View in Article

${{\rm{e}}^{ - {\rm{i}}H\Delta t}} \approx {{\rm{e}}^{ - {\rm{i}}{T_R}\Delta t/2}}{\{U_{\rm{e}}^{{\rm{SPO}}}(\Delta t/N)\}^N}{{\rm{e}}^{ - {\rm{i}}{T_R}\Delta t/2}},$(7)

View in Article

$U_{\rm{e}}^{{\rm{SPO}}}(\Delta t) = {{\rm{e}}^{ - {\rm{i}}{T_z}\Delta t/2}}{{\rm{e}}^{ - {\rm{i}}V\Delta t}}{{\rm{e}}^{ - {\rm{i}}{T_z}\Delta t/2}}$(8)

View in Article

Hong-Bin Yao, Xiang-Zhan Jiang, Chang-Hong Cao, Wen-Liang Li. Theoretical study of dissociation dynamics of HD+ and its quantum control with an intense laser field [J]. Acta Physica Sinica, 2019, 68(17): 178201-1
Download Citation