• Journal of Advanced Dielectrics
  • Vol. 12, Issue 1, 2160022 (2022)
G. A. Geguzina1、*, I. G. Popova2, and A. E. Panich3
Author Affiliations
  • 1Research Institute of Physics, Southern Federal University, No. 194, Stachki Ave., Rostov-on-Don, 344090, Russia
  • 2Department of Physics, Don State Technical University, No. 1, Gagarin sq., Rostov-on-Don, 344000, Russia
  • 3Institute of High Technology and Piezotechnics, Southern Federal University, No. 10, Milchakova str., Rostov-on-Don, 344090, Russia
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    DOI: 10.1142/S2010135X21600225 Cite this Article
    G. A. Geguzina, I. G. Popova, A. E. Panich. Binary perovskite solid solutions and trends in their phase transitions temperatures variation[J]. Journal of Advanced Dielectrics, 2022, 12(1): 2160022 Copy Citation Text show less

    Abstract

    Some of the known binary ABO3perovskites with ferro- (FE) or antiferroelectric (AFE) at TC and different magnetic phase transitions (PT): ferro-and antiferromagnetic at TN and also some of their solid solutions are considered. Some correlations between their FE or AFE and/or magnetic PTs temperatures, on the one hand, and their interatomic bond A–O strains, on the other hand, have been constructed. It is shown that in the plotted diagrams these temperatures change with a change in δAO values as follows: classical FEs are followed by multiferroics, starting with BiFeO3 and ending with YVO3, followed by classical AFEs. At the same time, the temperatures TC and TN experience maxima at the corresponding points for BiFeO3, then quickly decrease, and the difference between them, TC-TN, basically also decreases, slightly increasing along the way to the point EuTiO3. which made it possible to systematize these TC and TN.Some of the known binary ABO3perovskites with ferro- (FE) or antiferroelectric (AFE) at TC and different magnetic phase transitions (PT): ferro-and antiferromagnetic at TN and also some of their solid solutions are considered. Some correlations between their FE or AFE and/or magnetic PTs temperatures, on the one hand, and their interatomic bond A–O strains, on the other hand, have been constructed. It is shown that in the plotted diagrams these temperatures change with a change in δAO values as follows: classical FEs are followed by multiferroics, starting with BiFeO3 and ending with YVO3, followed by classical AFEs. At the same time, the temperatures TC and TN experience maxima at the corresponding points for BiFeO3, then quickly decrease, and the difference between them, TC-TN, basically also decreases, slightly increasing along the way to the point EuTiO3. which made it possible to systematize these TC and TN.
    G. A. Geguzina, I. G. Popova, A. E. Panich. Binary perovskite solid solutions and trends in their phase transitions temperatures variation[J]. Journal of Advanced Dielectrics, 2022, 12(1): 2160022
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