• Acta Physica Sinica
  • Vol. 69, Issue 3, 038501-1 (2020)
Run Wang1, Ya-Lan Jia1, Yue Zhang1, Xing-Juan Ma1, Qiang Xu1, Zhi-Xin Zhu1, Yan-Hong Deng2, Zu-Hong Xiong1, and Chun-Hong Gao1、2、*
Author Affiliations
  • 1School of Physical Science and Technology, Southwest University, Chongqing 400715, China
  • 2Applied Basic Research Base of Optoelectronic Information Technology of Hunan Province, Hengyang Normal University, Hengyang 421002, China
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    DOI: 10.7498/aps.69.20191263 Cite this Article
    Run Wang, Ya-Lan Jia, Yue Zhang, Xing-Juan Ma, Qiang Xu, Zhi-Xin Zhu, Yan-Hong Deng, Zu-Hong Xiong, Chun-Hong Gao. High efficiency green perovskite light-emitting diodes based on exciton blocking layer[J]. Acta Physica Sinica, 2020, 69(3): 038501-1 Copy Citation Text show less
    (a) Device structure of PeLEDs; (b) schematic energy level diagram of PeLEDs.(a) PeLEDs的器件结构; (b) PeLEDs的能级图
    Fig. 1. (a) Device structure of PeLEDs; (b) schematic energy level diagram of PeLEDs.(a) PeLEDs的器件结构; (b) PeLEDs的能级图
    EL performance of PeLEDs: (a) Current density-voltage (J-V); (b) luminance-voltage (L-V); (c) current-efficiency-voltage-external quantum efficiency (CE-V-EQE); (d) EL spectra of PeLEDs with 5 mg/mL TAPC at different applied voltages; the inset is normalized EL spectra of PeLEDs with different concentrations of TAPC at the same applied voltage of 5 V.PeLEDs的EL性能表征 (a)电流密度-电压; (b)亮度-电压; (c)电流效率-电压-外量子效率; (d) PeLEDs (TAPC浓度为5 mg/mL)在不同电压下的EL光谱, 内插图是不同TAPC浓度的PeLEDs在电压为5 V时的归一化EL谱
    Fig. 2. EL performance of PeLEDs: (a) Current density-voltage (J-V); (b) luminance-voltage (L-V); (c) current-efficiency-voltage-external quantum efficiency (CE-V-EQE); (d) EL spectra of PeLEDs with 5 mg/mL TAPC at different applied voltages; the inset is normalized EL spectra of PeLEDs with different concentrations of TAPC at the same applied voltage of 5 V. PeLEDs的EL性能表征 (a)电流密度-电压; (b)亮度-电压; (c)电流效率-电压-外量子效率; (d) PeLEDs (TAPC浓度为5 mg/mL)在不同电压下的EL光谱, 内插图是不同TAPC浓度的PeLEDs在电压为5 V时的归一化EL谱
    The EL stability of PeLEDs.PeLEDs的稳定性表征
    Fig. 3. The EL stability of PeLEDs.PeLEDs的稳定性表征
    SEM images of (a) ITO/PEDOT:PSS/CsPbBr3 and (b) ITO/PEDOT:PSS/TAPC/CsPbBr3; the size distribution of CsPbBr3 grain on (c) ITO/PEDOT:PSS/CsPbBr3 and (d) ITO/PEDOT:PSS/TAPC/CsPbBr3.(a) ITO/PEDOT:PSS/CsPbBr3和(b) ITO/PEDOT:PSS/TAPC/CsPbBr3样品的SEM图; (c) ITO/PEDOT:PSS/CsPbBr3和(d) ITO/PEDOT:PSS/TAPC/CsPbBr3样品的CsPbBr3颗粒尺寸统计分布
    Fig. 4. SEM images of (a) ITO/PEDOT:PSS/CsPbBr3 and (b) ITO/PEDOT:PSS/TAPC/CsPbBr3; the size distribution of CsPbBr3 grain on (c) ITO/PEDOT:PSS/CsPbBr3 and (d) ITO/PEDOT:PSS/TAPC/CsPbBr3. (a) ITO/PEDOT:PSS/CsPbBr3和(b) ITO/PEDOT:PSS/TAPC/CsPbBr3样品的SEM图; (c) ITO/PEDOT:PSS/CsPbBr3和(d) ITO/PEDOT:PSS/TAPC/CsPbBr3样品的CsPbBr3颗粒尺寸统计分布
    Characteristics of CsPbBr3 film on PEDOT:PSS and PEDOT:PSS/TAPC: (a) XRD; (b) absorption, and the inset is a large image of normalized PL spectra from 500 to 518 nm; (c) normalized PL spectra, and the inset is a large image of normalized PL spectra from 520 to 535 nm; (d) TRPL decay curves.在PEDOT:PSS和PEDOT:PSS/TAPC衬底上的CsPbBr3薄膜的表征 (a)晶体结构(XRD); (b)紫外吸收, 内插图是在500−518 nm波长范围吸收的放大图; (c) PL光谱, 内插图是在520−535 nm波长范围PL的放大图; (d) TRPL曲线
    Fig. 5. Characteristics of CsPbBr3 film on PEDOT:PSS and PEDOT:PSS/TAPC: (a) XRD; (b) absorption, and the inset is a large image of normalized PL spectra from 500 to 518 nm; (c) normalized PL spectra, and the inset is a large image of normalized PL spectra from 520 to 535 nm; (d) TRPL decay curves. 在PEDOT:PSS和PEDOT:PSS/TAPC衬底上的CsPbBr3薄膜的表征 (a)晶体结构(XRD); (b)紫外吸收, 内插图是在500−518 nm波长范围吸收的放大图; (c) PL光谱, 内插图是在520−535 nm波长范围PL的放大图; (d) TRPL曲线
    Current density-voltage characteristics of hole-dominated devices.单空穴器件的电流密度-电压特性曲线
    Fig. 6. Current density-voltage characteristics of hole-dominated devices.单空穴器件的电流密度-电压特性曲线
    Exciton recombination interface effects: (a) PEDOT: PSS/TAPC/CsPbBr3; (b) PEDOT:PSS/CsPbBr3.激子界面复合效应 (a) PEDOT:PSS/CsPbBr3; (b) PEDOT:PSS/TAPC/CsPbBr3
    Fig. 7. Exciton recombination interface effects: (a) PEDOT: PSS/TAPC/CsPbBr3; (b) PEDOT:PSS/CsPbBr3. 激子界面复合效应 (a) PEDOT:PSS/CsPbBr3; (b) PEDOT:PSS/TAPC/CsPbBr3
    器件TAPC浓度/mg·mL–1最大亮度/cd·m–2最大电流效率/cd·A–1外量子效率/%色坐标(x, y)
    A023961.810.47(0.13, 0.80)
    B260814.521.17(0.13, 0.80)
    C5131986.841.77(0.13, 0.80)
    D836781.130.29(0.13, 0.80)
    Table 1.

    List of EL performance of PeLEDs.

    PeLEDs性能

    FilmsB1/% B2/% τ1/ns τ2/ns τave/ns
    PEDOT:PSS/CsPbBr379214.86210.4547.44
    PEDOT:PSS/TAPC/CsPbBr375255.72212.6557.64
    Table 2.

    List of TRPL parameters.

    瞬态荧光寿命参数统计列表

    Run Wang, Ya-Lan Jia, Yue Zhang, Xing-Juan Ma, Qiang Xu, Zhi-Xin Zhu, Yan-Hong Deng, Zu-Hong Xiong, Chun-Hong Gao. High efficiency green perovskite light-emitting diodes based on exciton blocking layer[J]. Acta Physica Sinica, 2020, 69(3): 038501-1
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